Research output: Contribution to journal › Article › peer-review
Polybromide salts of tetraalkyl and N-heterocyclic cations: New entries into the structural library. / Gorokh, Igor D.; Adonin, Sergey A.; Sokolov, Maxim N. et al.
In: Inorganica Chimica Acta, Vol. 469, 01.01.2018, p. 583-587.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Polybromide salts of tetraalkyl and N-heterocyclic cations: New entries into the structural library
AU - Gorokh, Igor D.
AU - Adonin, Sergey A.
AU - Sokolov, Maxim N.
AU - Abramov, Pavel A.
AU - Korolkov, Ilya V.
AU - Semitut, Evgeniy Yu
AU - Fedin, Vladimir P.
N1 - Funding Information: This work has been supported by Russian Science Foundation (Grant No. 14-23-00013 ). SAA thanks the President of Russian Federation for a research fellowship. We thank one of the referees for her/his valuable suggestions. Publisher Copyright: © 2017 Elsevier B.V.
PY - 2018/1/1
Y1 - 2018/1/1
N2 - Reactions between Br2 dissolved in HBr and salts of various organic cations resulted in formation of a series of polyhalide salts: (IsoquinolH)Br3 (1), (2-BrPyH)Br3 (2), (H2(4,4′-bipy))(Br3)2 (3), Bu4NBr3 (4), (Collidinium){(Br3)(Br2)} (5) and Et4N{(Br3)(Br2)2} (6). All compounds were characterized by X-ray diffractometry; the role of supramolecular Br⋯Br contacts is discussed.
AB - Reactions between Br2 dissolved in HBr and salts of various organic cations resulted in formation of a series of polyhalide salts: (IsoquinolH)Br3 (1), (2-BrPyH)Br3 (2), (H2(4,4′-bipy))(Br3)2 (3), Bu4NBr3 (4), (Collidinium){(Br3)(Br2)} (5) and Et4N{(Br3)(Br2)2} (6). All compounds were characterized by X-ray diffractometry; the role of supramolecular Br⋯Br contacts is discussed.
KW - Polybromides
KW - Polyhalides
KW - Supramolecular contacts
KW - X-ray diffractometry
KW - ANIONS
KW - NETWORK
KW - CRYSTAL-STRUCTURES
KW - FLOW BATTERY
KW - HALOGEN-HALOGEN INTERACTIONS
KW - QUATERNARY AMMONIUM
KW - TRIBROMIDE
KW - BROMINE
KW - IONIC LIQUIDS
KW - DIHALOGENS
UR - http://www.scopus.com/inward/record.url?scp=85031827077&partnerID=8YFLogxK
U2 - 10.1016/j.ica.2017.10.008
DO - 10.1016/j.ica.2017.10.008
M3 - Article
AN - SCOPUS:85031827077
VL - 469
SP - 583
EP - 587
JO - Inorganica Chimica Acta
JF - Inorganica Chimica Acta
SN - 0020-1693
ER -
ID: 12101610