Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Structural diversity of zinc(ii) coordination polymers with octafluorobiphenyl-4,4′-dicarboxylate based on mononuclear, paddle wheel and cuboidal units. / Cheplakova, Anastasia M.; Kovalenko, Konstantin A.; Samsonenko, Denis G. и др.
в: CrystEngComm, Том 21, № 15, 01.01.2019, стр. 2524-2533.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Structural diversity of zinc(ii) coordination polymers with octafluorobiphenyl-4,4′-dicarboxylate based on mononuclear, paddle wheel and cuboidal units
AU - Cheplakova, Anastasia M.
AU - Kovalenko, Konstantin A.
AU - Samsonenko, Denis G.
AU - Vinogradov, Andrey S.
AU - Karpov, Victor M.
AU - Platonov, Vyacheslav E.
AU - Fedin, Vladimir P.
PY - 2019/1/1
Y1 - 2019/1/1
N2 - We present a series of six novel Zn(ii) complexes containing anions of perfluorinated biphenyl-4,4′-dicarboxylate (oFBPDC 2− ). Among them are the 0D complex [Zn(eg) 3 ](oFBPDC) (eg = ethylene glycol), the 1D [Zn(H 2 O)(ur)(oFBPDC)] (ur = urotropine) and [Zn(CH 3 OH) 2 (CH 3 OCH 2 CH 2 OH)(oFBPDC)] and the 2D layered [Zn 2 (CH 3 CN) 2 (oFBPDC) 2 ]·2C 6 H 6 ·2CH 3 CN, [Zn 2 (H 2 O) 2 (oFBPDC) 2 ]·4(CH 3 ) 2 CO, [{Zn 4 (μ 3 -OCH 3 ) 4 }(CH 3 OH) 4 (oFBPDC) 2 ]·[{Zn 4 (μ 3 -OCH 3 ) 4 }(H 2 O)(CH 3 OH) 3 (oFBPDC) 2 ]·13CH 3 OH. The latter coordination polymer is built up by unique Zn 4 (OCH 3 ) 4 cuboidal units. The complexes are characterized by single-crystal X-ray diffraction, FT-IR, elemental analysis, and TGA. Investigation of the CO 2 adsorption at 195 K on [Zn 2 (CH 3 CN) 2 (oFBPDC) 2 ] and [Zn 2 (H 2 O) 2 (oFBPDC) 2 ] of the layered polymeric structure revealed that they have BET surface areas of 334.8 and 150.6 m 2 g −1 , respectively.
AB - We present a series of six novel Zn(ii) complexes containing anions of perfluorinated biphenyl-4,4′-dicarboxylate (oFBPDC 2− ). Among them are the 0D complex [Zn(eg) 3 ](oFBPDC) (eg = ethylene glycol), the 1D [Zn(H 2 O)(ur)(oFBPDC)] (ur = urotropine) and [Zn(CH 3 OH) 2 (CH 3 OCH 2 CH 2 OH)(oFBPDC)] and the 2D layered [Zn 2 (CH 3 CN) 2 (oFBPDC) 2 ]·2C 6 H 6 ·2CH 3 CN, [Zn 2 (H 2 O) 2 (oFBPDC) 2 ]·4(CH 3 ) 2 CO, [{Zn 4 (μ 3 -OCH 3 ) 4 }(CH 3 OH) 4 (oFBPDC) 2 ]·[{Zn 4 (μ 3 -OCH 3 ) 4 }(H 2 O)(CH 3 OH) 3 (oFBPDC) 2 ]·13CH 3 OH. The latter coordination polymer is built up by unique Zn 4 (OCH 3 ) 4 cuboidal units. The complexes are characterized by single-crystal X-ray diffraction, FT-IR, elemental analysis, and TGA. Investigation of the CO 2 adsorption at 195 K on [Zn 2 (CH 3 CN) 2 (oFBPDC) 2 ] and [Zn 2 (H 2 O) 2 (oFBPDC) 2 ] of the layered polymeric structure revealed that they have BET surface areas of 334.8 and 150.6 m 2 g −1 , respectively.
KW - METAL-ORGANIC FRAMEWORKS
KW - CRYSTAL-STRUCTURE
KW - FLUORINE
KW - DESIGN
UR - http://www.scopus.com/inward/record.url?scp=85064081008&partnerID=8YFLogxK
U2 - 10.1039/c9ce00073a
DO - 10.1039/c9ce00073a
M3 - Article
AN - SCOPUS:85064081008
VL - 21
SP - 2524
EP - 2533
JO - CrystEngComm
JF - CrystEngComm
SN - 1466-8033
IS - 15
ER -
ID: 19342295