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Supramolecular Adduct of γ-Cyclodextrin and [{Re6Q8}(H2O)6]2+ (Q=S, Se). / Abramov, Pavel A.; Ivanov, Anton A.; Shestopalov, Michael A. et al.

In: Journal of Cluster Science, Vol. 29, No. 1, 01.01.2018, p. 9-13.

Research output: Contribution to journal › Article › peer-review

Harvard

Abramov, PA, Ivanov, AA, Shestopalov, MA, Moussawi, MA, Cadot, E, Floquet, S, Haouas, M & Sokolov, MN 2018, 'Supramolecular Adduct of γ-Cyclodextrin and [{Re6Q8}(H2O)6]2+ (Q=S, Se)', Journal of Cluster Science, vol. 29, no. 1, pp. 9-13. https://doi.org/10.1007/s10876-017-1312-z

APA

Abramov, P. A., Ivanov, A. A., Shestopalov, M. A., Moussawi, M. A., Cadot, E., Floquet, S., Haouas, M., & Sokolov, M. N. (2018). Supramolecular Adduct of γ-Cyclodextrin and [{Re6Q8}(H2O)6]2+ (Q=S, Se). Journal of Cluster Science, 29(1), 9-13. https://doi.org/10.1007/s10876-017-1312-z

Vancouver

Abramov PA, Ivanov AA, Shestopalov MA, Moussawi MA, Cadot E, Floquet S et al. Supramolecular Adduct of γ-Cyclodextrin and [{Re6Q8}(H2O)6]2+ (Q=S, Se). Journal of Cluster Science. 2018 Jan 1;29(1):9-13. doi: 10.1007/s10876-017-1312-z

Author

Abramov, Pavel A. ; Ivanov, Anton A. ; Shestopalov, Michael A. et al. / Supramolecular Adduct of γ-Cyclodextrin and [{Re6Q8}(H2O)6]2+ (Q=S, Se). In: Journal of Cluster Science. 2018 ; Vol. 29, No. 1. pp. 9-13.

BibTeX

@article{4727f4dcc98746acb4adb14d479b57a2,
title = "Supramolecular Adduct of γ-Cyclodextrin and [{Re6Q8}(H2O)6]2+ (Q=S, Se)",
abstract = "Slow evaporation of water solution of [{Re6S8}(H2O)6]2+ generated in situ from [{Re6S8}(OH)6]4– in presence of γ-cyclodextrin (CD) leads to crystallization of {[{Re6S8}(H2O)6] ⊂ [γ-CD]}(NO3)2·12H2O (1·12H2O) supramolecular complex, which was characterized by single-crystal X-ray diffraction crystallography, IR-spectroscopy, thermogravimetric and elemental analyses. X-ray analysis confirms the formation of 1:1 {[{Re6S8}(H2O)6] ⊂ [γ-CD]}2+ inclusion compound in the solid state. However, no adduct formation was detected between [{Re6S8}(H2O)6]2+ and γ-cyclodextrin in solution, according to 1H NMR spectroscopy. In the case of in situ generated [{Re6Se8}(H2O)6]2+ the reaction solution with γ-cyclodextrin is unstable and during the crystallization only amorphous precipitate has been obtained.",
keywords = "Crystal structure, Cyclodextrin, Rhenium cluster, SOLUBILIZATION, RHENIUM CLUSTER COMPLEXES, LUMINESCENCE, RAY CONTRAST AGENT, MOLYBDENUM, CELLULAR INTERNALIZATION, CYTOTOXICITY",
author = "Abramov, {Pavel A.} and Ivanov, {Anton A.} and Shestopalov, {Michael A.} and Moussawi, {Mhamad A.} and Emmanuel Cadot and S{\'e}bastien Floquet and Mohamed Haouas and Sokolov, {Maxim N.}",
year = "2018",
month = jan,
day = "1",
doi = "10.1007/s10876-017-1312-z",
language = "English",
volume = "29",
pages = "9--13",
journal = "Journal of Cluster Science",
issn = "1040-7278",
publisher = "Springer New York",
number = "1",

}

RIS

TY - JOUR

T1 - Supramolecular Adduct of γ-Cyclodextrin and [{Re6Q8}(H2O)6]2+ (Q=S, Se)

AU - Abramov, Pavel A.

AU - Ivanov, Anton A.

AU - Shestopalov, Michael A.

AU - Moussawi, Mhamad A.

AU - Cadot, Emmanuel

AU - Floquet, Sébastien

AU - Haouas, Mohamed

AU - Sokolov, Maxim N.

PY - 2018/1/1

Y1 - 2018/1/1

N2 - Slow evaporation of water solution of [{Re6S8}(H2O)6]2+ generated in situ from [{Re6S8}(OH)6]4– in presence of γ-cyclodextrin (CD) leads to crystallization of {[{Re6S8}(H2O)6] ⊂ [γ-CD]}(NO3)2·12H2O (1·12H2O) supramolecular complex, which was characterized by single-crystal X-ray diffraction crystallography, IR-spectroscopy, thermogravimetric and elemental analyses. X-ray analysis confirms the formation of 1:1 {[{Re6S8}(H2O)6] ⊂ [γ-CD]}2+ inclusion compound in the solid state. However, no adduct formation was detected between [{Re6S8}(H2O)6]2+ and γ-cyclodextrin in solution, according to 1H NMR spectroscopy. In the case of in situ generated [{Re6Se8}(H2O)6]2+ the reaction solution with γ-cyclodextrin is unstable and during the crystallization only amorphous precipitate has been obtained.

AB - Slow evaporation of water solution of [{Re6S8}(H2O)6]2+ generated in situ from [{Re6S8}(OH)6]4– in presence of γ-cyclodextrin (CD) leads to crystallization of {[{Re6S8}(H2O)6] ⊂ [γ-CD]}(NO3)2·12H2O (1·12H2O) supramolecular complex, which was characterized by single-crystal X-ray diffraction crystallography, IR-spectroscopy, thermogravimetric and elemental analyses. X-ray analysis confirms the formation of 1:1 {[{Re6S8}(H2O)6] ⊂ [γ-CD]}2+ inclusion compound in the solid state. However, no adduct formation was detected between [{Re6S8}(H2O)6]2+ and γ-cyclodextrin in solution, according to 1H NMR spectroscopy. In the case of in situ generated [{Re6Se8}(H2O)6]2+ the reaction solution with γ-cyclodextrin is unstable and during the crystallization only amorphous precipitate has been obtained.

KW - Crystal structure

KW - Cyclodextrin

KW - Rhenium cluster

KW - SOLUBILIZATION

KW - RHENIUM CLUSTER COMPLEXES

KW - LUMINESCENCE

KW - RAY CONTRAST AGENT

KW - MOLYBDENUM

KW - CELLULAR INTERNALIZATION

KW - CYTOTOXICITY

UR - http://www.scopus.com/inward/record.url?scp=85032902777&partnerID=8YFLogxK

U2 - 10.1007/s10876-017-1312-z

DO - 10.1007/s10876-017-1312-z

M3 - Article

AN - SCOPUS:85032902777

VL - 29

SP - 9

EP - 13

JO - Journal of Cluster Science

JF - Journal of Cluster Science

SN - 1040-7278

IS - 1

ER -

ID: 12101655