Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Structure of A Coordination Polymer [Cu(En)2CrO4]n. / Sukhikh, A. S.; Khranenko, S. P.; Gromilov, S. A.
в: Journal of Structural Chemistry, Том 59, № 2, 01.03.2018, стр. 395-397.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Structure of A Coordination Polymer [Cu(En)2CrO4]n
AU - Sukhikh, A. S.
AU - Khranenko, S. P.
AU - Gromilov, S. A.
PY - 2018/3/1
Y1 - 2018/3/1
N2 - The crystal structure of [Cu(En)2CrO4]n (En is ethylenediamine) is determined: a = 14.7359(4) Å, b = 9.8083(3) Å, c = 14.2664(4) Å, V = 2061.98(10) Å3, space group Cmce, Z = 8, dx = 1.931 g/cm3. It is demonstrated that the studied phase is isostructural with [Сu(Еn)2SO4]n. A pseudotetragonal copper atom coordination (Cu–N 2.0204 Å and 2.0244 Å, ∠N–Cu–N 84.73°) is completed to distorted octahedral by two oxygen atoms of chromate anions (Cu–O 2.433 Å and 2.380 Å).
AB - The crystal structure of [Cu(En)2CrO4]n (En is ethylenediamine) is determined: a = 14.7359(4) Å, b = 9.8083(3) Å, c = 14.2664(4) Å, V = 2061.98(10) Å3, space group Cmce, Z = 8, dx = 1.931 g/cm3. It is demonstrated that the studied phase is isostructural with [Сu(Еn)2SO4]n. A pseudotetragonal copper atom coordination (Cu–N 2.0204 Å and 2.0244 Å, ∠N–Cu–N 84.73°) is completed to distorted octahedral by two oxygen atoms of chromate anions (Cu–O 2.433 Å and 2.380 Å).
KW - chromate anion
KW - coordination polyhedron
KW - copper bis-ethylenediamine
KW - crystal chemistry
KW - single crystal X-ray diffraction analysis
UR - http://www.scopus.com/inward/record.url?scp=85048231956&partnerID=8YFLogxK
U2 - 10.1134/S0022476618020208
DO - 10.1134/S0022476618020208
M3 - Article
AN - SCOPUS:85048231956
VL - 59
SP - 395
EP - 397
JO - Journal of Structural Chemistry
JF - Journal of Structural Chemistry
SN - 0022-4766
IS - 2
ER -
ID: 13846156