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Octahedral chalcogenide rhenium cluster complexes with imidazole. / Konovalov, Dmitry I.; Ivanov, Anton A.; Vorotnikov, Yuri A. et al.

In: Polyhedron, Vol. 165, 01.06.2019, p. 79-85.

Research output: Contribution to journalArticlepeer-review

Harvard

Konovalov, DI, Ivanov, AA, Vorotnikov, YA, Smolentsev, AI, Eltsov, IV, Efremova, OA, Kitamura, N, Mironov, YV & Shestopalov, MA 2019, 'Octahedral chalcogenide rhenium cluster complexes with imidazole', Polyhedron, vol. 165, pp. 79-85. https://doi.org/10.1016/j.poly.2019.03.007

APA

Konovalov, D. I., Ivanov, A. A., Vorotnikov, Y. A., Smolentsev, A. I., Eltsov, I. V., Efremova, O. A., Kitamura, N., Mironov, Y. V., & Shestopalov, M. A. (2019). Octahedral chalcogenide rhenium cluster complexes with imidazole. Polyhedron, 165, 79-85. https://doi.org/10.1016/j.poly.2019.03.007

Vancouver

Konovalov DI, Ivanov AA, Vorotnikov YA, Smolentsev AI, Eltsov IV, Efremova OA et al. Octahedral chalcogenide rhenium cluster complexes with imidazole. Polyhedron. 2019 Jun 1;165:79-85. doi: 10.1016/j.poly.2019.03.007

Author

Konovalov, Dmitry I. ; Ivanov, Anton A. ; Vorotnikov, Yuri A. et al. / Octahedral chalcogenide rhenium cluster complexes with imidazole. In: Polyhedron. 2019 ; Vol. 165. pp. 79-85.

BibTeX

@article{1595fa4e159d4f2abaab2b0ff85d35a4,
title = "Octahedral chalcogenide rhenium cluster complexes with imidazole",
abstract = " Reactions of [{Re 6 Q 8 }Br 6 ] 4−/3− (Q = S, Se) with molten imidazole lead to the formation of two new neutral cluster complexes [{Re 6 Q 8 }(imzH) 4 (imz) 2 ] (imzH = imidazole). The interaction of [{Re 6 Q 8 }(imzH) 4 (imz) 2 ] with hydrohalic acids resulted in cationic complexes [{Re 6 Q 8 }(imzH) 6 ]X 2 (X = Cl, Br). All compounds were characterised by X-ray single-crystal and powder diffraction analyses, elemental analysis, energy dispersive X-ray and IR spectroscopies. The luminescence of the neutral compounds [{Re 6 Q 8 }(imzH) 4 (imz) 2 ] was also studied. ",
keywords = "Crystal structure, Imidazole, Luminescence, Protonation, Rhenium cluster, RETENTION, PYRIDINE, CL, SE, LUMINESCENCE, LIGANDS, HEXARHENIUM(III) COMPLEXES, REDOX, METAL, EMISSION",
author = "Konovalov, {Dmitry I.} and Ivanov, {Anton A.} and Vorotnikov, {Yuri A.} and Smolentsev, {Anton I.} and Eltsov, {Ilia V.} and Efremova, {Olga A.} and Noboru Kitamura and Mironov, {Yuri V.} and Shestopalov, {Michael A.}",
note = "Publisher Copyright: {\textcopyright} 2019 Elsevier Ltd",
year = "2019",
month = jun,
day = "1",
doi = "10.1016/j.poly.2019.03.007",
language = "English",
volume = "165",
pages = "79--85",
journal = "Polyhedron",
issn = "0277-5387",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Octahedral chalcogenide rhenium cluster complexes with imidazole

AU - Konovalov, Dmitry I.

AU - Ivanov, Anton A.

AU - Vorotnikov, Yuri A.

AU - Smolentsev, Anton I.

AU - Eltsov, Ilia V.

AU - Efremova, Olga A.

AU - Kitamura, Noboru

AU - Mironov, Yuri V.

AU - Shestopalov, Michael A.

N1 - Publisher Copyright: © 2019 Elsevier Ltd

PY - 2019/6/1

Y1 - 2019/6/1

N2 - Reactions of [{Re 6 Q 8 }Br 6 ] 4−/3− (Q = S, Se) with molten imidazole lead to the formation of two new neutral cluster complexes [{Re 6 Q 8 }(imzH) 4 (imz) 2 ] (imzH = imidazole). The interaction of [{Re 6 Q 8 }(imzH) 4 (imz) 2 ] with hydrohalic acids resulted in cationic complexes [{Re 6 Q 8 }(imzH) 6 ]X 2 (X = Cl, Br). All compounds were characterised by X-ray single-crystal and powder diffraction analyses, elemental analysis, energy dispersive X-ray and IR spectroscopies. The luminescence of the neutral compounds [{Re 6 Q 8 }(imzH) 4 (imz) 2 ] was also studied.

AB - Reactions of [{Re 6 Q 8 }Br 6 ] 4−/3− (Q = S, Se) with molten imidazole lead to the formation of two new neutral cluster complexes [{Re 6 Q 8 }(imzH) 4 (imz) 2 ] (imzH = imidazole). The interaction of [{Re 6 Q 8 }(imzH) 4 (imz) 2 ] with hydrohalic acids resulted in cationic complexes [{Re 6 Q 8 }(imzH) 6 ]X 2 (X = Cl, Br). All compounds were characterised by X-ray single-crystal and powder diffraction analyses, elemental analysis, energy dispersive X-ray and IR spectroscopies. The luminescence of the neutral compounds [{Re 6 Q 8 }(imzH) 4 (imz) 2 ] was also studied.

KW - Crystal structure

KW - Imidazole

KW - Luminescence

KW - Protonation

KW - Rhenium cluster

KW - RETENTION

KW - PYRIDINE

KW - CL

KW - SE

KW - LUMINESCENCE

KW - LIGANDS

KW - HEXARHENIUM(III) COMPLEXES

KW - REDOX

KW - METAL

KW - EMISSION

UR - http://www.scopus.com/inward/record.url?scp=85063519918&partnerID=8YFLogxK

U2 - 10.1016/j.poly.2019.03.007

DO - 10.1016/j.poly.2019.03.007

M3 - Article

AN - SCOPUS:85063519918

VL - 165

SP - 79

EP - 85

JO - Polyhedron

JF - Polyhedron

SN - 0277-5387

ER -

ID: 19029525