Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Post-mortem characterization of Rh/Ce0.75Zr0.25O2/Al2O3/FeCrAl wire mesh composite catalyst for diesel autothermal reforming. / Rogozhnikov, V. N.; Potemkin, D. I.; Ruban, N. V. и др.
в: Materials Letters, Том 257, 126715, 15.12.2019.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Post-mortem characterization of Rh/Ce0.75Zr0.25O2/Al2O3/FeCrAl wire mesh composite catalyst for diesel autothermal reforming
AU - Rogozhnikov, V. N.
AU - Potemkin, D. I.
AU - Ruban, N. V.
AU - Shilov, V. A.
AU - Salanov, A. N.
AU - Kulikov, A. V.
AU - Simonov, P. A.
AU - Gerasimov, E. Y.
AU - Sobyanin, V. A.
AU - Snytnikov, P. V.
N1 - Publisher Copyright: © 2019 Elsevier B.V. Copyright: Copyright 2019 Elsevier B.V., All rights reserved.
PY - 2019/12/15
Y1 - 2019/12/15
N2 - Front and end zones of Rh/Ce0.75Zr0.25O2−δ-ƞ-Al2O3/FeCrAl wire mesh catalytic module were studied by transmission electron microscopy (TEM) and scanning electron microscopy (SEM) techniques after more than 250 h on stream under hydrocarbon fuels steam (SR) and autothermal reforming (ATR) conditions. Catalyst coking by fibrous carbon growth under diesel ATR conditions was confirmed. This process was mainly located on the surface of the catalytic coating and did not induce exfoliation and damage of coating. Coking was attributed to contamination by iron, which was confirmed by TEM and energy-dispersive X-ray spectroscopy (EDX). Despite catalyst carbonization, the composite catalyst was shown to be stable and regeneratable under hydrocarbon ATR and SR conditions, no morphology and microstructure degradation was identified in both front and end zones of the monolith.
AB - Front and end zones of Rh/Ce0.75Zr0.25O2−δ-ƞ-Al2O3/FeCrAl wire mesh catalytic module were studied by transmission electron microscopy (TEM) and scanning electron microscopy (SEM) techniques after more than 250 h on stream under hydrocarbon fuels steam (SR) and autothermal reforming (ATR) conditions. Catalyst coking by fibrous carbon growth under diesel ATR conditions was confirmed. This process was mainly located on the surface of the catalytic coating and did not induce exfoliation and damage of coating. Coking was attributed to contamination by iron, which was confirmed by TEM and energy-dispersive X-ray spectroscopy (EDX). Despite catalyst carbonization, the composite catalyst was shown to be stable and regeneratable under hydrocarbon ATR and SR conditions, no morphology and microstructure degradation was identified in both front and end zones of the monolith.
KW - Autothermal reforming
KW - CONVERSION
KW - Coking
KW - Diesel
KW - HYDROGEN
KW - Interfaces
KW - MODULE
KW - Nanoparticles
KW - Rhodium catalysts
UR - http://www.scopus.com/inward/record.url?scp=85072771153&partnerID=8YFLogxK
U2 - 10.1016/j.matlet.2019.126715
DO - 10.1016/j.matlet.2019.126715
M3 - Article
AN - SCOPUS:85072771153
VL - 257
JO - Materials Letters
JF - Materials Letters
SN - 0167-577X
M1 - 126715
ER -
ID: 21753898