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Preparation of Zr(Mo,W)2O8 with a larger negative thermal expansion by controlling the thermal decomposition of Zr(Mo,W)2(OH,Cl)2·2H2O. / Petrushina, Mariya Yu; Dedova, Elena S.; Filatov, Eugeny Yu et al.

In: Scientific Reports, Vol. 8, No. 1, 5337, 28.03.2018, p. 5337.

Research output: Contribution to journal › Article › peer-review

Harvard

Petrushina, MY, Dedova, ES, Filatov, EY, Plyusnin, PE, Korenev, SV, Kulkov, SN, Derevyannikova, EA, Sharafutdinov, MR & Gubanov, AI 2018, 'Preparation of Zr(Mo,W)2O8 with a larger negative thermal expansion by controlling the thermal decomposition of Zr(Mo,W)2(OH,Cl)2·2H2O', Scientific Reports, vol. 8, no. 1, 5337, pp. 5337. https://doi.org/10.1038/s41598-018-23529-6

APA

Petrushina, M. Y., Dedova, E. S., Filatov, E. Y., Plyusnin, P. E., Korenev, S. V., Kulkov, S. N., Derevyannikova, E. A., Sharafutdinov, M. R., & Gubanov, A. I. (2018). Preparation of Zr(Mo,W)2O8 with a larger negative thermal expansion by controlling the thermal decomposition of Zr(Mo,W)2(OH,Cl)2·2H2O. Scientific Reports, 8(1), 5337. [5337]. https://doi.org/10.1038/s41598-018-23529-6

Vancouver

Petrushina MY, Dedova ES, Filatov EY, Plyusnin PE, Korenev SV, Kulkov SN et al. Preparation of Zr(Mo,W)2O8 with a larger negative thermal expansion by controlling the thermal decomposition of Zr(Mo,W)2(OH,Cl)2·2H2O. Scientific Reports. 2018 Mar 28;8(1):5337. 5337. doi: 10.1038/s41598-018-23529-6

Author

Petrushina, Mariya Yu ; Dedova, Elena S. ; Filatov, Eugeny Yu et al. / Preparation of Zr(Mo,W)2O8 with a larger negative thermal expansion by controlling the thermal decomposition of Zr(Mo,W)2(OH,Cl)2·2H2O. In: Scientific Reports. 2018 ; Vol. 8, No. 1. pp. 5337.

BibTeX

@article{08bb1ddb14a34c23b2f9558a650ee1d1,
title = "Preparation of Zr(Mo,W)2O8 with a larger negative thermal expansion by controlling the thermal decomposition of Zr(Mo,W)2(OH,Cl)2·2H2O",
abstract = "Solid solutions of Zr(Mo,W)2O7(OH,Cl)2·2H2O with a preset ratio of components were prepared by a hydrothermal method. The chemical composition of the solutions was determined by energy dispersive X-ray spectroscopy (EDX). For all the samples of ZrMoxW2-xO7(OH,Cl)2·2H2O (x = 0.0, 0.2, 0.4, 0.6, 0.8, 1.0, 1.2, 1.4, 1.6, 1.8, and 2.0), TGA and in situ powder X-ray diffraction (PXRD) studies (300-1100 K) were conducted. For each case, the boundaries of the transformations were determined: Zr(Mo,W)2O7(OH,Cl)2·2H2O → orthorhombic-ZrMoxW2-xO8 (425-525 K), orthorhombic-ZrMoxW2-xO8 → cubic-ZrMoxW2-xO8 (700-850 K), cubic-ZrMoxW2-xO8 → trigonal-ZrMoxW2-xO8 (800-1050 K for x > 1) and cubic-ZrMoxW2-xO8 → oxides (1000-1075 K for x ≤ 1). The cell parameters of the disordered cubic-ZrMoxW2-xO8 (space group Pa-3) were measured within 300-900 K, and the thermal expansion coefficients were calculated: -3.5·10-6 - -4.5·10-6 K-1. For the ordered ZrMo1.8W0.2O8 (space group P213), a negative thermal expansion (NTE) coefficient -9.6·10-6 K-1 (300-400 K) was calculated. Orthorhombic-ZrW2O8 is formed upon the decomposition of ZrW2O7(OH,Cl)2·2H2O within 500-800 K.",
keywords = "MATERIAL CUBIC ZRMO2O8, ZRW2O8",
author = "Petrushina, {Mariya Yu} and Dedova, {Elena S.} and Filatov, {Eugeny Yu} and Plyusnin, {Pavel E.} and Korenev, {Sergei V.} and Kulkov, {Sergei N.} and Derevyannikova, {Elizaveta A.} and Sharafutdinov, {Marat R.} and Gubanov, {Alexander I.}",
note = "Publisher Copyright: {\textcopyright} 2018 The Author(s).",
year = "2018",
month = mar,
day = "28",
doi = "10.1038/s41598-018-23529-6",
language = "English",
volume = "8",
pages = "5337",
journal = "Scientific Reports",
issn = "2045-2322",
publisher = "Nature Publishing Group",
number = "1",

}

RIS

TY - JOUR

T1 - Preparation of Zr(Mo,W)2O8 with a larger negative thermal expansion by controlling the thermal decomposition of Zr(Mo,W)2(OH,Cl)2·2H2O

AU - Petrushina, Mariya Yu

AU - Dedova, Elena S.

AU - Filatov, Eugeny Yu

AU - Plyusnin, Pavel E.

AU - Korenev, Sergei V.

AU - Kulkov, Sergei N.

AU - Derevyannikova, Elizaveta A.

AU - Sharafutdinov, Marat R.

AU - Gubanov, Alexander I.

N1 - Publisher Copyright: © 2018 The Author(s).

PY - 2018/3/28

Y1 - 2018/3/28

N2 - Solid solutions of Zr(Mo,W)2O7(OH,Cl)2·2H2O with a preset ratio of components were prepared by a hydrothermal method. The chemical composition of the solutions was determined by energy dispersive X-ray spectroscopy (EDX). For all the samples of ZrMoxW2-xO7(OH,Cl)2·2H2O (x = 0.0, 0.2, 0.4, 0.6, 0.8, 1.0, 1.2, 1.4, 1.6, 1.8, and 2.0), TGA and in situ powder X-ray diffraction (PXRD) studies (300-1100 K) were conducted. For each case, the boundaries of the transformations were determined: Zr(Mo,W)2O7(OH,Cl)2·2H2O → orthorhombic-ZrMoxW2-xO8 (425-525 K), orthorhombic-ZrMoxW2-xO8 → cubic-ZrMoxW2-xO8 (700-850 K), cubic-ZrMoxW2-xO8 → trigonal-ZrMoxW2-xO8 (800-1050 K for x > 1) and cubic-ZrMoxW2-xO8 → oxides (1000-1075 K for x ≤ 1). The cell parameters of the disordered cubic-ZrMoxW2-xO8 (space group Pa-3) were measured within 300-900 K, and the thermal expansion coefficients were calculated: -3.5·10-6 - -4.5·10-6 K-1. For the ordered ZrMo1.8W0.2O8 (space group P213), a negative thermal expansion (NTE) coefficient -9.6·10-6 K-1 (300-400 K) was calculated. Orthorhombic-ZrW2O8 is formed upon the decomposition of ZrW2O7(OH,Cl)2·2H2O within 500-800 K.

AB - Solid solutions of Zr(Mo,W)2O7(OH,Cl)2·2H2O with a preset ratio of components were prepared by a hydrothermal method. The chemical composition of the solutions was determined by energy dispersive X-ray spectroscopy (EDX). For all the samples of ZrMoxW2-xO7(OH,Cl)2·2H2O (x = 0.0, 0.2, 0.4, 0.6, 0.8, 1.0, 1.2, 1.4, 1.6, 1.8, and 2.0), TGA and in situ powder X-ray diffraction (PXRD) studies (300-1100 K) were conducted. For each case, the boundaries of the transformations were determined: Zr(Mo,W)2O7(OH,Cl)2·2H2O → orthorhombic-ZrMoxW2-xO8 (425-525 K), orthorhombic-ZrMoxW2-xO8 → cubic-ZrMoxW2-xO8 (700-850 K), cubic-ZrMoxW2-xO8 → trigonal-ZrMoxW2-xO8 (800-1050 K for x > 1) and cubic-ZrMoxW2-xO8 → oxides (1000-1075 K for x ≤ 1). The cell parameters of the disordered cubic-ZrMoxW2-xO8 (space group Pa-3) were measured within 300-900 K, and the thermal expansion coefficients were calculated: -3.5·10-6 - -4.5·10-6 K-1. For the ordered ZrMo1.8W0.2O8 (space group P213), a negative thermal expansion (NTE) coefficient -9.6·10-6 K-1 (300-400 K) was calculated. Orthorhombic-ZrW2O8 is formed upon the decomposition of ZrW2O7(OH,Cl)2·2H2O within 500-800 K.

KW - MATERIAL CUBIC ZRMO2O8

KW - ZRW2O8

UR - http://www.scopus.com/inward/record.url?scp=85044542955&partnerID=8YFLogxK

U2 - 10.1038/s41598-018-23529-6

DO - 10.1038/s41598-018-23529-6

M3 - Article

C2 - 29593240

AN - SCOPUS:85044542955

VL - 8

SP - 5337

JO - Scientific Reports

JF - Scientific Reports

SN - 2045-2322

IS - 1

M1 - 5337

ER -

ID: 12232405