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Structure of diethylentriammonium hexachloroiridate(IV) complexes. / Makotchenko, E. V.; Baidina, I. A.; Korol′kov, I. V.

In: Journal of Structural Chemistry, Vol. 62, No. 3, 03.2021, p. 422-430.

Research output: Contribution to journal › Article › peer-review

Harvard

Makotchenko, EV, Baidina, IA & Korol′kov, IV 2021, 'Structure of diethylentriammonium hexachloroiridate(IV) complexes', Journal of Structural Chemistry, vol. 62, no. 3, pp. 422-430. https://doi.org/10.1134/S0022476621030082

APA

Makotchenko, E. V., Baidina, I. A., & Korol′kov, I. V. (2021). Structure of diethylentriammonium hexachloroiridate(IV) complexes. Journal of Structural Chemistry, 62(3), 422-430. https://doi.org/10.1134/S0022476621030082

Vancouver

Makotchenko EV, Baidina IA, Korol′kov IV. Structure of diethylentriammonium hexachloroiridate(IV) complexes. Journal of Structural Chemistry. 2021 Mar;62(3):422-430. doi: 10.1134/S0022476621030082

Author

Makotchenko, E. V. ; Baidina, I. A. ; Korol′kov, I. V. / Structure of diethylentriammonium hexachloroiridate(IV) complexes. In: Journal of Structural Chemistry. 2021 ; Vol. 62, No. 3. pp. 422-430.

BibTeX

@article{2ef735a071eb45c4ba19bab4f6145cf4,
title = "Structure of diethylentriammonium hexachloroiridate(IV) complexes",
abstract = "The crystal structures of salts (DienH3)4[IrCl6]5Cl2 (I), (DienH3)[IrCl6]Cl (II), and (DienH3)2[IrCl6]3 (III) (DienH33+ is triple protonated diethylenetriamine). Crystal data for I: a = 26.891(2) {\AA}, b = 6.9379(3) {\AA}, c = 35.031(3) {\AA}, β = 100.758(2)°, space group C2/c, Z = 8, V = 6420.8(8) {\AA}3, ρcalc = 2.607 g/cm3; II: a = 6.8598(3) {\AA}, b = 23.2075(11) {\AA}, c = 9.5730(4) {\AA}, β = 90.240(2)°, space group P21/n, Z = 4, V = 1524.00(12) {\AA}3, ρcalc = 2.382 g/cm3; III:a = 12.4277(3) {\AA}, b = 19.6134(5) {\AA}, c = 14.3613(3) {\AA}, β = 98.260(1)°, space group P21/n, Z = 4, V = 3464.25(14) {\AA}3, ρcalc = 2.736 g/cm3.",
keywords = "complexes, diethylenetriamine, iridium, X-ray diffraction",
author = "Makotchenko, {E. V.} and Baidina, {I. A.} and Korol′kov, {I. V.}",
note = "Publisher Copyright: {\textcopyright} 2021, Pleiades Publishing, Ltd.",
year = "2021",
month = mar,
doi = "10.1134/S0022476621030082",
language = "English",
volume = "62",
pages = "422--430",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "3",

}

RIS

TY - JOUR

T1 - Structure of diethylentriammonium hexachloroiridate(IV) complexes

AU - Makotchenko, E. V.

AU - Baidina, I. A.

AU - Korol′kov, I. V.

N1 - Publisher Copyright: © 2021, Pleiades Publishing, Ltd.

PY - 2021/3

Y1 - 2021/3

N2 - The crystal structures of salts (DienH3)4[IrCl6]5Cl2 (I), (DienH3)[IrCl6]Cl (II), and (DienH3)2[IrCl6]3 (III) (DienH33+ is triple protonated diethylenetriamine). Crystal data for I: a = 26.891(2) Å, b = 6.9379(3) Å, c = 35.031(3) Å, β = 100.758(2)°, space group C2/c, Z = 8, V = 6420.8(8) Å3, ρcalc = 2.607 g/cm3; II: a = 6.8598(3) Å, b = 23.2075(11) Å, c = 9.5730(4) Å, β = 90.240(2)°, space group P21/n, Z = 4, V = 1524.00(12) Å3, ρcalc = 2.382 g/cm3; III:a = 12.4277(3) Å, b = 19.6134(5) Å, c = 14.3613(3) Å, β = 98.260(1)°, space group P21/n, Z = 4, V = 3464.25(14) Å3, ρcalc = 2.736 g/cm3.

AB - The crystal structures of salts (DienH3)4[IrCl6]5Cl2 (I), (DienH3)[IrCl6]Cl (II), and (DienH3)2[IrCl6]3 (III) (DienH33+ is triple protonated diethylenetriamine). Crystal data for I: a = 26.891(2) Å, b = 6.9379(3) Å, c = 35.031(3) Å, β = 100.758(2)°, space group C2/c, Z = 8, V = 6420.8(8) Å3, ρcalc = 2.607 g/cm3; II: a = 6.8598(3) Å, b = 23.2075(11) Å, c = 9.5730(4) Å, β = 90.240(2)°, space group P21/n, Z = 4, V = 1524.00(12) Å3, ρcalc = 2.382 g/cm3; III:a = 12.4277(3) Å, b = 19.6134(5) Å, c = 14.3613(3) Å, β = 98.260(1)°, space group P21/n, Z = 4, V = 3464.25(14) Å3, ρcalc = 2.736 g/cm3.

KW - complexes

KW - diethylenetriamine

KW - iridium

KW - X-ray diffraction

UR - http://www.scopus.com/inward/record.url?scp=85107592946&partnerID=8YFLogxK

U2 - 10.1134/S0022476621030082

DO - 10.1134/S0022476621030082

M3 - Article

AN - SCOPUS:85107592946

VL - 62

SP - 422

EP - 430

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 3

ER -

ID: 34174773