Research output: Contribution to journal › Article › peer-review
Polymeric Lead(II) Iodoacetate : Pb···I and I···I Non-Covalent Interactions in the Solid State. / Adonin, Sergey A.; Novikov, Alexander S.; Sokolov, Maxim N.
In: European Journal of Inorganic Chemistry, Vol. 2019, No. 39-40, 31.10.2019, p. 4221-4223.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Polymeric Lead(II) Iodoacetate
T2 - Pb···I and I···I Non-Covalent Interactions in the Solid State
AU - Adonin, Sergey A.
AU - Novikov, Alexander S.
AU - Sokolov, Maxim N.
PY - 2019/10/31
Y1 - 2019/10/31
N2 - Two-dimensional Pb II iodoacetate complex {Pb(ICH 2 COO) 2 } n (1) was prepared by reaction of lead nitrate with potassium iodoacetate. In 1, Pb is hepta-coordinated; additionally, metal centers participate in non-covalent I···I and Pb···I contacts. According to the analysis of XRD data and DFT calculations, the I···I non-covalent interactions are crystal packing-induced type I contacts, and Pb···I contacts are caused by interactions between Pb 2+ as electrophilic center and lone pairs of the iodine atom.
AB - Two-dimensional Pb II iodoacetate complex {Pb(ICH 2 COO) 2 } n (1) was prepared by reaction of lead nitrate with potassium iodoacetate. In 1, Pb is hepta-coordinated; additionally, metal centers participate in non-covalent I···I and Pb···I contacts. According to the analysis of XRD data and DFT calculations, the I···I non-covalent interactions are crystal packing-induced type I contacts, and Pb···I contacts are caused by interactions between Pb 2+ as electrophilic center and lone pairs of the iodine atom.
KW - Coordination polymers
KW - Iodoacetate
KW - Lead
KW - Noncovalent interactions
KW - QTAIM
KW - ANIONS
KW - INTERPLAY
KW - ORGANIC-LIGANDS
KW - NICKEL(II)
KW - HETEROMETALLIC COMPLEXES
KW - HYDROGEN
KW - HALOGEN BONDING INTERACTIONS
KW - CRYSTALS
KW - METAL-IONS
KW - ARCHITECTURES
UR - http://www.scopus.com/inward/record.url?scp=85065675492&partnerID=8YFLogxK
U2 - 10.1002/ejic.201900349
DO - 10.1002/ejic.201900349
M3 - Article
AN - SCOPUS:85065675492
VL - 2019
SP - 4221
EP - 4223
JO - European Journal of Inorganic Chemistry
JF - European Journal of Inorganic Chemistry
SN - 1434-1948
IS - 39-40
ER -
ID: 20163894