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Structure and Properties of (C4N2H12)[Pt(NO3)6] Salt. / Vasilchenko, D. B.; Topchiyan, P. A.; Tkachev, S. V. et al.

In: Journal of Structural Chemistry, Vol. 60, No. 8, 01.08.2019, p. 1327-1334.

Research output: Contribution to journal › Article › peer-review

Harvard

Vasilchenko, DB, Topchiyan, PA, Tkachev, SV, Baidina, IA, Korolkov, IV, Filatov, EY & Sheven, DG 2019, 'Structure and Properties of (C4N2H12)[Pt(NO3)6] Salt', Journal of Structural Chemistry, vol. 60, no. 8, pp. 1327-1334. https://doi.org/10.1134/S0022476619080122

APA

Vasilchenko, D. B., Topchiyan, P. A., Tkachev, S. V., Baidina, I. A., Korolkov, I. V., Filatov, E. Y., & Sheven, D. G. (2019). Structure and Properties of (C4N2H12)[Pt(NO3)6] Salt. Journal of Structural Chemistry, 60(8), 1327-1334. https://doi.org/10.1134/S0022476619080122

Vancouver

Vasilchenko DB, Topchiyan PA, Tkachev SV, Baidina IA, Korolkov IV, Filatov EY et al. Structure and Properties of (C4N2H12)[Pt(NO3)6] Salt. Journal of Structural Chemistry. 2019 Aug 1;60(8):1327-1334. doi: 10.1134/S0022476619080122

Author

Vasilchenko, D. B. ; Topchiyan, P. A. ; Tkachev, S. V. et al. / Structure and Properties of (C4N2H12)[Pt(NO3)6] Salt. In: Journal of Structural Chemistry. 2019 ; Vol. 60, No. 8. pp. 1327-1334.

BibTeX

@article{5cecb25da3b44af7a71668cfa70c3674,
title = "Structure and Properties of (C4N2H12)[Pt(NO3)6] Salt",
abstract = "From a nitrate solution of platinum(IV) hydroxide, (C4N2H12)[Pt(N03)6] salt containing a piperazinium cation is isolated. The salt structure is determined by X-ray crystallography. Crystallographic data are: a=15.589(1){\AA}, b= 12.919(1) {\AA}, c = 9.889(9){\AA}, β = 08.625(4)°, space group C2/c, Z=4, ρcalc = 2.306 g/cm3. In the structure, [Pt(NO3)6]2− anions having a shape of a trigonal antiprism are organized into a 3D network by the formation of hydrogen bonds with organic cations. For a series of salts containing [Pt(NO3)6]2− and [Pt2(ώ-OH)2(NO3)8]2− anionic platinum nitrato complexes a relationship between the structure and 195Pt MAS NMR spectra is shown.",
keywords = "MAS NMR, nitrato complexes, piperazine, platinum, X-ray crystallographic analysis, NANOPARTICLES, STATE, PT-195 NMR, CATALYST, PLATINUM(IV)",
author = "Vasilchenko, {D. B.} and Topchiyan, {P. A.} and Tkachev, {S. V.} and Baidina, {I. A.} and Korolkov, {I. V.} and Filatov, {E. Yu} and Sheven, {D. G.}",
year = "2019",
month = aug,
day = "1",
doi = "10.1134/S0022476619080122",
language = "English",
volume = "60",
pages = "1327--1334",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "8",

}

RIS

TY - JOUR

T1 - Structure and Properties of (C4N2H12)[Pt(NO3)6] Salt

AU - Vasilchenko, D. B.

AU - Topchiyan, P. A.

AU - Tkachev, S. V.

AU - Baidina, I. A.

AU - Korolkov, I. V.

AU - Filatov, E. Yu

AU - Sheven, D. G.

PY - 2019/8/1

Y1 - 2019/8/1

N2 - From a nitrate solution of platinum(IV) hydroxide, (C4N2H12)[Pt(N03)6] salt containing a piperazinium cation is isolated. The salt structure is determined by X-ray crystallography. Crystallographic data are: a=15.589(1)Å, b= 12.919(1) Å, c = 9.889(9)Å, β = 08.625(4)°, space group C2/c, Z=4, ρcalc = 2.306 g/cm3. In the structure, [Pt(NO3)6]2− anions having a shape of a trigonal antiprism are organized into a 3D network by the formation of hydrogen bonds with organic cations. For a series of salts containing [Pt(NO3)6]2− and [Pt2(ώ-OH)2(NO3)8]2− anionic platinum nitrato complexes a relationship between the structure and 195Pt MAS NMR spectra is shown.

AB - From a nitrate solution of platinum(IV) hydroxide, (C4N2H12)[Pt(N03)6] salt containing a piperazinium cation is isolated. The salt structure is determined by X-ray crystallography. Crystallographic data are: a=15.589(1)Å, b= 12.919(1) Å, c = 9.889(9)Å, β = 08.625(4)°, space group C2/c, Z=4, ρcalc = 2.306 g/cm3. In the structure, [Pt(NO3)6]2− anions having a shape of a trigonal antiprism are organized into a 3D network by the formation of hydrogen bonds with organic cations. For a series of salts containing [Pt(NO3)6]2− and [Pt2(ώ-OH)2(NO3)8]2− anionic platinum nitrato complexes a relationship between the structure and 195Pt MAS NMR spectra is shown.

KW - MAS NMR

KW - nitrato complexes

KW - piperazine

KW - platinum

KW - X-ray crystallographic analysis

KW - NANOPARTICLES

KW - STATE

KW - PT-195 NMR

KW - CATALYST

KW - PLATINUM(IV)

UR - http://www.scopus.com/inward/record.url?scp=85071941601&partnerID=8YFLogxK

U2 - 10.1134/S0022476619080122

DO - 10.1134/S0022476619080122

M3 - Article

AN - SCOPUS:85071941601

VL - 60

SP - 1327

EP - 1334

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 8

ER -

ID: 21465858