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Structural and morphological properties of Ce1–xMxOy (M = Gd, La, Mg) supports for the catalysts of autothermal ethanol conversion. / Kerzhentsev, M. A.; Matus, E. V.; Ismagilov, I. Z. et al.

In: Journal of Structural Chemistry, Vol. 58, No. 1, 01.01.2017, p. 126-134.

Research output: Contribution to journal › Article › peer-review

Harvard

Kerzhentsev, MA, Matus, EV, Ismagilov, IZ, Ushakov, VA, Stonkus, OA, Larina, TV, Kozlova, GS, Bharali, P & Ismagilov, ZR 2017, 'Structural and morphological properties of Ce1–xMxOy (M = Gd, La, Mg) supports for the catalysts of autothermal ethanol conversion', Journal of Structural Chemistry, vol. 58, no. 1, pp. 126-134. https://doi.org/10.1134/S002247661701019X

APA

Kerzhentsev, M. A., Matus, E. V., Ismagilov, I. Z., Ushakov, V. A., Stonkus, O. A., Larina, T. V., Kozlova, G. S., Bharali, P., & Ismagilov, Z. R. (2017). Structural and morphological properties of Ce1–xMxOy (M = Gd, La, Mg) supports for the catalysts of autothermal ethanol conversion. Journal of Structural Chemistry, 58(1), 126-134. https://doi.org/10.1134/S002247661701019X

Vancouver

Kerzhentsev MA, Matus EV, Ismagilov IZ, Ushakov VA, Stonkus OA, Larina TV et al. Structural and morphological properties of Ce1–xMxOy (M = Gd, La, Mg) supports for the catalysts of autothermal ethanol conversion. Journal of Structural Chemistry. 2017 Jan 1;58(1):126-134. doi: 10.1134/S002247661701019X

Author

Kerzhentsev, M. A. ; Matus, E. V. ; Ismagilov, I. Z. et al. / Structural and morphological properties of Ce1–xMxOy (M = Gd, La, Mg) supports for the catalysts of autothermal ethanol conversion. In: Journal of Structural Chemistry. 2017 ; Vol. 58, No. 1. pp. 126-134.

BibTeX

@article{17b82e6d781d4c3c9386bf34294381c5,
title = "Structural and morphological properties of Ce1–xMxOy (M = Gd, La, Mg) supports for the catalysts of autothermal ethanol conversion",
abstract = "A complex of physicochemical methods (powder XRD analysis, transmission and scanning electron microscopy, electron spectroscopy of diffuse reflectance, low-temperature nitrogen adsorption) is used for the comparative study of structural and morphological properties of oxide supports Ce1–xMxOy (M = Gd, La, Mg; x = 0-0.5; 1.5 ≤ y ≤ 2.0) for catalysts for the autothermal reforming of bioethanol to a hydrogen-bearing gas. It is shown that Ce1–xMxOy samples synthesized by the method of ester polymer precursors are mesoporous materials being the homogenous substitutional solid solutions with the fluorite-type cubic structure. The structural and textural properties of the Ce1–xMxOy materials are regulated by varying the type of the dopant cation (M = Gd, La, Mg), the molar ratio M/Ce (0, 0.1, 0.25, 1), and heat treatment conditions (temperature 300-800 °C; duration 4-24 h). The relationship between the synthesis parameters and the characteristics of the Ce1–xMxOy materials is found.",
keywords = "cerium dioxide, dopants, electron microscopy, electron spectroscopy of diffuse reflectance, nanomaterials, powder XRD analysis, OXIDE, SOLID-SOLUTIONS, CERIA, HYDROGEN-PRODUCTION, NI",
author = "Kerzhentsev, {M. A.} and Matus, {E. V.} and Ismagilov, {I. Z.} and Ushakov, {V. A.} and Stonkus, {O. A.} and Larina, {T. V.} and Kozlova, {G. S.} and P. Bharali and Ismagilov, {Z. R.}",
year = "2017",
month = jan,
day = "1",
doi = "10.1134/S002247661701019X",
language = "English",
volume = "58",
pages = "126--134",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "1",

}

RIS

TY - JOUR

T1 - Structural and morphological properties of Ce1–xMxOy (M = Gd, La, Mg) supports for the catalysts of autothermal ethanol conversion

AU - Kerzhentsev, M. A.

AU - Matus, E. V.

AU - Ismagilov, I. Z.

AU - Ushakov, V. A.

AU - Stonkus, O. A.

AU - Larina, T. V.

AU - Kozlova, G. S.

AU - Bharali, P.

AU - Ismagilov, Z. R.

PY - 2017/1/1

Y1 - 2017/1/1

N2 - A complex of physicochemical methods (powder XRD analysis, transmission and scanning electron microscopy, electron spectroscopy of diffuse reflectance, low-temperature nitrogen adsorption) is used for the comparative study of structural and morphological properties of oxide supports Ce1–xMxOy (M = Gd, La, Mg; x = 0-0.5; 1.5 ≤ y ≤ 2.0) for catalysts for the autothermal reforming of bioethanol to a hydrogen-bearing gas. It is shown that Ce1–xMxOy samples synthesized by the method of ester polymer precursors are mesoporous materials being the homogenous substitutional solid solutions with the fluorite-type cubic structure. The structural and textural properties of the Ce1–xMxOy materials are regulated by varying the type of the dopant cation (M = Gd, La, Mg), the molar ratio M/Ce (0, 0.1, 0.25, 1), and heat treatment conditions (temperature 300-800 °C; duration 4-24 h). The relationship between the synthesis parameters and the characteristics of the Ce1–xMxOy materials is found.

AB - A complex of physicochemical methods (powder XRD analysis, transmission and scanning electron microscopy, electron spectroscopy of diffuse reflectance, low-temperature nitrogen adsorption) is used for the comparative study of structural and morphological properties of oxide supports Ce1–xMxOy (M = Gd, La, Mg; x = 0-0.5; 1.5 ≤ y ≤ 2.0) for catalysts for the autothermal reforming of bioethanol to a hydrogen-bearing gas. It is shown that Ce1–xMxOy samples synthesized by the method of ester polymer precursors are mesoporous materials being the homogenous substitutional solid solutions with the fluorite-type cubic structure. The structural and textural properties of the Ce1–xMxOy materials are regulated by varying the type of the dopant cation (M = Gd, La, Mg), the molar ratio M/Ce (0, 0.1, 0.25, 1), and heat treatment conditions (temperature 300-800 °C; duration 4-24 h). The relationship between the synthesis parameters and the characteristics of the Ce1–xMxOy materials is found.

KW - cerium dioxide

KW - dopants

KW - electron microscopy

KW - electron spectroscopy of diffuse reflectance

KW - nanomaterials

KW - powder XRD analysis

KW - OXIDE

KW - SOLID-SOLUTIONS

KW - CERIA

KW - HYDROGEN-PRODUCTION

KW - NI

UR - http://www.scopus.com/inward/record.url?scp=85016069887&partnerID=8YFLogxK

U2 - 10.1134/S002247661701019X

DO - 10.1134/S002247661701019X

M3 - Article

AN - SCOPUS:85016069887

VL - 58

SP - 126

EP - 134

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 1

ER -

ID: 10271017