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Structure, Volatility, and Luminescence of Phenanthroline Adducts with Lanthanide Tris-Dipivaloylmethanates. / Stabnikov, P. A.; Urkasym kyzy, S.; Trubin, S. V. et al.

In: Journal of Structural Chemistry, Vol. 61, No. 1, 01.01.2020, p. 101-108.

Research output: Contribution to journalArticlepeer-review

Harvard

Stabnikov, PA, Urkasym kyzy, S, Trubin, SV, Pervukhina, NV, Korolkov, IV, Berezin, AS & Morozova, NB 2020, 'Structure, Volatility, and Luminescence of Phenanthroline Adducts with Lanthanide Tris-Dipivaloylmethanates', Journal of Structural Chemistry, vol. 61, no. 1, pp. 101-108. https://doi.org/10.1134/S0022476620010114

APA

Stabnikov, P. A., Urkasym kyzy, S., Trubin, S. V., Pervukhina, N. V., Korolkov, I. V., Berezin, A. S., & Morozova, N. B. (2020). Structure, Volatility, and Luminescence of Phenanthroline Adducts with Lanthanide Tris-Dipivaloylmethanates. Journal of Structural Chemistry, 61(1), 101-108. https://doi.org/10.1134/S0022476620010114

Vancouver

Stabnikov PA, Urkasym kyzy S, Trubin SV, Pervukhina NV, Korolkov IV, Berezin AS et al. Structure, Volatility, and Luminescence of Phenanthroline Adducts with Lanthanide Tris-Dipivaloylmethanates. Journal of Structural Chemistry. 2020 Jan 1;61(1):101-108. doi: 10.1134/S0022476620010114

Author

Stabnikov, P. A. ; Urkasym kyzy, S. ; Trubin, S. V. et al. / Structure, Volatility, and Luminescence of Phenanthroline Adducts with Lanthanide Tris-Dipivaloylmethanates. In: Journal of Structural Chemistry. 2020 ; Vol. 61, No. 1. pp. 101-108.

BibTeX

@article{9a95e6e70f244646b91d60b242960df0,
title = "Structure, Volatility, and Luminescence of Phenanthroline Adducts with Lanthanide Tris-Dipivaloylmethanates",
abstract = "A series of Ln(III) tris-dipivaloylmethanates with phenanthroline with the composition Ln(thd)3Phen (Ln = Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb) is synthesized. It is found that all adducts are isostructural with previously known La(thd)3Phen, Tb(thd)3Phen, and Dy(thd)3Phen complexes. Crystal structures of Sm(thd)3Phen (I) and Eu(thd)3Phen (II) complexes are determined at 150(2) K (space group P1 ¯ , a = 10.8590(5) {\AA}, b = 12.3049(6) {\AA}, c = 18.4479(10) {\AA}, α = 80.210(2)°, β = 87.499(2)°, γ = 68.799(2)°, V = 2264.3(2) {\AA}3, Z = 2; space group P1 ¯ , a = 10.8788(3) {\AA}, b = 12.3009(3) {\AA}, c = 18.4309(5) {\AA}, α = 80.3644(9)°, β = 87.5440(10)°, γ = 68.7376(8)°, V = 2265.7(1) {\AA}3, Z = 2 respectively). Crystal structures of I and II consist of isolated Ln(thd)3Phen molecules (Ln = Sm(III), Eu(III)). The highest luminescence quantum yields for this series of adducts are established for Eu(thd)3Phen (10%) and Sm(thd)3Phen (1.5%). Thermogravimetric studies show that the volatility of adducts weakly increases from Pr(thd)3Phen to Yb(thd)3Phen. Their melting points are close to the reported data.",
keywords = "crystal structure, Ln(III) β-diketonates, luminescence, phenanthroline, volatility, Ln(III) beta-diketonates, CRYSTAL",
author = "Stabnikov, {P. A.} and {Urkasym kyzy}, S. and Trubin, {S. V.} and Pervukhina, {N. V.} and Korolkov, {I. V.} and Berezin, {A. S.} and Morozova, {N. B.}",
note = "Publisher Copyright: {\textcopyright} 2020, Pleiades Publishing, Ltd. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.",
year = "2020",
month = jan,
day = "1",
doi = "10.1134/S0022476620010114",
language = "English",
volume = "61",
pages = "101--108",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "1",

}

RIS

TY - JOUR

T1 - Structure, Volatility, and Luminescence of Phenanthroline Adducts with Lanthanide Tris-Dipivaloylmethanates

AU - Stabnikov, P. A.

AU - Urkasym kyzy, S.

AU - Trubin, S. V.

AU - Pervukhina, N. V.

AU - Korolkov, I. V.

AU - Berezin, A. S.

AU - Morozova, N. B.

N1 - Publisher Copyright: © 2020, Pleiades Publishing, Ltd. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.

PY - 2020/1/1

Y1 - 2020/1/1

N2 - A series of Ln(III) tris-dipivaloylmethanates with phenanthroline with the composition Ln(thd)3Phen (Ln = Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb) is synthesized. It is found that all adducts are isostructural with previously known La(thd)3Phen, Tb(thd)3Phen, and Dy(thd)3Phen complexes. Crystal structures of Sm(thd)3Phen (I) and Eu(thd)3Phen (II) complexes are determined at 150(2) K (space group P1 ¯ , a = 10.8590(5) Å, b = 12.3049(6) Å, c = 18.4479(10) Å, α = 80.210(2)°, β = 87.499(2)°, γ = 68.799(2)°, V = 2264.3(2) Å3, Z = 2; space group P1 ¯ , a = 10.8788(3) Å, b = 12.3009(3) Å, c = 18.4309(5) Å, α = 80.3644(9)°, β = 87.5440(10)°, γ = 68.7376(8)°, V = 2265.7(1) Å3, Z = 2 respectively). Crystal structures of I and II consist of isolated Ln(thd)3Phen molecules (Ln = Sm(III), Eu(III)). The highest luminescence quantum yields for this series of adducts are established for Eu(thd)3Phen (10%) and Sm(thd)3Phen (1.5%). Thermogravimetric studies show that the volatility of adducts weakly increases from Pr(thd)3Phen to Yb(thd)3Phen. Their melting points are close to the reported data.

AB - A series of Ln(III) tris-dipivaloylmethanates with phenanthroline with the composition Ln(thd)3Phen (Ln = Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb) is synthesized. It is found that all adducts are isostructural with previously known La(thd)3Phen, Tb(thd)3Phen, and Dy(thd)3Phen complexes. Crystal structures of Sm(thd)3Phen (I) and Eu(thd)3Phen (II) complexes are determined at 150(2) K (space group P1 ¯ , a = 10.8590(5) Å, b = 12.3049(6) Å, c = 18.4479(10) Å, α = 80.210(2)°, β = 87.499(2)°, γ = 68.799(2)°, V = 2264.3(2) Å3, Z = 2; space group P1 ¯ , a = 10.8788(3) Å, b = 12.3009(3) Å, c = 18.4309(5) Å, α = 80.3644(9)°, β = 87.5440(10)°, γ = 68.7376(8)°, V = 2265.7(1) Å3, Z = 2 respectively). Crystal structures of I and II consist of isolated Ln(thd)3Phen molecules (Ln = Sm(III), Eu(III)). The highest luminescence quantum yields for this series of adducts are established for Eu(thd)3Phen (10%) and Sm(thd)3Phen (1.5%). Thermogravimetric studies show that the volatility of adducts weakly increases from Pr(thd)3Phen to Yb(thd)3Phen. Their melting points are close to the reported data.

KW - crystal structure

KW - Ln(III) β-diketonates

KW - luminescence

KW - phenanthroline

KW - volatility

KW - Ln(III) beta-diketonates

KW - CRYSTAL

UR - http://www.scopus.com/inward/record.url?scp=85087936261&partnerID=8YFLogxK

U2 - 10.1134/S0022476620010114

DO - 10.1134/S0022476620010114

M3 - Article

AN - SCOPUS:85087936261

VL - 61

SP - 101

EP - 108

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 1

ER -

ID: 24767750