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Post-mortem characterization of Rh/Ce0.75Zr0.25O2/Al2O3/FeCrAl wire mesh composite catalyst for diesel autothermal reforming. / Rogozhnikov, V. N.; Potemkin, D. I.; Ruban, N. V. et al.

In: Materials Letters, Vol. 257, 126715, 15.12.2019.

Research output: Contribution to journal › Article › peer-review

Harvard

Rogozhnikov, VN, Potemkin, DI, Ruban, NV, Shilov, VA, Salanov, AN, Kulikov, AV, Simonov, PA, Gerasimov, EY, Sobyanin, VA & Snytnikov, PV 2019, 'Post-mortem characterization of Rh/Ce0.75Zr0.25O2/Al2O3/FeCrAl wire mesh composite catalyst for diesel autothermal reforming', Materials Letters, vol. 257, 126715. https://doi.org/10.1016/j.matlet.2019.126715

APA

Rogozhnikov, V. N., Potemkin, D. I., Ruban, N. V., Shilov, V. A., Salanov, A. N., Kulikov, A. V., Simonov, P. A., Gerasimov, E. Y., Sobyanin, V. A., & Snytnikov, P. V. (2019). Post-mortem characterization of Rh/Ce0.75Zr0.25O2/Al2O3/FeCrAl wire mesh composite catalyst for diesel autothermal reforming. Materials Letters, 257, [126715]. https://doi.org/10.1016/j.matlet.2019.126715

Vancouver

Rogozhnikov VN, Potemkin DI, Ruban NV, Shilov VA, Salanov AN, Kulikov AV et al. Post-mortem characterization of Rh/Ce0.75Zr0.25O2/Al2O3/FeCrAl wire mesh composite catalyst for diesel autothermal reforming. Materials Letters. 2019 Dec 15;257:126715. doi: 10.1016/j.matlet.2019.126715

Author

Rogozhnikov, V. N. ; Potemkin, D. I. ; Ruban, N. V. et al. / Post-mortem characterization of Rh/Ce0.75Zr0.25O2/Al2O3/FeCrAl wire mesh composite catalyst for diesel autothermal reforming. In: Materials Letters. 2019 ; Vol. 257.

BibTeX

@article{b751bd875ab648b5a305ccc11b7dbef3,
title = "Post-mortem characterization of Rh/Ce0.75Zr0.25O2/Al2O3/FeCrAl wire mesh composite catalyst for diesel autothermal reforming",
abstract = "Front and end zones of Rh/Ce0.75Zr0.25O2−δ-ƞ-Al2O3/FeCrAl wire mesh catalytic module were studied by transmission electron microscopy (TEM) and scanning electron microscopy (SEM) techniques after more than 250 h on stream under hydrocarbon fuels steam (SR) and autothermal reforming (ATR) conditions. Catalyst coking by fibrous carbon growth under diesel ATR conditions was confirmed. This process was mainly located on the surface of the catalytic coating and did not induce exfoliation and damage of coating. Coking was attributed to contamination by iron, which was confirmed by TEM and energy-dispersive X-ray spectroscopy (EDX). Despite catalyst carbonization, the composite catalyst was shown to be stable and regeneratable under hydrocarbon ATR and SR conditions, no morphology and microstructure degradation was identified in both front and end zones of the monolith.",
keywords = "Autothermal reforming, CONVERSION, Coking, Diesel, HYDROGEN, Interfaces, MODULE, Nanoparticles, Rhodium catalysts",
author = "Rogozhnikov, {V. N.} and Potemkin, {D. I.} and Ruban, {N. V.} and Shilov, {V. A.} and Salanov, {A. N.} and Kulikov, {A. V.} and Simonov, {P. A.} and Gerasimov, {E. Y.} and Sobyanin, {V. A.} and Snytnikov, {P. V.}",
note = "Publisher Copyright: {\textcopyright} 2019 Elsevier B.V. Copyright: Copyright 2019 Elsevier B.V., All rights reserved.",
year = "2019",
month = dec,
day = "15",
doi = "10.1016/j.matlet.2019.126715",
language = "English",
volume = "257",
journal = "Materials Letters",
issn = "0167-577X",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Post-mortem characterization of Rh/Ce0.75Zr0.25O2/Al2O3/FeCrAl wire mesh composite catalyst for diesel autothermal reforming

AU - Rogozhnikov, V. N.

AU - Potemkin, D. I.

AU - Ruban, N. V.

AU - Shilov, V. A.

AU - Salanov, A. N.

AU - Kulikov, A. V.

AU - Simonov, P. A.

AU - Gerasimov, E. Y.

AU - Sobyanin, V. A.

AU - Snytnikov, P. V.

N1 - Publisher Copyright: © 2019 Elsevier B.V. Copyright: Copyright 2019 Elsevier B.V., All rights reserved.

PY - 2019/12/15

Y1 - 2019/12/15

N2 - Front and end zones of Rh/Ce0.75Zr0.25O2−δ-ƞ-Al2O3/FeCrAl wire mesh catalytic module were studied by transmission electron microscopy (TEM) and scanning electron microscopy (SEM) techniques after more than 250 h on stream under hydrocarbon fuels steam (SR) and autothermal reforming (ATR) conditions. Catalyst coking by fibrous carbon growth under diesel ATR conditions was confirmed. This process was mainly located on the surface of the catalytic coating and did not induce exfoliation and damage of coating. Coking was attributed to contamination by iron, which was confirmed by TEM and energy-dispersive X-ray spectroscopy (EDX). Despite catalyst carbonization, the composite catalyst was shown to be stable and regeneratable under hydrocarbon ATR and SR conditions, no morphology and microstructure degradation was identified in both front and end zones of the monolith.

AB - Front and end zones of Rh/Ce0.75Zr0.25O2−δ-ƞ-Al2O3/FeCrAl wire mesh catalytic module were studied by transmission electron microscopy (TEM) and scanning electron microscopy (SEM) techniques after more than 250 h on stream under hydrocarbon fuels steam (SR) and autothermal reforming (ATR) conditions. Catalyst coking by fibrous carbon growth under diesel ATR conditions was confirmed. This process was mainly located on the surface of the catalytic coating and did not induce exfoliation and damage of coating. Coking was attributed to contamination by iron, which was confirmed by TEM and energy-dispersive X-ray spectroscopy (EDX). Despite catalyst carbonization, the composite catalyst was shown to be stable and regeneratable under hydrocarbon ATR and SR conditions, no morphology and microstructure degradation was identified in both front and end zones of the monolith.

KW - Autothermal reforming

KW - CONVERSION

KW - Coking

KW - Diesel

KW - HYDROGEN

KW - Interfaces

KW - MODULE

KW - Nanoparticles

KW - Rhodium catalysts

UR - http://www.scopus.com/inward/record.url?scp=85072771153&partnerID=8YFLogxK

U2 - 10.1016/j.matlet.2019.126715

DO - 10.1016/j.matlet.2019.126715

M3 - Article

AN - SCOPUS:85072771153

VL - 257

JO - Materials Letters

JF - Materials Letters

SN - 0167-577X

M1 - 126715

ER -

ID: 21753898