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Structural diversity of zinc(ii) coordination polymers with octafluorobiphenyl-4,4′-dicarboxylate based on mononuclear, paddle wheel and cuboidal units. / Cheplakova, Anastasia M.; Kovalenko, Konstantin A.; Samsonenko, Denis G. et al.

In: CrystEngComm, Vol. 21, No. 15, 01.01.2019, p. 2524-2533.

Research output: Contribution to journal › Article › peer-review

Harvard

Cheplakova, AM, Kovalenko, KA, Samsonenko, DG, Vinogradov, AS, Karpov, VM, Platonov, VE & Fedin, VP 2019, 'Structural diversity of zinc(ii) coordination polymers with octafluorobiphenyl-4,4′-dicarboxylate based on mononuclear, paddle wheel and cuboidal units', CrystEngComm, vol. 21, no. 15, pp. 2524-2533. https://doi.org/10.1039/c9ce00073a

APA

Cheplakova, A. M., Kovalenko, K. A., Samsonenko, D. G., Vinogradov, A. S., Karpov, V. M., Platonov, V. E., & Fedin, V. P. (2019). Structural diversity of zinc(ii) coordination polymers with octafluorobiphenyl-4,4′-dicarboxylate based on mononuclear, paddle wheel and cuboidal units. CrystEngComm, 21(15), 2524-2533. https://doi.org/10.1039/c9ce00073a

Vancouver

Cheplakova AM, Kovalenko KA, Samsonenko DG, Vinogradov AS, Karpov VM, Platonov VE et al. Structural diversity of zinc(ii) coordination polymers with octafluorobiphenyl-4,4′-dicarboxylate based on mononuclear, paddle wheel and cuboidal units. CrystEngComm. 2019 Jan 1;21(15):2524-2533. doi: 10.1039/c9ce00073a

Author

Cheplakova, Anastasia M. ; Kovalenko, Konstantin A. ; Samsonenko, Denis G. et al. / Structural diversity of zinc(ii) coordination polymers with octafluorobiphenyl-4,4′-dicarboxylate based on mononuclear, paddle wheel and cuboidal units. In: CrystEngComm. 2019 ; Vol. 21, No. 15. pp. 2524-2533.

BibTeX

@article{b25d9a3b02d8480880ae258768111d3c,
title = "Structural diversity of zinc(ii) coordination polymers with octafluorobiphenyl-4,4′-dicarboxylate based on mononuclear, paddle wheel and cuboidal units",
abstract = " We present a series of six novel Zn(ii) complexes containing anions of perfluorinated biphenyl-4,4′-dicarboxylate (oFBPDC 2− ). Among them are the 0D complex [Zn(eg) 3 ](oFBPDC) (eg = ethylene glycol), the 1D [Zn(H 2 O)(ur)(oFBPDC)] (ur = urotropine) and [Zn(CH 3 OH) 2 (CH 3 OCH 2 CH 2 OH)(oFBPDC)] and the 2D layered [Zn 2 (CH 3 CN) 2 (oFBPDC) 2 ]·2C 6 H 6 ·2CH 3 CN, [Zn 2 (H 2 O) 2 (oFBPDC) 2 ]·4(CH 3 ) 2 CO, [{Zn 4 (μ 3 -OCH 3 ) 4 }(CH 3 OH) 4 (oFBPDC) 2 ]·[{Zn 4 (μ 3 -OCH 3 ) 4 }(H 2 O)(CH 3 OH) 3 (oFBPDC) 2 ]·13CH 3 OH. The latter coordination polymer is built up by unique Zn 4 (OCH 3 ) 4 cuboidal units. The complexes are characterized by single-crystal X-ray diffraction, FT-IR, elemental analysis, and TGA. Investigation of the CO 2 adsorption at 195 K on [Zn 2 (CH 3 CN) 2 (oFBPDC) 2 ] and [Zn 2 (H 2 O) 2 (oFBPDC) 2 ] of the layered polymeric structure revealed that they have BET surface areas of 334.8 and 150.6 m 2 g −1 , respectively. ",
keywords = "METAL-ORGANIC FRAMEWORKS, CRYSTAL-STRUCTURE, FLUORINE, DESIGN",
author = "Cheplakova, {Anastasia M.} and Kovalenko, {Konstantin A.} and Samsonenko, {Denis G.} and Vinogradov, {Andrey S.} and Karpov, {Victor M.} and Platonov, {Vyacheslav E.} and Fedin, {Vladimir P.}",
year = "2019",
month = jan,
day = "1",
doi = "10.1039/c9ce00073a",
language = "English",
volume = "21",
pages = "2524--2533",
journal = "CrystEngComm",
issn = "1466-8033",
publisher = "Royal Society of Chemistry",
number = "15",

}

RIS

TY - JOUR

T1 - Structural diversity of zinc(ii) coordination polymers with octafluorobiphenyl-4,4′-dicarboxylate based on mononuclear, paddle wheel and cuboidal units

AU - Cheplakova, Anastasia M.

AU - Kovalenko, Konstantin A.

AU - Samsonenko, Denis G.

AU - Vinogradov, Andrey S.

AU - Karpov, Victor M.

AU - Platonov, Vyacheslav E.

AU - Fedin, Vladimir P.

PY - 2019/1/1

Y1 - 2019/1/1

N2 - We present a series of six novel Zn(ii) complexes containing anions of perfluorinated biphenyl-4,4′-dicarboxylate (oFBPDC 2− ). Among them are the 0D complex [Zn(eg) 3 ](oFBPDC) (eg = ethylene glycol), the 1D [Zn(H 2 O)(ur)(oFBPDC)] (ur = urotropine) and [Zn(CH 3 OH) 2 (CH 3 OCH 2 CH 2 OH)(oFBPDC)] and the 2D layered [Zn 2 (CH 3 CN) 2 (oFBPDC) 2 ]·2C 6 H 6 ·2CH 3 CN, [Zn 2 (H 2 O) 2 (oFBPDC) 2 ]·4(CH 3 ) 2 CO, [{Zn 4 (μ 3 -OCH 3 ) 4 }(CH 3 OH) 4 (oFBPDC) 2 ]·[{Zn 4 (μ 3 -OCH 3 ) 4 }(H 2 O)(CH 3 OH) 3 (oFBPDC) 2 ]·13CH 3 OH. The latter coordination polymer is built up by unique Zn 4 (OCH 3 ) 4 cuboidal units. The complexes are characterized by single-crystal X-ray diffraction, FT-IR, elemental analysis, and TGA. Investigation of the CO 2 adsorption at 195 K on [Zn 2 (CH 3 CN) 2 (oFBPDC) 2 ] and [Zn 2 (H 2 O) 2 (oFBPDC) 2 ] of the layered polymeric structure revealed that they have BET surface areas of 334.8 and 150.6 m 2 g −1 , respectively.

AB - We present a series of six novel Zn(ii) complexes containing anions of perfluorinated biphenyl-4,4′-dicarboxylate (oFBPDC 2− ). Among them are the 0D complex [Zn(eg) 3 ](oFBPDC) (eg = ethylene glycol), the 1D [Zn(H 2 O)(ur)(oFBPDC)] (ur = urotropine) and [Zn(CH 3 OH) 2 (CH 3 OCH 2 CH 2 OH)(oFBPDC)] and the 2D layered [Zn 2 (CH 3 CN) 2 (oFBPDC) 2 ]·2C 6 H 6 ·2CH 3 CN, [Zn 2 (H 2 O) 2 (oFBPDC) 2 ]·4(CH 3 ) 2 CO, [{Zn 4 (μ 3 -OCH 3 ) 4 }(CH 3 OH) 4 (oFBPDC) 2 ]·[{Zn 4 (μ 3 -OCH 3 ) 4 }(H 2 O)(CH 3 OH) 3 (oFBPDC) 2 ]·13CH 3 OH. The latter coordination polymer is built up by unique Zn 4 (OCH 3 ) 4 cuboidal units. The complexes are characterized by single-crystal X-ray diffraction, FT-IR, elemental analysis, and TGA. Investigation of the CO 2 adsorption at 195 K on [Zn 2 (CH 3 CN) 2 (oFBPDC) 2 ] and [Zn 2 (H 2 O) 2 (oFBPDC) 2 ] of the layered polymeric structure revealed that they have BET surface areas of 334.8 and 150.6 m 2 g −1 , respectively.

KW - METAL-ORGANIC FRAMEWORKS

KW - CRYSTAL-STRUCTURE

KW - FLUORINE

KW - DESIGN

UR - http://www.scopus.com/inward/record.url?scp=85064081008&partnerID=8YFLogxK

U2 - 10.1039/c9ce00073a

DO - 10.1039/c9ce00073a

M3 - Article

AN - SCOPUS:85064081008

VL - 21

SP - 2524

EP - 2533

JO - CrystEngComm

JF - CrystEngComm

SN - 1466-8033

IS - 15

ER -

ID: 19342295