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Reactions of Chalcogenide β-Diiminate Nickel Complexes with Samarium Bis(pentamethylcyclopentadienide). / Afonin, M. Yu; Sukhikh, T. S.; Konokhova, A. Yu et al.

In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Vol. 44, No. 2, 01.02.2018, p. 147-154.

Research output: Contribution to journal › Article › peer-review

Harvard

Afonin, MY, Sukhikh, TS, Konokhova, AY & Konchenko, SN 2018, 'Reactions of Chalcogenide β-Diiminate Nickel Complexes with Samarium Bis(pentamethylcyclopentadienide)', Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 44, no. 2, pp. 147-154. https://doi.org/10.1134/S107032841802001X

APA

Afonin, M. Y., Sukhikh, T. S., Konokhova, A. Y., & Konchenko, S. N. (2018). Reactions of Chalcogenide β-Diiminate Nickel Complexes with Samarium Bis(pentamethylcyclopentadienide). Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 44(2), 147-154. https://doi.org/10.1134/S107032841802001X

Vancouver

Afonin MY, Sukhikh TS, Konokhova AY, Konchenko SN. Reactions of Chalcogenide β-Diiminate Nickel Complexes with Samarium Bis(pentamethylcyclopentadienide). Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2018 Feb 1;44(2):147-154. doi: 10.1134/S107032841802001X

Author

Afonin, M. Yu ; Sukhikh, T. S. ; Konokhova, A. Yu et al. / Reactions of Chalcogenide β-Diiminate Nickel Complexes with Samarium Bis(pentamethylcyclopentadienide). In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2018 ; Vol. 44, No. 2. pp. 147-154.

BibTeX

@article{68558aaf4ac942088ffbaee72deb0b0e,
title = "Reactions of Chalcogenide β-Diiminate Nickel Complexes with Samarium Bis(pentamethylcyclopentadienide)",
abstract = "The reactions of [(LiPrNi)2(μ-η2:η2-S4)] (I) and [(LiPrNi)2(μ-η2:η2-Se2)] (II) (LiPr = CH[C(Me)N(2,6-iPr2C6H3)]2) with decamethylsamarocene [Sm(Cp*)2(Тhf)2] (Cp* = η5-C5Me5) are studied. It is assumed that the reactions afford hetero-d/f-metal complexes. However, these complexes are not observed but the transfer of chalcogens from Ni to Sm and the formation of [(Sm(Cp*)2(Тhf))2(μ-S)] (III) and [(Sm(Cp*)2(Тhf))2(μ-Se)] (IV) occur. The second reaction products are [(LiPrNi)2(μ-η2:η2-S2)] (V) in the case of sulfur and [(LiPrNiI)2(μ-η6:η6-C7H8)2] (VI) in the case of selenium. All reaction products have been described previously, but compounds III and V are isolated as new crystalline phase, the structures of which are determined by X-ray diffraction analysis (CIF files CCDC nos. 1559045 (V) and 1559046 (III)).",
keywords = "chalcogenide complexes, crystal structure, nickel, samarium, LANTHANIDE, SINGLE-MOLECULE MAGNETS, BOND",
author = "Afonin, {M. Yu} and Sukhikh, {T. S.} and Konokhova, {A. Yu} and Konchenko, {S. N.}",
note = "Publisher Copyright: {\textcopyright} 2018, Pleiades Publishing, Ltd.",
year = "2018",
month = feb,
day = "1",
doi = "10.1134/S107032841802001X",
language = "English",
volume = "44",
pages = "147--154",
journal = "Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya",
issn = "1070-3284",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "2",

}

RIS

TY - JOUR

T1 - Reactions of Chalcogenide β-Diiminate Nickel Complexes with Samarium Bis(pentamethylcyclopentadienide)

AU - Afonin, M. Yu

AU - Sukhikh, T. S.

AU - Konokhova, A. Yu

AU - Konchenko, S. N.

N1 - Publisher Copyright: © 2018, Pleiades Publishing, Ltd.

PY - 2018/2/1

Y1 - 2018/2/1

N2 - The reactions of [(LiPrNi)2(μ-η2:η2-S4)] (I) and [(LiPrNi)2(μ-η2:η2-Se2)] (II) (LiPr = CH[C(Me)N(2,6-iPr2C6H3)]2) with decamethylsamarocene [Sm(Cp*)2(Тhf)2] (Cp* = η5-C5Me5) are studied. It is assumed that the reactions afford hetero-d/f-metal complexes. However, these complexes are not observed but the transfer of chalcogens from Ni to Sm and the formation of [(Sm(Cp*)2(Тhf))2(μ-S)] (III) and [(Sm(Cp*)2(Тhf))2(μ-Se)] (IV) occur. The second reaction products are [(LiPrNi)2(μ-η2:η2-S2)] (V) in the case of sulfur and [(LiPrNiI)2(μ-η6:η6-C7H8)2] (VI) in the case of selenium. All reaction products have been described previously, but compounds III and V are isolated as new crystalline phase, the structures of which are determined by X-ray diffraction analysis (CIF files CCDC nos. 1559045 (V) and 1559046 (III)).

AB - The reactions of [(LiPrNi)2(μ-η2:η2-S4)] (I) and [(LiPrNi)2(μ-η2:η2-Se2)] (II) (LiPr = CH[C(Me)N(2,6-iPr2C6H3)]2) with decamethylsamarocene [Sm(Cp*)2(Тhf)2] (Cp* = η5-C5Me5) are studied. It is assumed that the reactions afford hetero-d/f-metal complexes. However, these complexes are not observed but the transfer of chalcogens from Ni to Sm and the formation of [(Sm(Cp*)2(Тhf))2(μ-S)] (III) and [(Sm(Cp*)2(Тhf))2(μ-Se)] (IV) occur. The second reaction products are [(LiPrNi)2(μ-η2:η2-S2)] (V) in the case of sulfur and [(LiPrNiI)2(μ-η6:η6-C7H8)2] (VI) in the case of selenium. All reaction products have been described previously, but compounds III and V are isolated as new crystalline phase, the structures of which are determined by X-ray diffraction analysis (CIF files CCDC nos. 1559045 (V) and 1559046 (III)).

KW - chalcogenide complexes

KW - crystal structure

KW - nickel

KW - samarium

KW - LANTHANIDE

KW - SINGLE-MOLECULE MAGNETS

KW - BOND

UR - http://www.scopus.com/inward/record.url?scp=85043333524&partnerID=8YFLogxK

U2 - 10.1134/S107032841802001X

DO - 10.1134/S107032841802001X

M3 - Article

AN - SCOPUS:85043333524

VL - 44

SP - 147

EP - 154

JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

SN - 1070-3284

IS - 2

ER -

ID: 10421962