Standard

Syntheses and structures of complexes {Mo2S2O2}2+ with labile Cl- and DMF ligands. / Ogienko, D. S.; Smolentsev, A. I.; Bashirov, D. A. et al.

In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Vol. 41, No. 11, 01.11.2015, p. 759-764.

Research output: Contribution to journal › Article › peer-review

Harvard

Ogienko, DS, Smolentsev, AI, Bashirov, DA, Afonin, MY, Petrov, PA & Konchenko, SN 2015, 'Syntheses and structures of complexes {Mo2S2O2}2+ with labile Cl- and DMF ligands', Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 41, no. 11, pp. 759-764. https://doi.org/10.1134/S1070328415110056

APA

Ogienko, D. S., Smolentsev, A. I., Bashirov, D. A., Afonin, M. Y., Petrov, P. A., & Konchenko, S. N. (2015). Syntheses and structures of complexes {Mo2S2O2}2+ with labile Cl- and DMF ligands. Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 41(11), 759-764. https://doi.org/10.1134/S1070328415110056

Vancouver

Ogienko DS, Smolentsev AI, Bashirov DA, Afonin MY, Petrov PA, Konchenko SN. Syntheses and structures of complexes {Mo2S2O2}2+ with labile Cl- and DMF ligands. Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2015 Nov 1;41(11):759-764. doi: 10.1134/S1070328415110056

Author

Ogienko, D. S. ; Smolentsev, A. I. ; Bashirov, D. A. et al. / Syntheses and structures of complexes {Mo2S2O2}2+ with labile Cl- and DMF ligands. In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2015 ; Vol. 41, No. 11. pp. 759-764.

BibTeX

@article{4612237c67764d1f99f9998a24828c00,
title = "Syntheses and structures of complexes {Mo2S2O2}2+ with labile Cl- and DMF ligands",
abstract = "Complex (Me4N)2[Mo2S2O2Cl4] ((Me4N)2[II]) is synthesized by passing gaseous HCl through a solution of (Me4N)2[Mo2O2S8] ((Me4N)2[I]). The recrystallization of (Me4N)2[II] from N,N-dimethylformamide (DMF) gives compound (Me4N)[Mo2S2O2Cl3(DMF)3] ((Me4N)[III]). The oxidation of (Et4N)2[I] with iodine in DMF affords the earlier described complex [Mo2S2O2(DMF)6]I2 ([IV]I 2). However, this complex was not structurally characterized. The structures of the synthesized compounds are determined by X-ray diffraction analyses (CIF files CCDC nos. 1059924-1059926). Thus, several complexes in which the binuclear fragment {Mo2S2O2}2+ has a labile coordination environment were synthesized and characterized.",
author = "Ogienko, {D. S.} and Smolentsev, {A. I.} and Bashirov, {D. A.} and Afonin, {M. Yu} and Petrov, {P. A.} and Konchenko, {S. N.}",
year = "2015",
month = nov,
day = "1",
doi = "10.1134/S1070328415110056",
language = "English",
volume = "41",
pages = "759--764",
journal = "Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya",
issn = "1070-3284",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "11",

}

RIS

TY - JOUR

T1 - Syntheses and structures of complexes {Mo2S2O2}2+ with labile Cl- and DMF ligands

AU - Ogienko, D. S.

AU - Smolentsev, A. I.

AU - Bashirov, D. A.

AU - Afonin, M. Yu

AU - Petrov, P. A.

AU - Konchenko, S. N.

PY - 2015/11/1

Y1 - 2015/11/1

N2 - Complex (Me4N)2[Mo2S2O2Cl4] ((Me4N)2[II]) is synthesized by passing gaseous HCl through a solution of (Me4N)2[Mo2O2S8] ((Me4N)2[I]). The recrystallization of (Me4N)2[II] from N,N-dimethylformamide (DMF) gives compound (Me4N)[Mo2S2O2Cl3(DMF)3] ((Me4N)[III]). The oxidation of (Et4N)2[I] with iodine in DMF affords the earlier described complex [Mo2S2O2(DMF)6]I2 ([IV]I 2). However, this complex was not structurally characterized. The structures of the synthesized compounds are determined by X-ray diffraction analyses (CIF files CCDC nos. 1059924-1059926). Thus, several complexes in which the binuclear fragment {Mo2S2O2}2+ has a labile coordination environment were synthesized and characterized.

AB - Complex (Me4N)2[Mo2S2O2Cl4] ((Me4N)2[II]) is synthesized by passing gaseous HCl through a solution of (Me4N)2[Mo2O2S8] ((Me4N)2[I]). The recrystallization of (Me4N)2[II] from N,N-dimethylformamide (DMF) gives compound (Me4N)[Mo2S2O2Cl3(DMF)3] ((Me4N)[III]). The oxidation of (Et4N)2[I] with iodine in DMF affords the earlier described complex [Mo2S2O2(DMF)6]I2 ([IV]I 2). However, this complex was not structurally characterized. The structures of the synthesized compounds are determined by X-ray diffraction analyses (CIF files CCDC nos. 1059924-1059926). Thus, several complexes in which the binuclear fragment {Mo2S2O2}2+ has a labile coordination environment were synthesized and characterized.

UR - http://www.scopus.com/inward/record.url?scp=84946044280&partnerID=8YFLogxK

U2 - 10.1134/S1070328415110056

DO - 10.1134/S1070328415110056

M3 - Article

AN - SCOPUS:84946044280

VL - 41

SP - 759

EP - 764

JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

SN - 1070-3284

IS - 11

ER -

ID: 25414972