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Octahedral chalcogenide rhenium cluster complexes with imidazole. / Konovalov, Dmitry I.; Ivanov, Anton A.; Vorotnikov, Yuri A. и др.
в: Polyhedron, Том 165, 01.06.2019, стр. 79-85.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Octahedral chalcogenide rhenium cluster complexes with imidazole
AU - Konovalov, Dmitry I.
AU - Ivanov, Anton A.
AU - Vorotnikov, Yuri A.
AU - Smolentsev, Anton I.
AU - Eltsov, Ilia V.
AU - Efremova, Olga A.
AU - Kitamura, Noboru
AU - Mironov, Yuri V.
AU - Shestopalov, Michael A.
N1 - Publisher Copyright: © 2019 Elsevier Ltd
PY - 2019/6/1
Y1 - 2019/6/1
N2 - Reactions of [{Re 6 Q 8 }Br 6 ] 4−/3− (Q = S, Se) with molten imidazole lead to the formation of two new neutral cluster complexes [{Re 6 Q 8 }(imzH) 4 (imz) 2 ] (imzH = imidazole). The interaction of [{Re 6 Q 8 }(imzH) 4 (imz) 2 ] with hydrohalic acids resulted in cationic complexes [{Re 6 Q 8 }(imzH) 6 ]X 2 (X = Cl, Br). All compounds were characterised by X-ray single-crystal and powder diffraction analyses, elemental analysis, energy dispersive X-ray and IR spectroscopies. The luminescence of the neutral compounds [{Re 6 Q 8 }(imzH) 4 (imz) 2 ] was also studied.
AB - Reactions of [{Re 6 Q 8 }Br 6 ] 4−/3− (Q = S, Se) with molten imidazole lead to the formation of two new neutral cluster complexes [{Re 6 Q 8 }(imzH) 4 (imz) 2 ] (imzH = imidazole). The interaction of [{Re 6 Q 8 }(imzH) 4 (imz) 2 ] with hydrohalic acids resulted in cationic complexes [{Re 6 Q 8 }(imzH) 6 ]X 2 (X = Cl, Br). All compounds were characterised by X-ray single-crystal and powder diffraction analyses, elemental analysis, energy dispersive X-ray and IR spectroscopies. The luminescence of the neutral compounds [{Re 6 Q 8 }(imzH) 4 (imz) 2 ] was also studied.
KW - Crystal structure
KW - Imidazole
KW - Luminescence
KW - Protonation
KW - Rhenium cluster
KW - RETENTION
KW - PYRIDINE
KW - CL
KW - SE
KW - LUMINESCENCE
KW - LIGANDS
KW - HEXARHENIUM(III) COMPLEXES
KW - REDOX
KW - METAL
KW - EMISSION
UR - http://www.scopus.com/inward/record.url?scp=85063519918&partnerID=8YFLogxK
U2 - 10.1016/j.poly.2019.03.007
DO - 10.1016/j.poly.2019.03.007
M3 - Article
AN - SCOPUS:85063519918
VL - 165
SP - 79
EP - 85
JO - Polyhedron
JF - Polyhedron
SN - 0277-5387
ER -
ID: 19029525