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Structure of A Coordination Polymer [Cu(En)2CrO4]n. / Sukhikh, A. S.; Khranenko, S. P.; Gromilov, S. A.

In: Journal of Structural Chemistry, Vol. 59, No. 2, 01.03.2018, p. 395-397.

Research output: Contribution to journal › Article › peer-review

Harvard

Sukhikh, AS, Khranenko, SP & Gromilov, SA 2018, 'Structure of A Coordination Polymer [Cu(En)2CrO4]n', Journal of Structural Chemistry, vol. 59, no. 2, pp. 395-397. https://doi.org/10.1134/S0022476618020208

APA

Sukhikh, A. S., Khranenko, S. P., & Gromilov, S. A. (2018). Structure of A Coordination Polymer [Cu(En)2CrO4]n. Journal of Structural Chemistry, 59(2), 395-397. https://doi.org/10.1134/S0022476618020208

Vancouver

Sukhikh AS, Khranenko SP, Gromilov SA. Structure of A Coordination Polymer [Cu(En)2CrO4]n. Journal of Structural Chemistry. 2018 Mar 1;59(2):395-397. doi: 10.1134/S0022476618020208

Author

Sukhikh, A. S. ; Khranenko, S. P. ; Gromilov, S. A. / Structure of A Coordination Polymer [Cu(En)2CrO4]n. In: Journal of Structural Chemistry. 2018 ; Vol. 59, No. 2. pp. 395-397.

BibTeX

@article{585385a5d9e94ec8b821362750c12bad,
title = "Structure of A Coordination Polymer [Cu(En)2CrO4]n",
abstract = "The crystal structure of [Cu(En)2CrO4]n (En is ethylenediamine) is determined: a = 14.7359(4) {\AA}, b = 9.8083(3) {\AA}, c = 14.2664(4) {\AA}, V = 2061.98(10) {\AA}3, space group Cmce, Z = 8, dx = 1.931 g/cm3. It is demonstrated that the studied phase is isostructural with [Сu(Еn)2SO4]n. A pseudotetragonal copper atom coordination (Cu–N 2.0204 {\AA} and 2.0244 {\AA}, ∠N–Cu–N 84.73°) is completed to distorted octahedral by two oxygen atoms of chromate anions (Cu–O 2.433 {\AA} and 2.380 {\AA}).",
keywords = "chromate anion, coordination polyhedron, copper bis-ethylenediamine, crystal chemistry, single crystal X-ray diffraction analysis",
author = "Sukhikh, {A. S.} and Khranenko, {S. P.} and Gromilov, {S. A.}",
year = "2018",
month = mar,
day = "1",
doi = "10.1134/S0022476618020208",
language = "English",
volume = "59",
pages = "395--397",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "2",

}

RIS

TY - JOUR

T1 - Structure of A Coordination Polymer [Cu(En)2CrO4]n

AU - Sukhikh, A. S.

AU - Khranenko, S. P.

AU - Gromilov, S. A.

PY - 2018/3/1

Y1 - 2018/3/1

N2 - The crystal structure of [Cu(En)2CrO4]n (En is ethylenediamine) is determined: a = 14.7359(4) Å, b = 9.8083(3) Å, c = 14.2664(4) Å, V = 2061.98(10) Å3, space group Cmce, Z = 8, dx = 1.931 g/cm3. It is demonstrated that the studied phase is isostructural with [Сu(Еn)2SO4]n. A pseudotetragonal copper atom coordination (Cu–N 2.0204 Å and 2.0244 Å, ∠N–Cu–N 84.73°) is completed to distorted octahedral by two oxygen atoms of chromate anions (Cu–O 2.433 Å and 2.380 Å).

AB - The crystal structure of [Cu(En)2CrO4]n (En is ethylenediamine) is determined: a = 14.7359(4) Å, b = 9.8083(3) Å, c = 14.2664(4) Å, V = 2061.98(10) Å3, space group Cmce, Z = 8, dx = 1.931 g/cm3. It is demonstrated that the studied phase is isostructural with [Сu(Еn)2SO4]n. A pseudotetragonal copper atom coordination (Cu–N 2.0204 Å and 2.0244 Å, ∠N–Cu–N 84.73°) is completed to distorted octahedral by two oxygen atoms of chromate anions (Cu–O 2.433 Å and 2.380 Å).

KW - chromate anion

KW - coordination polyhedron

KW - copper bis-ethylenediamine

KW - crystal chemistry

KW - single crystal X-ray diffraction analysis

UR - http://www.scopus.com/inward/record.url?scp=85048231956&partnerID=8YFLogxK

U2 - 10.1134/S0022476618020208

DO - 10.1134/S0022476618020208

M3 - Article

AN - SCOPUS:85048231956

VL - 59

SP - 395

EP - 397

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 2

ER -

ID: 13846156