TY - JOUR

T1 - Polymeric Lead(II) Iodoacetate

T2 - Pb···I and I···I Non-Covalent Interactions in the Solid State

AU - Adonin, Sergey A.

AU - Novikov, Alexander S.

AU - Sokolov, Maxim N.

PY - 2019/10/31

Y1 - 2019/10/31

N2 - Two-dimensional Pb II iodoacetate complex {Pb(ICH 2 COO) 2 } n (1) was prepared by reaction of lead nitrate with potassium iodoacetate. In 1, Pb is hepta-coordinated; additionally, metal centers participate in non-covalent I···I and Pb···I contacts. According to the analysis of XRD data and DFT calculations, the I···I non-covalent interactions are crystal packing-induced type I contacts, and Pb···I contacts are caused by interactions between Pb 2+ as electrophilic center and lone pairs of the iodine atom.

AB - Two-dimensional Pb II iodoacetate complex {Pb(ICH 2 COO) 2 } n (1) was prepared by reaction of lead nitrate with potassium iodoacetate. In 1, Pb is hepta-coordinated; additionally, metal centers participate in non-covalent I···I and Pb···I contacts. According to the analysis of XRD data and DFT calculations, the I···I non-covalent interactions are crystal packing-induced type I contacts, and Pb···I contacts are caused by interactions between Pb 2+ as electrophilic center and lone pairs of the iodine atom.

KW - Coordination polymers

KW - Iodoacetate

KW - Lead

KW - Noncovalent interactions

KW - QTAIM

KW - ANIONS

KW - INTERPLAY

KW - ORGANIC-LIGANDS

KW - NICKEL(II)

KW - HETEROMETALLIC COMPLEXES

KW - HYDROGEN

KW - HALOGEN BONDING INTERACTIONS

KW - CRYSTALS

KW - METAL-IONS

KW - ARCHITECTURES

UR - http://www.scopus.com/inward/record.url?scp=85065675492&partnerID=8YFLogxK

U2 - 10.1002/ejic.201900349

DO - 10.1002/ejic.201900349

M3 - Article

AN - SCOPUS:85065675492

VL - 2019

SP - 4221

EP - 4223

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

SN - 1434-1948

IS - 39-40

ER -