Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Syntheses and structures of complexes {Mo2S2O2}2+ with labile Cl- and DMF ligands. / Ogienko, D. S.; Smolentsev, A. I.; Bashirov, D. A. и др.
в: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Том 41, № 11, 01.11.2015, стр. 759-764.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Syntheses and structures of complexes {Mo2S2O2}2+ with labile Cl- and DMF ligands
AU - Ogienko, D. S.
AU - Smolentsev, A. I.
AU - Bashirov, D. A.
AU - Afonin, M. Yu
AU - Petrov, P. A.
AU - Konchenko, S. N.
PY - 2015/11/1
Y1 - 2015/11/1
N2 - Complex (Me4N)2[Mo2S2O2Cl4] ((Me4N)2[II]) is synthesized by passing gaseous HCl through a solution of (Me4N)2[Mo2O2S8] ((Me4N)2[I]). The recrystallization of (Me4N)2[II] from N,N-dimethylformamide (DMF) gives compound (Me4N)[Mo2S2O2Cl3(DMF)3] ((Me4N)[III]). The oxidation of (Et4N)2[I] with iodine in DMF affords the earlier described complex [Mo2S2O2(DMF)6]I2 ([IV]I 2). However, this complex was not structurally characterized. The structures of the synthesized compounds are determined by X-ray diffraction analyses (CIF files CCDC nos. 1059924-1059926). Thus, several complexes in which the binuclear fragment {Mo2S2O2}2+ has a labile coordination environment were synthesized and characterized.
AB - Complex (Me4N)2[Mo2S2O2Cl4] ((Me4N)2[II]) is synthesized by passing gaseous HCl through a solution of (Me4N)2[Mo2O2S8] ((Me4N)2[I]). The recrystallization of (Me4N)2[II] from N,N-dimethylformamide (DMF) gives compound (Me4N)[Mo2S2O2Cl3(DMF)3] ((Me4N)[III]). The oxidation of (Et4N)2[I] with iodine in DMF affords the earlier described complex [Mo2S2O2(DMF)6]I2 ([IV]I 2). However, this complex was not structurally characterized. The structures of the synthesized compounds are determined by X-ray diffraction analyses (CIF files CCDC nos. 1059924-1059926). Thus, several complexes in which the binuclear fragment {Mo2S2O2}2+ has a labile coordination environment were synthesized and characterized.
UR - http://www.scopus.com/inward/record.url?scp=84946044280&partnerID=8YFLogxK
U2 - 10.1134/S1070328415110056
DO - 10.1134/S1070328415110056
M3 - Article
AN - SCOPUS:84946044280
VL - 41
SP - 759
EP - 764
JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
SN - 1070-3284
IS - 11
ER -
ID: 25414972