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Steam reforming of dimethoxymethane, methanol and dimethyl ether on CuO–ZnO/Γ-Al2O3 catalyst. / Pechenkin, A. A.; Badmaev, S. D.; Belyaev, V. D. et al.

In: Kinetics and Catalysis, Vol. 58, No. 5, 09.2017, p. 577-584.

Research output: Contribution to journal › Article › peer-review

Harvard

Pechenkin, AA, Badmaev, SD, Belyaev, VD, Paukshtis, EA, Stonkus, OA & Sobyanin, VA 2017, 'Steam reforming of dimethoxymethane, methanol and dimethyl ether on CuO–ZnO/Γ-Al2O3 catalyst', Kinetics and Catalysis, vol. 58, no. 5, pp. 577-584. https://doi.org/10.1134/S0023158417050196

APA

Pechenkin, A. A., Badmaev, S. D., Belyaev, V. D., Paukshtis, E. A., Stonkus, O. A., & Sobyanin, V. A. (2017). Steam reforming of dimethoxymethane, methanol and dimethyl ether on CuO–ZnO/Γ-Al2O3 catalyst. Kinetics and Catalysis, 58(5), 577-584. https://doi.org/10.1134/S0023158417050196

Vancouver

Pechenkin AA, Badmaev SD, Belyaev VD, Paukshtis EA, Stonkus OA, Sobyanin VA. Steam reforming of dimethoxymethane, methanol and dimethyl ether on CuO–ZnO/Γ-Al2O3 catalyst. Kinetics and Catalysis. 2017 Sept;58(5):577-584. doi: 10.1134/S0023158417050196

Author

Pechenkin, A. A. ; Badmaev, S. D. ; Belyaev, V. D. et al. / Steam reforming of dimethoxymethane, methanol and dimethyl ether on CuO–ZnO/Γ-Al2O3 catalyst. In: Kinetics and Catalysis. 2017 ; Vol. 58, No. 5. pp. 577-584.

BibTeX

@article{e6ff76d740ee4471a3fa41bea775877a,
title = "Steam reforming of dimethoxymethane, methanol and dimethyl ether on CuO–ZnO/Γ-Al2O3 catalyst",
abstract = "The performance of a СuO–ZnO/γ-Al2O3 catalyst for the reactions of methanol, dimethyl ether (DME) and dimethoxymethane (DMM) steam reforming (SR) to hydrogen-rich gas was studied. The catalyst was found to be active and selective for methanol and DMM SR producing hydrogen-rich gas with low content of CO (<1 vol %). It provided complete conversion of methanol and DMM at 300°C, and hydrogen productivity of, respectively, 15 and 16.5 LH2gcat -1h-1. With the use of physicochemical methods and catalytic experiments, it was shown that the catalyst surface contained the acid sites typical for γ-Al2O3, and CuO–ZnO agglomerates, responsible, respectively, for DMM hydration to methanol and formaldehyde, and SR of these compounds to hydrogen-rich gas.",
keywords = "copper-zinc catalysts, dimethyl ether, dimetoxymethane, fuel cells, hydrogen, methanol, steam reforming, PERFORMANCE, COPPER, CO, HYDROGEN-RICH GAS, METHANATION, BIFUNCTIONAL CATALYSTS, FUEL-CELL APPLICATIONS, CU-BASED CATALYSTS",
author = "Pechenkin, {A. A.} and Badmaev, {S. D.} and Belyaev, {V. D.} and Paukshtis, {E. A.} and Stonkus, {O. A.} and Sobyanin, {V. A.}",
note = "Publisher Copyright: {\textcopyright} 2017, Pleiades Publishing, Ltd.",
year = "2017",
month = sep,
doi = "10.1134/S0023158417050196",
language = "English",
volume = "58",
pages = "577--584",
journal = "Kinetics and Catalysis",
issn = "0023-1584",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "5",

}

RIS

TY - JOUR

T1 - Steam reforming of dimethoxymethane, methanol and dimethyl ether on CuO–ZnO/Γ-Al2O3 catalyst

AU - Pechenkin, A. A.

AU - Badmaev, S. D.

AU - Belyaev, V. D.

AU - Paukshtis, E. A.

AU - Stonkus, O. A.

AU - Sobyanin, V. A.

N1 - Publisher Copyright: © 2017, Pleiades Publishing, Ltd.

PY - 2017/9

Y1 - 2017/9

N2 - The performance of a СuO–ZnO/γ-Al2O3 catalyst for the reactions of methanol, dimethyl ether (DME) and dimethoxymethane (DMM) steam reforming (SR) to hydrogen-rich gas was studied. The catalyst was found to be active and selective for methanol and DMM SR producing hydrogen-rich gas with low content of CO (<1 vol %). It provided complete conversion of methanol and DMM at 300°C, and hydrogen productivity of, respectively, 15 and 16.5 LH2gcat -1h-1. With the use of physicochemical methods and catalytic experiments, it was shown that the catalyst surface contained the acid sites typical for γ-Al2O3, and CuO–ZnO agglomerates, responsible, respectively, for DMM hydration to methanol and formaldehyde, and SR of these compounds to hydrogen-rich gas.

AB - The performance of a СuO–ZnO/γ-Al2O3 catalyst for the reactions of methanol, dimethyl ether (DME) and dimethoxymethane (DMM) steam reforming (SR) to hydrogen-rich gas was studied. The catalyst was found to be active and selective for methanol and DMM SR producing hydrogen-rich gas with low content of CO (<1 vol %). It provided complete conversion of methanol and DMM at 300°C, and hydrogen productivity of, respectively, 15 and 16.5 LH2gcat -1h-1. With the use of physicochemical methods and catalytic experiments, it was shown that the catalyst surface contained the acid sites typical for γ-Al2O3, and CuO–ZnO agglomerates, responsible, respectively, for DMM hydration to methanol and formaldehyde, and SR of these compounds to hydrogen-rich gas.

KW - copper-zinc catalysts

KW - dimethyl ether

KW - dimetoxymethane

KW - fuel cells

KW - hydrogen

KW - methanol

KW - steam reforming

KW - PERFORMANCE

KW - COPPER

KW - CO

KW - HYDROGEN-RICH GAS

KW - METHANATION

KW - BIFUNCTIONAL CATALYSTS

KW - FUEL-CELL APPLICATIONS

KW - CU-BASED CATALYSTS

UR - http://www.scopus.com/inward/record.url?scp=85030649433&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/3be177b3-86bf-3af4-9986-cf54a4ee1b0f/

U2 - 10.1134/S0023158417050196

DO - 10.1134/S0023158417050196

M3 - Article

AN - SCOPUS:85030649433

VL - 58

SP - 577

EP - 584

JO - Kinetics and Catalysis

JF - Kinetics and Catalysis

SN - 0023-1584

IS - 5

ER -

ID: 10067809