Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Structure of diethylentriammonium hexachloroiridate(IV) complexes. / Makotchenko, E. V.; Baidina, I. A.; Korol′kov, I. V.
в: Journal of Structural Chemistry, Том 62, № 3, 03.2021, стр. 422-430.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Structure of diethylentriammonium hexachloroiridate(IV) complexes
AU - Makotchenko, E. V.
AU - Baidina, I. A.
AU - Korol′kov, I. V.
N1 - Publisher Copyright: © 2021, Pleiades Publishing, Ltd.
PY - 2021/3
Y1 - 2021/3
N2 - The crystal structures of salts (DienH3)4[IrCl6]5Cl2 (I), (DienH3)[IrCl6]Cl (II), and (DienH3)2[IrCl6]3 (III) (DienH33+ is triple protonated diethylenetriamine). Crystal data for I: a = 26.891(2) Å, b = 6.9379(3) Å, c = 35.031(3) Å, β = 100.758(2)°, space group C2/c, Z = 8, V = 6420.8(8) Å3, ρcalc = 2.607 g/cm3; II: a = 6.8598(3) Å, b = 23.2075(11) Å, c = 9.5730(4) Å, β = 90.240(2)°, space group P21/n, Z = 4, V = 1524.00(12) Å3, ρcalc = 2.382 g/cm3; III:a = 12.4277(3) Å, b = 19.6134(5) Å, c = 14.3613(3) Å, β = 98.260(1)°, space group P21/n, Z = 4, V = 3464.25(14) Å3, ρcalc = 2.736 g/cm3.
AB - The crystal structures of salts (DienH3)4[IrCl6]5Cl2 (I), (DienH3)[IrCl6]Cl (II), and (DienH3)2[IrCl6]3 (III) (DienH33+ is triple protonated diethylenetriamine). Crystal data for I: a = 26.891(2) Å, b = 6.9379(3) Å, c = 35.031(3) Å, β = 100.758(2)°, space group C2/c, Z = 8, V = 6420.8(8) Å3, ρcalc = 2.607 g/cm3; II: a = 6.8598(3) Å, b = 23.2075(11) Å, c = 9.5730(4) Å, β = 90.240(2)°, space group P21/n, Z = 4, V = 1524.00(12) Å3, ρcalc = 2.382 g/cm3; III:a = 12.4277(3) Å, b = 19.6134(5) Å, c = 14.3613(3) Å, β = 98.260(1)°, space group P21/n, Z = 4, V = 3464.25(14) Å3, ρcalc = 2.736 g/cm3.
KW - complexes
KW - diethylenetriamine
KW - iridium
KW - X-ray diffraction
UR - http://www.scopus.com/inward/record.url?scp=85107592946&partnerID=8YFLogxK
U2 - 10.1134/S0022476621030082
DO - 10.1134/S0022476621030082
M3 - Article
AN - SCOPUS:85107592946
VL - 62
SP - 422
EP - 430
JO - Journal of Structural Chemistry
JF - Journal of Structural Chemistry
SN - 0022-4766
IS - 3
ER -
ID: 34174773