Self-assembly of Ag(I)-based complexes and layered coordination polymers bridged by (2-thiazolyl)sulfides

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Self-assembly of Ag(I)-based complexes and layered coordination polymers bridged by (2-thiazolyl)sulfides. / Rogovoy, Maxim I.; Samsonenko, Denis G.; Rakhmanova, Mariana I. et al.

In: Inorganica Chimica Acta, Vol. 489, 01.04.2019, p. 19-26.

Research output: Contribution to journal › Article › peer-review

BibTeX

@article{753336f00e05484eb1b720eeed854e31,

title = "Self-assembly of Ag(I)-based complexes and layered coordination polymers bridged by (2-thiazolyl)sulfides",

abstract = "Dinuclear complex, [Ag2(2-Mt)2(MeCN)2(NO3)2] (1) as well as layered (2D) coordination polymers (CPs), [Ag2(2-Mt)2(NO3)2]n (2) and [Ag4(2-Mt)4(NO3)4·2H2O]n (3), are self-assembled from 2-(methylthio)thiazole (2-Mt) and AgNO3 under different conditions. These compounds contain a [Ag2(2-Mt)2] unit consisting of two metal atoms bridged by 2-Mt ligands (μ2-N,S) in head-to-tail (for 1 and 2) and head-to-head (for 3) manner. 2-(Methylthio)benzothiazole (2-Mbt) reacts with AgNO3 to assemble complex [Ag2(2-Mbt)2(MeCN)2(NO3)2] (4), showing interesting dual emission behavior associated with the presence of fluorescence and phosphorescence, contributions of which depends on the excitation wavelength.",

keywords = "Coordination polymers, Dual-emission, Self-assembly, Silver(I), Thiazoles, Thioether ligands, AG(I) COMPLEXES, SILVER(I) COMPLEXES, CRYSTAL-STRUCTURE, SPECTROSCOPIC PROPERTIES, THIAZOLE, NETWORKS, SULFUR, LUMINESCENCE, CLUSTERS, DONOR LIGANDS",

author = "Rogovoy, {Maxim I.} and Samsonenko, {Denis G.} and Rakhmanova, {Mariana I.} and Artem'ev, {Alexander V.}",

note = "Publisher Copyright: {\textcopyright} 2019 Elsevier B.V.",

year = "2019",

month = apr,

day = "1",

doi = "10.1016/j.ica.2019.01.036",

language = "English",

volume = "489",

pages = "19--26",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Self-assembly of Ag(I)-based complexes and layered coordination polymers bridged by (2-thiazolyl)sulfides

AU - Rogovoy, Maxim I.

AU - Samsonenko, Denis G.

AU - Rakhmanova, Mariana I.

AU - Artem'ev, Alexander V.

PY - 2019/4/1

Y1 - 2019/4/1

N2 - Dinuclear complex, [Ag2(2-Mt)2(MeCN)2(NO3)2] (1) as well as layered (2D) coordination polymers (CPs), [Ag2(2-Mt)2(NO3)2]n (2) and [Ag4(2-Mt)4(NO3)4·2H2O]n (3), are self-assembled from 2-(methylthio)thiazole (2-Mt) and AgNO3 under different conditions. These compounds contain a [Ag2(2-Mt)2] unit consisting of two metal atoms bridged by 2-Mt ligands (μ2-N,S) in head-to-tail (for 1 and 2) and head-to-head (for 3) manner. 2-(Methylthio)benzothiazole (2-Mbt) reacts with AgNO3 to assemble complex [Ag2(2-Mbt)2(MeCN)2(NO3)2] (4), showing interesting dual emission behavior associated with the presence of fluorescence and phosphorescence, contributions of which depends on the excitation wavelength.

AB - Dinuclear complex, [Ag2(2-Mt)2(MeCN)2(NO3)2] (1) as well as layered (2D) coordination polymers (CPs), [Ag2(2-Mt)2(NO3)2]n (2) and [Ag4(2-Mt)4(NO3)4·2H2O]n (3), are self-assembled from 2-(methylthio)thiazole (2-Mt) and AgNO3 under different conditions. These compounds contain a [Ag2(2-Mt)2] unit consisting of two metal atoms bridged by 2-Mt ligands (μ2-N,S) in head-to-tail (for 1 and 2) and head-to-head (for 3) manner. 2-(Methylthio)benzothiazole (2-Mbt) reacts with AgNO3 to assemble complex [Ag2(2-Mbt)2(MeCN)2(NO3)2] (4), showing interesting dual emission behavior associated with the presence of fluorescence and phosphorescence, contributions of which depends on the excitation wavelength.

KW - Coordination polymers

KW - Dual-emission

KW - Self-assembly

KW - Silver(I)

KW - Thiazoles

KW - Thioether ligands

KW - AG(I) COMPLEXES

KW - SILVER(I) COMPLEXES

KW - CRYSTAL-STRUCTURE

KW - SPECTROSCOPIC PROPERTIES

KW - THIAZOLE

KW - NETWORKS

KW - SULFUR

KW - LUMINESCENCE

KW - CLUSTERS

KW - DONOR LIGANDS

UR - http://www.scopus.com/inward/record.url?scp=85061174959&partnerID=8YFLogxK

U2 - 10.1016/j.ica.2019.01.036

DO - 10.1016/j.ica.2019.01.036

M3 - Article

AN - SCOPUS:85061174959

VL - 489

SP - 19

EP - 26

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

SN - 0020-1693

ER -

ID: 18489550