Research output: Contribution to journal › Article › peer-review
One-pot synthesis of (Mo6I8)4+-doped polystyrene microspheres via a free radical dispersion copolymerisation reaction. / Vorotnikova, Natalya A.; Edeleva, Mariya V.; Kurskaya, Olga G. et al.
In: Polymer International, Vol. 66, No. 12, 01.12.2017, p. 1906-1912.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - One-pot synthesis of (Mo6I8)4+-doped polystyrene microspheres via a free radical dispersion copolymerisation reaction
AU - Vorotnikova, Natalya A.
AU - Edeleva, Mariya V.
AU - Kurskaya, Olga G.
AU - Brylev, Konstantin A.
AU - Shestopalov, Alexander M.
AU - Mironov, Yuri V.
AU - Sutherland, Andrew J.
AU - Efremova, Olga A.
AU - Shestopalov, Michael A.
N1 - Publisher Copyright: © 2017 Society of Chemical Industry
PY - 2017/12/1
Y1 - 2017/12/1
N2 - Molybdenum octahedral clusters, when incorporated into an appropriate polymer matrix, are considered as promising agents for a range of biological applications. This work describes the one-pot synthesis, morphology and cellular toxicity of nano-sized polystyrene beads doped with luminescent cluster complexes [(Mo6X8)(NO3)6]2- (X=Cl, Br or I). Specifically, the particles were obtained by free radical dispersion copolymerisation of styrene and methacrylic acid or 4-vinylpyridine in the presence of the cluster complexes. The effects of the cluster loading in the reaction mixture on both the content of the final material and number-average molar mass of the copolymers were evaluated.
AB - Molybdenum octahedral clusters, when incorporated into an appropriate polymer matrix, are considered as promising agents for a range of biological applications. This work describes the one-pot synthesis, morphology and cellular toxicity of nano-sized polystyrene beads doped with luminescent cluster complexes [(Mo6X8)(NO3)6]2- (X=Cl, Br or I). Specifically, the particles were obtained by free radical dispersion copolymerisation of styrene and methacrylic acid or 4-vinylpyridine in the presence of the cluster complexes. The effects of the cluster loading in the reaction mixture on both the content of the final material and number-average molar mass of the copolymers were evaluated.
KW - copolymer material
KW - free radical polymerisation
KW - luminescence
KW - molybdenum cluster complex
UR - http://www.scopus.com/inward/record.url?scp=85031678536&partnerID=8YFLogxK
UR - https://www.mendeley.com/catalogue/725059c5-bced-31a2-94d9-ff17f79566fd/
U2 - 10.1002/pi.5473
DO - 10.1002/pi.5473
M3 - Article
AN - SCOPUS:85031678536
VL - 66
SP - 1906
EP - 1912
JO - Polymer International
JF - Polymer International
SN - 0959-8103
IS - 12
ER -
ID: 9866246