Research output: Contribution to journal › Article › peer-review
Polymeric hybrid iodoplumbates and iodobismuthates containing mono- and bisalkylated derivatives of 1,2-bis(4-pyridyl)ethylene : Structural and optical features. / Usoltsev, Andrey N.; Adonin, Sergey A.; Abramov, Pavel A. et al.
In: Inorganica Chimica Acta, Vol. 462, 01.06.2017, p. 323-328.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Polymeric hybrid iodoplumbates and iodobismuthates containing mono- and bisalkylated derivatives of 1,2-bis(4-pyridyl)ethylene
T2 - Structural and optical features
AU - Usoltsev, Andrey N.
AU - Adonin, Sergey A.
AU - Abramov, Pavel A.
AU - Korolkov, Ilya V.
AU - Yushina, Irina V.
AU - Antonova, Olga V.
AU - Sokolov, Maxim N.
AU - Fedin, Vladimir P.
PY - 2017/6/1
Y1 - 2017/6/1
N2 - Reactions of PbI2 with N-alkylated derivatives of 1,2-bis(4-pyridyl)ethylene (bpen) MeBpenI and Me2BpenI2 result in 1D-polymeric complexes [{Pb(MeBpen)I3}] (1) and (Me2bpen)[{PbI3}]2 (2). For both compounds, band gap values were determinated experimentally; 1 demonstrates weak red luminescence. Binuclear hybrid iodobismuthate [Bi2(MeBpen)2I8] (3) was obtained by the similar scheme using BiI3 instead of PbI2.
AB - Reactions of PbI2 with N-alkylated derivatives of 1,2-bis(4-pyridyl)ethylene (bpen) MeBpenI and Me2BpenI2 result in 1D-polymeric complexes [{Pb(MeBpen)I3}] (1) and (Me2bpen)[{PbI3}]2 (2). For both compounds, band gap values were determinated experimentally; 1 demonstrates weak red luminescence. Binuclear hybrid iodobismuthate [Bi2(MeBpen)2I8] (3) was obtained by the similar scheme using BiI3 instead of PbI2.
KW - Band gap determination
KW - Bismuth
KW - Iodide complexes
KW - Lead
KW - Luminescence
KW - X-ray diffractometry
KW - PHOTOCATALYTIC PROPERTIES
KW - SOLAR-CELLS
KW - LEAD-FREE
KW - BISMUTH COMPLEXES
KW - CRYSTAL-STRUCTURES
KW - ORGANIC-INORGANIC HYBRID
KW - LAYERED PEROVSKITE SEMICONDUCTOR
KW - CENTER-DOT
KW - COORDINATION POLYMERS
KW - HIRSHFELD SURFACE
UR - http://www.scopus.com/inward/record.url?scp=85017466892&partnerID=8YFLogxK
U2 - 10.1016/j.ica.2017.04.002
DO - 10.1016/j.ica.2017.04.002
M3 - Article
AN - SCOPUS:85017466892
VL - 462
SP - 323
EP - 328
JO - Inorganica Chimica Acta
JF - Inorganica Chimica Acta
SN - 0020-1693
ER -
ID: 8968753