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Structural investigation of salts containing ions [Pd(NH3)4]2+ and [IrF6]2–. / Gubanov, A. I.; Danilenko, A. M.; Smolentsev, A. I. et al.

In: Journal of Structural Chemistry, Vol. 57, No. 8, 01.12.2016, p. 1606-1612.

Research output: Contribution to journal › Article › peer-review

Harvard

Gubanov, AI, Danilenko, AM, Smolentsev, AI, Kuratieva, NV, Venediktov, AB & Korenev, SV 2016, 'Structural investigation of salts containing ions [Pd(NH3)4]2+ and [IrF6]2–', Journal of Structural Chemistry, vol. 57, no. 8, pp. 1606-1612. https://doi.org/10.1134/S0022476616080175

APA

Gubanov, A. I., Danilenko, A. M., Smolentsev, A. I., Kuratieva, N. V., Venediktov, A. B., & Korenev, S. V. (2016). Structural investigation of salts containing ions [Pd(NH3)4]2+ and [IrF6]2–. Journal of Structural Chemistry, 57(8), 1606-1612. https://doi.org/10.1134/S0022476616080175

Vancouver

Gubanov AI, Danilenko AM, Smolentsev AI, Kuratieva NV, Venediktov AB, Korenev SV. Structural investigation of salts containing ions [Pd(NH3)4]2+ and [IrF6]2–. Journal of Structural Chemistry. 2016 Dec 1;57(8):1606-1612. doi: 10.1134/S0022476616080175

Author

Gubanov, A. I. ; Danilenko, A. M. ; Smolentsev, A. I. et al. / Structural investigation of salts containing ions [Pd(NH3)4]2+ and [IrF6]2–. In: Journal of Structural Chemistry. 2016 ; Vol. 57, No. 8. pp. 1606-1612.

BibTeX

@article{a07164d8313c4b5d85b52cc5ba9ce0f0,
title = "Structural investigation of salts containing ions [Pd(NH3)4]2+ and [IrF6]2–",
abstract = "Double complex salts (DCS) α-[Pd(NH3)4][IrF6]·H2O (P21/m, a = 6.3181(3) {\AA}, b = 10.8718(5) {\AA}, с = 7.4526(4) {\AA}, β = 103.568(2)°), β-[Pd(NH3)4][IrF6]·H2O (P21/с, a = 8.5773(3) {\AA}, b = 10.8791(4) {\AA}, с = = 12.6741(3) {\AA}, β = 122.497(2)°), [Pd(NH3)4]3[IrF6]2Cl2·H2O (P-1, a = 7.6080(2) {\AA}, b = 7.6274(2) {\AA}, с = 11.8070(3) {\AA}, β = 122.497(2)°), and [Pd(NH3)4]2[IrF6]NO3 (Fm-3m, a = 11.21210(10) {\AA}) have been synthesized and structurally characterized for the first time. The existence of polymorphs for the DCS has been revealed. The influence of the chemical composition of the initial reagents on the reaction course and, respectively, the products, has been demonstrated. A hypothesis on the influence of the second coordination sphere on the formation of one or the other polymorph of the DCS has been suggested. It has been shown that the series α-[Pd(NH3)4][МF6]·H2O (M = Pt, Pd) exhibits isostructurality.",
keywords = "coordination compounds, crystal structure, double complex salts, fluoride complexes, iridium, palladium, synthesis",
author = "Gubanov, {A. I.} and Danilenko, {A. M.} and Smolentsev, {A. I.} and Kuratieva, {N. V.} and Venediktov, {A. B.} and Korenev, {S. V.}",
year = "2016",
month = dec,
day = "1",
doi = "10.1134/S0022476616080175",
language = "English",
volume = "57",
pages = "1606--1612",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "8",

}

RIS

TY - JOUR

T1 - Structural investigation of salts containing ions [Pd(NH3)4]2+ and [IrF6]2–

AU - Gubanov, A. I.

AU - Danilenko, A. M.

AU - Smolentsev, A. I.

AU - Kuratieva, N. V.

AU - Venediktov, A. B.

AU - Korenev, S. V.

PY - 2016/12/1

Y1 - 2016/12/1

N2 - Double complex salts (DCS) α-[Pd(NH3)4][IrF6]·H2O (P21/m, a = 6.3181(3) Å, b = 10.8718(5) Å, с = 7.4526(4) Å, β = 103.568(2)°), β-[Pd(NH3)4][IrF6]·H2O (P21/с, a = 8.5773(3) Å, b = 10.8791(4) Å, с = = 12.6741(3) Å, β = 122.497(2)°), [Pd(NH3)4]3[IrF6]2Cl2·H2O (P-1, a = 7.6080(2) Å, b = 7.6274(2) Å, с = 11.8070(3) Å, β = 122.497(2)°), and [Pd(NH3)4]2[IrF6]NO3 (Fm-3m, a = 11.21210(10) Å) have been synthesized and structurally characterized for the first time. The existence of polymorphs for the DCS has been revealed. The influence of the chemical composition of the initial reagents on the reaction course and, respectively, the products, has been demonstrated. A hypothesis on the influence of the second coordination sphere on the formation of one or the other polymorph of the DCS has been suggested. It has been shown that the series α-[Pd(NH3)4][МF6]·H2O (M = Pt, Pd) exhibits isostructurality.

AB - Double complex salts (DCS) α-[Pd(NH3)4][IrF6]·H2O (P21/m, a = 6.3181(3) Å, b = 10.8718(5) Å, с = 7.4526(4) Å, β = 103.568(2)°), β-[Pd(NH3)4][IrF6]·H2O (P21/с, a = 8.5773(3) Å, b = 10.8791(4) Å, с = = 12.6741(3) Å, β = 122.497(2)°), [Pd(NH3)4]3[IrF6]2Cl2·H2O (P-1, a = 7.6080(2) Å, b = 7.6274(2) Å, с = 11.8070(3) Å, β = 122.497(2)°), and [Pd(NH3)4]2[IrF6]NO3 (Fm-3m, a = 11.21210(10) Å) have been synthesized and structurally characterized for the first time. The existence of polymorphs for the DCS has been revealed. The influence of the chemical composition of the initial reagents on the reaction course and, respectively, the products, has been demonstrated. A hypothesis on the influence of the second coordination sphere on the formation of one or the other polymorph of the DCS has been suggested. It has been shown that the series α-[Pd(NH3)4][МF6]·H2O (M = Pt, Pd) exhibits isostructurality.

KW - coordination compounds

KW - crystal structure

KW - double complex salts

KW - fluoride complexes

KW - iridium

KW - palladium

KW - synthesis

UR - http://www.scopus.com/inward/record.url?scp=85009953975&partnerID=8YFLogxK

U2 - 10.1134/S0022476616080175

DO - 10.1134/S0022476616080175

M3 - Article

AN - SCOPUS:85009953975

VL - 57

SP - 1606

EP - 1612

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 8

ER -

ID: 25401349