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Structure and Properties of (C4N2H12)[Pt(NO3)6] Salt. / Vasilchenko, D. B.; Topchiyan, P. A.; Tkachev, S. V. и др.
в: Journal of Structural Chemistry, Том 60, № 8, 01.08.2019, стр. 1327-1334.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Structure and Properties of (C4N2H12)[Pt(NO3)6] Salt
AU - Vasilchenko, D. B.
AU - Topchiyan, P. A.
AU - Tkachev, S. V.
AU - Baidina, I. A.
AU - Korolkov, I. V.
AU - Filatov, E. Yu
AU - Sheven, D. G.
PY - 2019/8/1
Y1 - 2019/8/1
N2 - From a nitrate solution of platinum(IV) hydroxide, (C4N2H12)[Pt(N03)6] salt containing a piperazinium cation is isolated. The salt structure is determined by X-ray crystallography. Crystallographic data are: a=15.589(1)Å, b= 12.919(1) Å, c = 9.889(9)Å, β = 08.625(4)°, space group C2/c, Z=4, ρcalc = 2.306 g/cm3. In the structure, [Pt(NO3)6]2− anions having a shape of a trigonal antiprism are organized into a 3D network by the formation of hydrogen bonds with organic cations. For a series of salts containing [Pt(NO3)6]2− and [Pt2(ώ-OH)2(NO3)8]2− anionic platinum nitrato complexes a relationship between the structure and 195Pt MAS NMR spectra is shown.
AB - From a nitrate solution of platinum(IV) hydroxide, (C4N2H12)[Pt(N03)6] salt containing a piperazinium cation is isolated. The salt structure is determined by X-ray crystallography. Crystallographic data are: a=15.589(1)Å, b= 12.919(1) Å, c = 9.889(9)Å, β = 08.625(4)°, space group C2/c, Z=4, ρcalc = 2.306 g/cm3. In the structure, [Pt(NO3)6]2− anions having a shape of a trigonal antiprism are organized into a 3D network by the formation of hydrogen bonds with organic cations. For a series of salts containing [Pt(NO3)6]2− and [Pt2(ώ-OH)2(NO3)8]2− anionic platinum nitrato complexes a relationship between the structure and 195Pt MAS NMR spectra is shown.
KW - MAS NMR
KW - nitrato complexes
KW - piperazine
KW - platinum
KW - X-ray crystallographic analysis
KW - NANOPARTICLES
KW - STATE
KW - PT-195 NMR
KW - CATALYST
KW - PLATINUM(IV)
UR - http://www.scopus.com/inward/record.url?scp=85071941601&partnerID=8YFLogxK
U2 - 10.1134/S0022476619080122
DO - 10.1134/S0022476619080122
M3 - Article
AN - SCOPUS:85071941601
VL - 60
SP - 1327
EP - 1334
JO - Journal of Structural Chemistry
JF - Journal of Structural Chemistry
SN - 0022-4766
IS - 8
ER -
ID: 21465858