Standard

PH-Controlled One Pot Syntheses of Giant Mo2O2S2-Containing Seleno-Tungstate Architectures. / Moussawi, Mhamad Aly; Floquet, Sébastien; Abramov, Pavel A. et al.

In: Inorganic Chemistry, Vol. 57, No. 1, 02.01.2018, p. 56-63.

Research output: Contribution to journal › Article › peer-review

Harvard

Moussawi, MA, Floquet, S, Abramov, PA, Vicent, C, Haouas, M & Cadot, E 2018, 'PH-Controlled One Pot Syntheses of Giant Mo2O2S2-Containing Seleno-Tungstate Architectures', Inorganic Chemistry, vol. 57, no. 1, pp. 56-63. https://doi.org/10.1021/acs.inorgchem.7b01644

APA

Moussawi, M. A., Floquet, S., Abramov, P. A., Vicent, C., Haouas, M., & Cadot, E. (2018). PH-Controlled One Pot Syntheses of Giant Mo2O2S2-Containing Seleno-Tungstate Architectures. Inorganic Chemistry, 57(1), 56-63. https://doi.org/10.1021/acs.inorgchem.7b01644

Vancouver

Moussawi MA, Floquet S, Abramov PA, Vicent C, Haouas M, Cadot E. PH-Controlled One Pot Syntheses of Giant Mo2O2S2-Containing Seleno-Tungstate Architectures. Inorganic Chemistry. 2018 Jan 2;57(1):56-63. doi: 10.1021/acs.inorgchem.7b01644

Author

Moussawi, Mhamad Aly ; Floquet, Sébastien ; Abramov, Pavel A. et al. / PH-Controlled One Pot Syntheses of Giant Mo2O2S2-Containing Seleno-Tungstate Architectures. In: Inorganic Chemistry. 2018 ; Vol. 57, No. 1. pp. 56-63.

BibTeX

@article{92308bcdf8e54837870f1b0fd740cd63,
title = "PH-Controlled One Pot Syntheses of Giant Mo2O2S2-Containing Seleno-Tungstate Architectures",
abstract = "Self-assembly reactions of Na2WO4, SeO2/SeO3 2-, and [Mo2O2(μ-S)2(H2O)6]2+ give, depending on the pH value, two new large polyoxometalate complexes: i.e., [(γ-Se2W14O52)3(Mo2O2(μ-S)2(H2O)2)6]24- (1) isolated at pH 3.5 and [(γ-Se2W14O52)4(WO3(H2O))8(W2O5)2(W4O12)2(Mo2O2(μ-S)2(H2O)2)4(Mo2O2(μ-S)2(SeO3))4]36- (2) isolated at pH 2. Both compounds were characterized in the solid state by single-crystal X-ray diffraction, EDX, elemental analysis, TGA, and FT-IR and in solution by ESI-MS and NMR.",
keywords = "BUILDING-BLOCK STRATEGY, DYNAMIC LIBRARY, POLYOXOMETALATE, CLUSTERS, NANOSCALE, UNITS, TEMPLATES, CHEMISTRY, ANION, POLYOXOTUNGSTATES",
author = "Moussawi, {Mhamad Aly} and S{\'e}bastien Floquet and Abramov, {Pavel A.} and Cristian Vicent and Mohamed Haouas and Emmanuel Cadot",
year = "2018",
month = jan,
day = "2",
doi = "10.1021/acs.inorgchem.7b01644",
language = "English",
volume = "57",
pages = "56--63",
journal = "Inorganic Chemistry",
issn = "0020-1669",
publisher = "American Chemical Society",
number = "1",

}

RIS

TY - JOUR

T1 - PH-Controlled One Pot Syntheses of Giant Mo2O2S2-Containing Seleno-Tungstate Architectures

AU - Moussawi, Mhamad Aly

AU - Floquet, Sébastien

AU - Abramov, Pavel A.

AU - Vicent, Cristian

AU - Haouas, Mohamed

AU - Cadot, Emmanuel

PY - 2018/1/2

Y1 - 2018/1/2

N2 - Self-assembly reactions of Na2WO4, SeO2/SeO3 2-, and [Mo2O2(μ-S)2(H2O)6]2+ give, depending on the pH value, two new large polyoxometalate complexes: i.e., [(γ-Se2W14O52)3(Mo2O2(μ-S)2(H2O)2)6]24- (1) isolated at pH 3.5 and [(γ-Se2W14O52)4(WO3(H2O))8(W2O5)2(W4O12)2(Mo2O2(μ-S)2(H2O)2)4(Mo2O2(μ-S)2(SeO3))4]36- (2) isolated at pH 2. Both compounds were characterized in the solid state by single-crystal X-ray diffraction, EDX, elemental analysis, TGA, and FT-IR and in solution by ESI-MS and NMR.

AB - Self-assembly reactions of Na2WO4, SeO2/SeO3 2-, and [Mo2O2(μ-S)2(H2O)6]2+ give, depending on the pH value, two new large polyoxometalate complexes: i.e., [(γ-Se2W14O52)3(Mo2O2(μ-S)2(H2O)2)6]24- (1) isolated at pH 3.5 and [(γ-Se2W14O52)4(WO3(H2O))8(W2O5)2(W4O12)2(Mo2O2(μ-S)2(H2O)2)4(Mo2O2(μ-S)2(SeO3))4]36- (2) isolated at pH 2. Both compounds were characterized in the solid state by single-crystal X-ray diffraction, EDX, elemental analysis, TGA, and FT-IR and in solution by ESI-MS and NMR.

KW - BUILDING-BLOCK STRATEGY

KW - DYNAMIC LIBRARY

KW - POLYOXOMETALATE

KW - CLUSTERS

KW - NANOSCALE

KW - UNITS

KW - TEMPLATES

KW - CHEMISTRY

KW - ANION

KW - POLYOXOTUNGSTATES

UR - http://www.scopus.com/inward/record.url?scp=85040055732&partnerID=8YFLogxK

U2 - 10.1021/acs.inorgchem.7b01644

DO - 10.1021/acs.inorgchem.7b01644

M3 - Article

C2 - 29244493

AN - SCOPUS:85040055732

VL - 57

SP - 56

EP - 63

JO - Inorganic Chemistry

JF - Inorganic Chemistry

SN - 0020-1669

IS - 1

ER -

ID: 12081363