Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
PH-Controlled One Pot Syntheses of Giant Mo2O2S2-Containing Seleno-Tungstate Architectures. / Moussawi, Mhamad Aly; Floquet, Sébastien; Abramov, Pavel A. и др.
в: Inorganic Chemistry, Том 57, № 1, 02.01.2018, стр. 56-63.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - PH-Controlled One Pot Syntheses of Giant Mo2O2S2-Containing Seleno-Tungstate Architectures
AU - Moussawi, Mhamad Aly
AU - Floquet, Sébastien
AU - Abramov, Pavel A.
AU - Vicent, Cristian
AU - Haouas, Mohamed
AU - Cadot, Emmanuel
PY - 2018/1/2
Y1 - 2018/1/2
N2 - Self-assembly reactions of Na2WO4, SeO2/SeO3 2-, and [Mo2O2(μ-S)2(H2O)6]2+ give, depending on the pH value, two new large polyoxometalate complexes: i.e., [(γ-Se2W14O52)3(Mo2O2(μ-S)2(H2O)2)6]24- (1) isolated at pH 3.5 and [(γ-Se2W14O52)4(WO3(H2O))8(W2O5)2(W4O12)2(Mo2O2(μ-S)2(H2O)2)4(Mo2O2(μ-S)2(SeO3))4]36- (2) isolated at pH 2. Both compounds were characterized in the solid state by single-crystal X-ray diffraction, EDX, elemental analysis, TGA, and FT-IR and in solution by ESI-MS and NMR.
AB - Self-assembly reactions of Na2WO4, SeO2/SeO3 2-, and [Mo2O2(μ-S)2(H2O)6]2+ give, depending on the pH value, two new large polyoxometalate complexes: i.e., [(γ-Se2W14O52)3(Mo2O2(μ-S)2(H2O)2)6]24- (1) isolated at pH 3.5 and [(γ-Se2W14O52)4(WO3(H2O))8(W2O5)2(W4O12)2(Mo2O2(μ-S)2(H2O)2)4(Mo2O2(μ-S)2(SeO3))4]36- (2) isolated at pH 2. Both compounds were characterized in the solid state by single-crystal X-ray diffraction, EDX, elemental analysis, TGA, and FT-IR and in solution by ESI-MS and NMR.
KW - BUILDING-BLOCK STRATEGY
KW - DYNAMIC LIBRARY
KW - POLYOXOMETALATE
KW - CLUSTERS
KW - NANOSCALE
KW - UNITS
KW - TEMPLATES
KW - CHEMISTRY
KW - ANION
KW - POLYOXOTUNGSTATES
UR - http://www.scopus.com/inward/record.url?scp=85040055732&partnerID=8YFLogxK
U2 - 10.1021/acs.inorgchem.7b01644
DO - 10.1021/acs.inorgchem.7b01644
M3 - Article
C2 - 29244493
AN - SCOPUS:85040055732
VL - 57
SP - 56
EP - 63
JO - Inorganic Chemistry
JF - Inorganic Chemistry
SN - 0020-1669
IS - 1
ER -
ID: 12081363