Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Ni-loaded nanocrystalline ceria-zirconia solid solutions prepared via modified Pechini route as stable to coking catalysts of CH4 dry reforming. / Sadykov, Vladislav A.; Simonov, Mikhail N.; Mezentseva, Natalia V. и др.
в: Open Chemistry, Том 14, № 1, 01.01.2016, стр. 363-376.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Ni-loaded nanocrystalline ceria-zirconia solid solutions prepared via modified Pechini route as stable to coking catalysts of CH4 dry reforming
AU - Sadykov, Vladislav A.
AU - Simonov, Mikhail N.
AU - Mezentseva, Natalia V.
AU - Pavlova, Svetlana N.
AU - Fedorova, Yulia E.
AU - Bobin, Aleksei S.
AU - Bespalko, Yulia N.
AU - Ishchenko, Arcady V.
AU - Krieger, Tamara A.
AU - Glazneva, Tatiana S.
AU - Larina, Tatyana V.
AU - Cherepanova, Svetlana V.
AU - Kaichev, Vasilii V.
AU - Saraev, Andrey A.
AU - Chesalov, Yurii A.
AU - Shmakov, Aleksandr N.
AU - Roger, Anne Cecile
AU - Adamski, Andrzej
PY - 2016/1/1
Y1 - 2016/1/1
N2 - Mixed nanocrystalline Ce-Zr-O oxides (Ce/Zr = 1 or 7/3) were prepared by modified Pechini route using ethylene glycol solutions of metal salts. Detailed characterization of their real structure and surface properties by X-ray diffraction on synchrotron radiation with the full-profile Rietveld analysis, high resolution electron microscopy with elemental analysis, Raman spectroscopy, UV-Vis and X-ray photoelectron spectroscopy revealed a high homogeneity of cations distribution in nanodomains resulting in stabilization of disordered cubic phase. This provides a high dispersion of NiO loaded on these mixed oxides by wet impregnation, a high reactivity and mobility of oxygen in these catalysts and strong interaction of Ni with support in the reduced state. This helps to achieve a high activity and coking stability of developed catalysts in CH4 dry reforming in feeds with CH4 concentration up to 15% and CH4/CO2 ratio =1.
AB - Mixed nanocrystalline Ce-Zr-O oxides (Ce/Zr = 1 or 7/3) were prepared by modified Pechini route using ethylene glycol solutions of metal salts. Detailed characterization of their real structure and surface properties by X-ray diffraction on synchrotron radiation with the full-profile Rietveld analysis, high resolution electron microscopy with elemental analysis, Raman spectroscopy, UV-Vis and X-ray photoelectron spectroscopy revealed a high homogeneity of cations distribution in nanodomains resulting in stabilization of disordered cubic phase. This provides a high dispersion of NiO loaded on these mixed oxides by wet impregnation, a high reactivity and mobility of oxygen in these catalysts and strong interaction of Ni with support in the reduced state. This helps to achieve a high activity and coking stability of developed catalysts in CH4 dry reforming in feeds with CH4 concentration up to 15% and CH4/CO2 ratio =1.
KW - Ce-Zr-O oxide
KW - coking stability
KW - methane dry reforming
KW - Ni stabilization
UR - http://www.scopus.com/inward/record.url?scp=85013192693&partnerID=8YFLogxK
U2 - 10.1515/chem-2016-0039
DO - 10.1515/chem-2016-0039
M3 - Article
AN - SCOPUS:85013192693
VL - 14
SP - 363
EP - 376
JO - Open Chemistry
JF - Open Chemistry
SN - 2391-5420
IS - 1
ER -
ID: 25394477