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Spin-crossover in iron(II) complexes with tris(pyrazol-1-yl)methane and сluster anions [{W 6 X 8 }X 6 ] 2– (X = Cl, Br, I). / Shakirova, O. G.; Korotaev, E. V.; Evtushok, D. V. et al.

In: Journal of Molecular Structure, Vol. 1193, 05.10.2019, p. 1-6.

Research output: Contribution to journal › Article › peer-review

Harvard

Shakirova, OG, Korotaev, EV, Evtushok, DV, Kuratieva, NV, Sheludyakova, LA, Shestopalov, MA & Lavrenova, LG 2019, 'Spin-crossover in iron(II) complexes with tris(pyrazol-1-yl)methane and сluster anions [{W 6 X 8 }X 6 ] 2– (X = Cl, Br, I)', Journal of Molecular Structure, vol. 1193, pp. 1-6. https://doi.org/10.1016/j.molstruc.2019.03.015

APA

Shakirova, O. G., Korotaev, E. V., Evtushok, D. V., Kuratieva, N. V., Sheludyakova, L. A., Shestopalov, M. A., & Lavrenova, L. G. (2019). Spin-crossover in iron(II) complexes with tris(pyrazol-1-yl)methane and сluster anions [{W 6 X 8 }X 6 ] 2– (X = Cl, Br, I). Journal of Molecular Structure, 1193, 1-6. https://doi.org/10.1016/j.molstruc.2019.03.015

Vancouver

Shakirova OG, Korotaev EV, Evtushok DV, Kuratieva NV, Sheludyakova LA, Shestopalov MA et al. Spin-crossover in iron(II) complexes with tris(pyrazol-1-yl)methane and сluster anions [{W 6 X 8 }X 6 ] 2– (X = Cl, Br, I). Journal of Molecular Structure. 2019 Oct 5;1193:1-6. doi: 10.1016/j.molstruc.2019.03.015

Author

Shakirova, O. G. ; Korotaev, E. V. ; Evtushok, D. V. et al. / Spin-crossover in iron(II) complexes with tris(pyrazol-1-yl)methane and сluster anions [{W 6 X 8 }X 6 ] 2– (X = Cl, Br, I). In: Journal of Molecular Structure. 2019 ; Vol. 1193. pp. 1-6.

BibTeX

@article{96d3b24d9f1945f5b36cc5ff2ba79970,
title = "Spin-crossover in iron(II) complexes with tris(pyrazol-1-yl)methane and сluster anions [{W 6 X 8 }X 6 ] 2– (X = Cl, Br, I)",
abstract = " Iron(II) complexes with tris(pyrazol-1-yl)methane (HC(pz) 3 ) and cluster anions [{W 6 X 8 }X 6 ] 2– (X = Cl, Br, I) of the composition [Fe(HC(pz) 3 ) 2 ][{W 6 X 8 }X 6 ]⋅2H 2 O ((1–3)⋅2H 2 O) were synthesized. The compounds were characterized by element analysis, single-crystal and powder X-ray diffraction measurements, infrared, diffuse reflectance spectroscopy and static magnetic susceptibility. The temperature dependence μ eff (T) shows that the high-temperature spin-crossover (SCO) 1 A 1g ↔ 5 T 2g is observed in both hydrates (1–3)·2H 2 O and dehydrated compounds (1–3). SCO is accompanied by thermochromism. ",
keywords = "Cluster anion, Complex, Crystal structure, Iron(II), Spin-crossover, Synthesis, Thermochromism, tris(pyrazol-1-yl)methane, MO, TRANSITION MOLECULAR MATERIALS, COORDINATION-COMPOUNDS, TEMPERATURE, CLOSO-BORATE COMPLEXES",
author = "Shakirova, {O. G.} and Korotaev, {E. V.} and Evtushok, {D. V.} and Kuratieva, {N. V.} and Sheludyakova, {L. A.} and Shestopalov, {M. A.} and Lavrenova, {L. G.}",
note = "Funding Information: The authors express gratitude to N. P. Korotkevich for recording the diffraction patterns and to I. V. Yushina for the diffuse reflectance spectra. T This work was supported by RFBR according to the research projects № 16-53-00020 Bel_a and № 18-53-00002 Bel_a . Also, D.V. Evtushok is grateful for the RFBR (grant № 18-33-00235 mol_a ).",
year = "2019",
month = oct,
day = "5",
doi = "10.1016/j.molstruc.2019.03.015",
language = "English",
volume = "1193",
pages = "1--6",
journal = "Journal of Molecular Structure",
issn = "0022-2860",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Spin-crossover in iron(II) complexes with tris(pyrazol-1-yl)methane and сluster anions [{W 6 X 8 }X 6 ] 2– (X = Cl, Br, I)

AU - Shakirova, O. G.

AU - Korotaev, E. V.

AU - Evtushok, D. V.

AU - Kuratieva, N. V.

AU - Sheludyakova, L. A.

AU - Shestopalov, M. A.

AU - Lavrenova, L. G.

N1 - Funding Information: The authors express gratitude to N. P. Korotkevich for recording the diffraction patterns and to I. V. Yushina for the diffuse reflectance spectra. T This work was supported by RFBR according to the research projects № 16-53-00020 Bel_a and № 18-53-00002 Bel_a . Also, D.V. Evtushok is grateful for the RFBR (grant № 18-33-00235 mol_a ).

PY - 2019/10/5

Y1 - 2019/10/5

N2 - Iron(II) complexes with tris(pyrazol-1-yl)methane (HC(pz) 3 ) and cluster anions [{W 6 X 8 }X 6 ] 2– (X = Cl, Br, I) of the composition [Fe(HC(pz) 3 ) 2 ][{W 6 X 8 }X 6 ]⋅2H 2 O ((1–3)⋅2H 2 O) were synthesized. The compounds were characterized by element analysis, single-crystal and powder X-ray diffraction measurements, infrared, diffuse reflectance spectroscopy and static magnetic susceptibility. The temperature dependence μ eff (T) shows that the high-temperature spin-crossover (SCO) 1 A 1g ↔ 5 T 2g is observed in both hydrates (1–3)·2H 2 O and dehydrated compounds (1–3). SCO is accompanied by thermochromism.

AB - Iron(II) complexes with tris(pyrazol-1-yl)methane (HC(pz) 3 ) and cluster anions [{W 6 X 8 }X 6 ] 2– (X = Cl, Br, I) of the composition [Fe(HC(pz) 3 ) 2 ][{W 6 X 8 }X 6 ]⋅2H 2 O ((1–3)⋅2H 2 O) were synthesized. The compounds were characterized by element analysis, single-crystal and powder X-ray diffraction measurements, infrared, diffuse reflectance spectroscopy and static magnetic susceptibility. The temperature dependence μ eff (T) shows that the high-temperature spin-crossover (SCO) 1 A 1g ↔ 5 T 2g is observed in both hydrates (1–3)·2H 2 O and dehydrated compounds (1–3). SCO is accompanied by thermochromism.

KW - Cluster anion

KW - Complex

KW - Crystal structure

KW - Iron(II)

KW - Spin-crossover

KW - Synthesis

KW - Thermochromism

KW - tris(pyrazol-1-yl)methane

KW - MO

KW - TRANSITION MOLECULAR MATERIALS

KW - COORDINATION-COMPOUNDS

KW - TEMPERATURE

KW - CLOSO-BORATE COMPLEXES

UR - http://www.scopus.com/inward/record.url?scp=85065440810&partnerID=8YFLogxK

U2 - 10.1016/j.molstruc.2019.03.015

DO - 10.1016/j.molstruc.2019.03.015

M3 - Article

AN - SCOPUS:85065440810

VL - 1193

SP - 1

EP - 6

JO - Journal of Molecular Structure

JF - Journal of Molecular Structure

SN - 0022-2860

ER -

ID: 20041878