Research output: Contribution to journal › Article › peer-review
Resonant tip-enhanced Raman scattering by CdSe nanocrystals on plasmonic substrates. / Milekhin, I. A.; Rahaman, M.; Anikin, K. V. et al.
In: Nanoscale Advances, Vol. 2, No. 11, 11.2020, p. 5441-5449.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Resonant tip-enhanced Raman scattering by CdSe nanocrystals on plasmonic substrates
AU - Milekhin, I. A.
AU - Rahaman, M.
AU - Anikin, K. V.
AU - Rodyakina, E. E.
AU - Duda, T. A.
AU - Saidzhonov, B. M.
AU - Vasiliev, R. B.
AU - Dzhagan, V. M.
AU - Milekhin, A. G.
AU - Latyshev, A. V.
AU - Zahn, D. R.T.
N1 - Publisher Copyright: © The Royal Society of Chemistry.
PY - 2020/11
Y1 - 2020/11
N2 - Tip-enhanced Raman scattering (TERS) has recently emerged as a powerful technique for studying the local properties of low dimensional materials. Being a plasmon driven system, a dramatic enhancement of the TERS sensitivity can be achieved by an appropriate choice of the plasmonic substrate in the so-called gap-mode configuration. Here, we investigate the phonon properties of CdSe nanocrystals (NCs) utilizing gap-mode TERS. Using the Langmuir-Blodgett technique, we homogeneously deposited submonolayers of colloidal CdSe NCs on two different nanostructured plasmonic substrates. Amplified by resonant gap-mode TERS, the scattering by the optical phonon modes of CdSe NCs is markedly enhanced making it possible to observe up to the third overtone of the LO mode reliably. The home-made plasmonic substrates and TERS tips allow the analysis of the TERS images of CdSe phonon modes with nanometer spatial resolution. The CdSe phonon scattering intensity is strongly correlated with the local electromagnetic field distribution across the plasmonic substrates. This journal is
AB - Tip-enhanced Raman scattering (TERS) has recently emerged as a powerful technique for studying the local properties of low dimensional materials. Being a plasmon driven system, a dramatic enhancement of the TERS sensitivity can be achieved by an appropriate choice of the plasmonic substrate in the so-called gap-mode configuration. Here, we investigate the phonon properties of CdSe nanocrystals (NCs) utilizing gap-mode TERS. Using the Langmuir-Blodgett technique, we homogeneously deposited submonolayers of colloidal CdSe NCs on two different nanostructured plasmonic substrates. Amplified by resonant gap-mode TERS, the scattering by the optical phonon modes of CdSe NCs is markedly enhanced making it possible to observe up to the third overtone of the LO mode reliably. The home-made plasmonic substrates and TERS tips allow the analysis of the TERS images of CdSe phonon modes with nanometer spatial resolution. The CdSe phonon scattering intensity is strongly correlated with the local electromagnetic field distribution across the plasmonic substrates. This journal is
UR - http://www.scopus.com/inward/record.url?scp=85096037665&partnerID=8YFLogxK
U2 - 10.1039/d0na00554a
DO - 10.1039/d0na00554a
M3 - Article
C2 - 36132045
AN - SCOPUS:85096037665
VL - 2
SP - 5441
EP - 5449
JO - Nanoscale Advances
JF - Nanoscale Advances
SN - 2516-0230
IS - 11
ER -
ID: 25998335