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Ni-loaded nanocrystalline ceria-zirconia solid solutions prepared via modified Pechini route as stable to coking catalysts of CH4 dry reforming. / Sadykov, Vladislav A.; Simonov, Mikhail N.; Mezentseva, Natalia V. et al.

In: Open Chemistry, Vol. 14, No. 1, 01.01.2016, p. 363-376.

Research output: Contribution to journal › Article › peer-review

Harvard

Sadykov, VA, Simonov, MN, Mezentseva, NV, Pavlova, SN, Fedorova, YE, Bobin, AS, Bespalko, YN, Ishchenko, AV, Krieger, TA, Glazneva, TS, Larina, TV, Cherepanova, SV, Kaichev, VV, Saraev, AA, Chesalov, YA, Shmakov, AN, Roger, AC & Adamski, A 2016, 'Ni-loaded nanocrystalline ceria-zirconia solid solutions prepared via modified Pechini route as stable to coking catalysts of CH4 dry reforming', Open Chemistry, vol. 14, no. 1, pp. 363-376. https://doi.org/10.1515/chem-2016-0039

APA

Sadykov, V. A., Simonov, M. N., Mezentseva, N. V., Pavlova, S. N., Fedorova, Y. E., Bobin, A. S., Bespalko, Y. N., Ishchenko, A. V., Krieger, T. A., Glazneva, T. S., Larina, T. V., Cherepanova, S. V., Kaichev, V. V., Saraev, A. A., Chesalov, Y. A., Shmakov, A. N., Roger, A. C., & Adamski, A. (2016). Ni-loaded nanocrystalline ceria-zirconia solid solutions prepared via modified Pechini route as stable to coking catalysts of CH4 dry reforming. Open Chemistry, 14(1), 363-376. https://doi.org/10.1515/chem-2016-0039

Vancouver

Sadykov VA, Simonov MN, Mezentseva NV, Pavlova SN, Fedorova YE, Bobin AS et al. Ni-loaded nanocrystalline ceria-zirconia solid solutions prepared via modified Pechini route as stable to coking catalysts of CH4 dry reforming. Open Chemistry. 2016 Jan 1;14(1):363-376. doi: 10.1515/chem-2016-0039

Author

Sadykov, Vladislav A. ; Simonov, Mikhail N. ; Mezentseva, Natalia V. et al. / Ni-loaded nanocrystalline ceria-zirconia solid solutions prepared via modified Pechini route as stable to coking catalysts of CH4 dry reforming. In: Open Chemistry. 2016 ; Vol. 14, No. 1. pp. 363-376.

BibTeX

@article{78620f3767ff405ca4b495804695c730,
title = "Ni-loaded nanocrystalline ceria-zirconia solid solutions prepared via modified Pechini route as stable to coking catalysts of CH4 dry reforming",
abstract = "Mixed nanocrystalline Ce-Zr-O oxides (Ce/Zr = 1 or 7/3) were prepared by modified Pechini route using ethylene glycol solutions of metal salts. Detailed characterization of their real structure and surface properties by X-ray diffraction on synchrotron radiation with the full-profile Rietveld analysis, high resolution electron microscopy with elemental analysis, Raman spectroscopy, UV-Vis and X-ray photoelectron spectroscopy revealed a high homogeneity of cations distribution in nanodomains resulting in stabilization of disordered cubic phase. This provides a high dispersion of NiO loaded on these mixed oxides by wet impregnation, a high reactivity and mobility of oxygen in these catalysts and strong interaction of Ni with support in the reduced state. This helps to achieve a high activity and coking stability of developed catalysts in CH4 dry reforming in feeds with CH4 concentration up to 15% and CH4/CO2 ratio =1.",
keywords = "Ce-Zr-O oxide, coking stability, methane dry reforming, Ni stabilization",
author = "Sadykov, {Vladislav A.} and Simonov, {Mikhail N.} and Mezentseva, {Natalia V.} and Pavlova, {Svetlana N.} and Fedorova, {Yulia E.} and Bobin, {Aleksei S.} and Bespalko, {Yulia N.} and Ishchenko, {Arcady V.} and Krieger, {Tamara A.} and Glazneva, {Tatiana S.} and Larina, {Tatyana V.} and Cherepanova, {Svetlana V.} and Kaichev, {Vasilii V.} and Saraev, {Andrey A.} and Chesalov, {Yurii A.} and Shmakov, {Aleksandr N.} and Roger, {Anne Cecile} and Andrzej Adamski",
year = "2016",
month = jan,
day = "1",
doi = "10.1515/chem-2016-0039",
language = "English",
volume = "14",
pages = "363--376",
journal = "Open Chemistry",
issn = "2391-5420",
publisher = "Walter de Gruyter GmbH",
number = "1",

}

RIS

TY - JOUR

T1 - Ni-loaded nanocrystalline ceria-zirconia solid solutions prepared via modified Pechini route as stable to coking catalysts of CH4 dry reforming

AU - Sadykov, Vladislav A.

AU - Simonov, Mikhail N.

AU - Mezentseva, Natalia V.

AU - Pavlova, Svetlana N.

AU - Fedorova, Yulia E.

AU - Bobin, Aleksei S.

AU - Bespalko, Yulia N.

AU - Ishchenko, Arcady V.

AU - Krieger, Tamara A.

AU - Glazneva, Tatiana S.

AU - Larina, Tatyana V.

AU - Cherepanova, Svetlana V.

AU - Kaichev, Vasilii V.

AU - Saraev, Andrey A.

AU - Chesalov, Yurii A.

AU - Shmakov, Aleksandr N.

AU - Roger, Anne Cecile

AU - Adamski, Andrzej

PY - 2016/1/1

Y1 - 2016/1/1

N2 - Mixed nanocrystalline Ce-Zr-O oxides (Ce/Zr = 1 or 7/3) were prepared by modified Pechini route using ethylene glycol solutions of metal salts. Detailed characterization of their real structure and surface properties by X-ray diffraction on synchrotron radiation with the full-profile Rietveld analysis, high resolution electron microscopy with elemental analysis, Raman spectroscopy, UV-Vis and X-ray photoelectron spectroscopy revealed a high homogeneity of cations distribution in nanodomains resulting in stabilization of disordered cubic phase. This provides a high dispersion of NiO loaded on these mixed oxides by wet impregnation, a high reactivity and mobility of oxygen in these catalysts and strong interaction of Ni with support in the reduced state. This helps to achieve a high activity and coking stability of developed catalysts in CH4 dry reforming in feeds with CH4 concentration up to 15% and CH4/CO2 ratio =1.

AB - Mixed nanocrystalline Ce-Zr-O oxides (Ce/Zr = 1 or 7/3) were prepared by modified Pechini route using ethylene glycol solutions of metal salts. Detailed characterization of their real structure and surface properties by X-ray diffraction on synchrotron radiation with the full-profile Rietveld analysis, high resolution electron microscopy with elemental analysis, Raman spectroscopy, UV-Vis and X-ray photoelectron spectroscopy revealed a high homogeneity of cations distribution in nanodomains resulting in stabilization of disordered cubic phase. This provides a high dispersion of NiO loaded on these mixed oxides by wet impregnation, a high reactivity and mobility of oxygen in these catalysts and strong interaction of Ni with support in the reduced state. This helps to achieve a high activity and coking stability of developed catalysts in CH4 dry reforming in feeds with CH4 concentration up to 15% and CH4/CO2 ratio =1.

KW - Ce-Zr-O oxide

KW - coking stability

KW - methane dry reforming

KW - Ni stabilization

UR - http://www.scopus.com/inward/record.url?scp=85013192693&partnerID=8YFLogxK

U2 - 10.1515/chem-2016-0039

DO - 10.1515/chem-2016-0039

M3 - Article

AN - SCOPUS:85013192693

VL - 14

SP - 363

EP - 376

JO - Open Chemistry

JF - Open Chemistry

SN - 2391-5420

IS - 1

ER -

ID: 25394477