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Novel chalcogenide vanadium complexes with β-diimine ligand : synthesis and structural studies. / Konokhova, A. Yu; Afonin, M. Yu; Sukhikh, T. S. et al.

In: Journal of Coordination Chemistry, Vol. 72, No. 10, 19.05.2019, p. 1661-1670.

Research output: Contribution to journal › Article › peer-review

Harvard

Konokhova, AY, Afonin, MY, Sukhikh, TS & Konchenko, SN 2019, 'Novel chalcogenide vanadium complexes with β-diimine ligand: synthesis and structural studies', Journal of Coordination Chemistry, vol. 72, no. 10, pp. 1661-1670. https://doi.org/10.1080/00958972.2019.1613649

APA

Konokhova, A. Y., Afonin, M. Y., Sukhikh, T. S., & Konchenko, S. N. (2019). Novel chalcogenide vanadium complexes with β-diimine ligand: synthesis and structural studies. Journal of Coordination Chemistry, 72(10), 1661-1670. https://doi.org/10.1080/00958972.2019.1613649

Vancouver

Konokhova AY, Afonin MY, Sukhikh TS, Konchenko SN. Novel chalcogenide vanadium complexes with β-diimine ligand: synthesis and structural studies. Journal of Coordination Chemistry. 2019 May 19;72(10):1661-1670. doi: 10.1080/00958972.2019.1613649

Author

Konokhova, A. Yu ; Afonin, M. Yu ; Sukhikh, T. S. et al. / Novel chalcogenide vanadium complexes with β-diimine ligand : synthesis and structural studies. In: Journal of Coordination Chemistry. 2019 ; Vol. 72, No. 10. pp. 1661-1670.

BibTeX

@article{4f3c9879f6c24ec7ae4577a83e4fc158,
title = "Novel chalcogenide vanadium complexes with β-diimine ligand: synthesis and structural studies",
abstract = " Three new chalcogenide vanadium complexes with a β-diketiminate ligand have been synthesized by reduction of the elemental chalcogens (S, Se, Te) with [(µ-η 6 :η 6 -toluene){V(nacnac)} 2 ] (1) (nacnac = HC(C(Me)NC 6 H 3 - i Pr 2 ) 2 ). The structures of the sulfide and selenide complexes [((nacnac)V = E) 2 (μ,ƞ 2 -E 2 )] (E = S (2), Se (3)) are similar; the chalcogenides act both as bridging (E 2 2- ) and terminal (E 2- ) ligands. In compound [V 2 (µ-Te) 2 (nacnac) 2 ] (4), all tellurium atoms are present only as bridging Te 2- ligands. The compounds have been characterized by IR-spectroscopy, elemental analysis, and single-crystal X-ray diffraction. The possibility of the formation of additional V = Te bonds in 4 has been studied using Hirshfeld analysis. It has been found that the difference in the reactivity of 1 towards Te is not due to the steric hindrance. ",
keywords = "chalcogenides, crystal structure, Vanadium, β-diketiminate ligand, CHEMISTRY, REACTIVITY, CRYSTAL-STRUCTURES, SULFUR, beta-diketiminate ligand, DERIVATIVES",
author = "Konokhova, {A. Yu} and Afonin, {M. Yu} and Sukhikh, {T. S.} and Konchenko, {S. N.}",
year = "2019",
month = may,
day = "19",
doi = "10.1080/00958972.2019.1613649",
language = "English",
volume = "72",
pages = "1661--1670",
journal = "Journal of Coordination Chemistry",
issn = "0095-8972",
publisher = "Taylor and Francis Ltd.",
number = "10",

}

RIS

TY - JOUR

T1 - Novel chalcogenide vanadium complexes with β-diimine ligand

T2 - synthesis and structural studies

AU - Konokhova, A. Yu

AU - Afonin, M. Yu

AU - Sukhikh, T. S.

AU - Konchenko, S. N.

PY - 2019/5/19

Y1 - 2019/5/19

N2 - Three new chalcogenide vanadium complexes with a β-diketiminate ligand have been synthesized by reduction of the elemental chalcogens (S, Se, Te) with [(µ-η 6 :η 6 -toluene){V(nacnac)} 2 ] (1) (nacnac = HC(C(Me)NC 6 H 3 - i Pr 2 ) 2 ). The structures of the sulfide and selenide complexes [((nacnac)V = E) 2 (μ,ƞ 2 -E 2 )] (E = S (2), Se (3)) are similar; the chalcogenides act both as bridging (E 2 2- ) and terminal (E 2- ) ligands. In compound [V 2 (µ-Te) 2 (nacnac) 2 ] (4), all tellurium atoms are present only as bridging Te 2- ligands. The compounds have been characterized by IR-spectroscopy, elemental analysis, and single-crystal X-ray diffraction. The possibility of the formation of additional V = Te bonds in 4 has been studied using Hirshfeld analysis. It has been found that the difference in the reactivity of 1 towards Te is not due to the steric hindrance.

AB - Three new chalcogenide vanadium complexes with a β-diketiminate ligand have been synthesized by reduction of the elemental chalcogens (S, Se, Te) with [(µ-η 6 :η 6 -toluene){V(nacnac)} 2 ] (1) (nacnac = HC(C(Me)NC 6 H 3 - i Pr 2 ) 2 ). The structures of the sulfide and selenide complexes [((nacnac)V = E) 2 (μ,ƞ 2 -E 2 )] (E = S (2), Se (3)) are similar; the chalcogenides act both as bridging (E 2 2- ) and terminal (E 2- ) ligands. In compound [V 2 (µ-Te) 2 (nacnac) 2 ] (4), all tellurium atoms are present only as bridging Te 2- ligands. The compounds have been characterized by IR-spectroscopy, elemental analysis, and single-crystal X-ray diffraction. The possibility of the formation of additional V = Te bonds in 4 has been studied using Hirshfeld analysis. It has been found that the difference in the reactivity of 1 towards Te is not due to the steric hindrance.

KW - chalcogenides

KW - crystal structure

KW - Vanadium

KW - β-diketiminate ligand

KW - CHEMISTRY

KW - REACTIVITY

KW - CRYSTAL-STRUCTURES

KW - SULFUR

KW - beta-diketiminate ligand

KW - DERIVATIVES

UR - http://www.scopus.com/inward/record.url?scp=85065846074&partnerID=8YFLogxK

U2 - 10.1080/00958972.2019.1613649

DO - 10.1080/00958972.2019.1613649

M3 - Article

AN - SCOPUS:85065846074

VL - 72

SP - 1661

EP - 1670

JO - Journal of Coordination Chemistry

JF - Journal of Coordination Chemistry

SN - 0095-8972

IS - 10

ER -

ID: 20045082