NEW γ-SUBSTITUTED β-DIKETONATES OF Al(III), Fe(III), AND Cu(II)

Standard

NEW γ-SUBSTITUTED β-DIKETONATES OF Al(III), Fe(III), AND Cu(II). / Stabnikov, P. A.; Alferova, N.; Korolkov, I. et al.

In: Journal of Structural Chemistry, Vol. 61, No. 10, 10.2020, p. 1615-1623.

Research output: Contribution to journal › Article › peer-review

Harvard

Stabnikov, PA, Alferova, N, Korolkov, I, Pervukhina, N, Trubin, S, Babailov, SP & Turgambaeva, AE 2020, 'NEW γ-SUBSTITUTED β-DIKETONATES OF Al(III), Fe(III), AND Cu(II)', Journal of Structural Chemistry, vol. 61, no. 10, pp. 1615-1623. https://doi.org/10.1134/S0022476620100145

APA

Stabnikov, P. A., Alferova, N., Korolkov, I., Pervukhina, N., Trubin, S., Babailov, S. P., & Turgambaeva, A. E. (2020). NEW γ-SUBSTITUTED β-DIKETONATES OF Al(III), Fe(III), AND Cu(II). Journal of Structural Chemistry, 61(10), 1615-1623. https://doi.org/10.1134/S0022476620100145

Vancouver

Stabnikov PA, Alferova N, Korolkov I, Pervukhina N, Trubin S, Babailov SP et al. NEW γ-SUBSTITUTED β-DIKETONATES OF Al(III), Fe(III), AND Cu(II). Journal of Structural Chemistry. 2020 Oct;61(10):1615-1623. doi: 10.1134/S0022476620100145

Author

Stabnikov, P. A. ; Alferova, N. ; Korolkov, I. et al. / NEW γ-SUBSTITUTED β-DIKETONATES OF Al(III), Fe(III), AND Cu(II). In: Journal of Structural Chemistry. 2020 ; Vol. 61, No. 10. pp. 1615-1623.

BibTeX

@article{b6caa816f348465db42a86e620af6be7,

title = "NEW γ-SUBSTITUTED β-DIKETONATES OF Al(III), Fe(III), AND Cu(II)",

abstract = "Abstract: The structures of two Al(III) and Fe(III) β-diketonates with a γ-substituted ligand are studied by single crystal X-ray diffraction at 150(2) K. Crystallographic data for Al(γ-Me-hd) 3 (I) are: space group P 1, a = 10.855(1) {\AA}, b = 11.129(1) {\AA}, с = 11.894(1) {\AA}, α = 85.634(3)°, F0200062 = 73.118(3)°, γ = 66.771(3)°, V = 1262.2(2) {\AA} 3, Z = 2, R 1 = 0.0438. For Fe(γ-Me-hd) 3 (II): space group P2 1/с, a = 10.0374(5) {\AA}, b = 17.0798(7) {\AA}, с = 15.7213(6) {\AA}, F0200062 = 107.459(1)°, V = 2571.1(2) {\AA} 3, Z = 4, R 1 = 0.0364. Compounds I and II are isotypical because their molecules have the same structure but crystallize in different crystal systems. The crystal structures of I and II are molecular and consist of discrete M(γ-Me-hd) 3 (M = Al, Fe) molecules. Thermogravimetric studies show that complexes I and II are similarly volatile. For Cu(γ-Me-hd) 2 complex (III) the saturated vapor pressure is measured by the Knudsen method in the temperature range 100-150 °C. Sublimation thermodynamic parameters are found and vapor thermolysis is investigated. ",

keywords = "substituted metal beta-diketonates, crystal structure, volatility, MOCVD precursors, MOLECULAR-STRUCTURE, CRYSTAL-STRUCTURES, VOLATILITY, substituted metal β-diketonates",

author = "Stabnikov, {P. A.} and N. Alferova and I. Korolkov and N. Pervukhina and S. Trubin and Babailov, {S. P.} and Turgambaeva, {A. E.}",

year = "2020",

month = oct,

doi = "10.1134/S0022476620100145",

language = "English",

volume = "61",

pages = "1615--1623",

journal = "Journal of Structural Chemistry",

issn = "0022-4766",

publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",

number = "10",

}

RIS

TY - JOUR

T1 - NEW γ-SUBSTITUTED β-DIKETONATES OF Al(III), Fe(III), AND Cu(II)

AU - Stabnikov, P. A.

AU - Alferova, N.

AU - Korolkov, I.

AU - Pervukhina, N.

AU - Trubin, S.

AU - Babailov, S. P.

AU - Turgambaeva, A. E.

PY - 2020/10

Y1 - 2020/10

N2 - Abstract: The structures of two Al(III) and Fe(III) β-diketonates with a γ-substituted ligand are studied by single crystal X-ray diffraction at 150(2) K. Crystallographic data for Al(γ-Me-hd) 3 (I) are: space group P 1, a = 10.855(1) Å, b = 11.129(1) Å, с = 11.894(1) Å, α = 85.634(3)°, F0200062 = 73.118(3)°, γ = 66.771(3)°, V = 1262.2(2) Å 3, Z = 2, R 1 = 0.0438. For Fe(γ-Me-hd) 3 (II): space group P2 1/с, a = 10.0374(5) Å, b = 17.0798(7) Å, с = 15.7213(6) Å, F0200062 = 107.459(1)°, V = 2571.1(2) Å 3, Z = 4, R 1 = 0.0364. Compounds I and II are isotypical because their molecules have the same structure but crystallize in different crystal systems. The crystal structures of I and II are molecular and consist of discrete M(γ-Me-hd) 3 (M = Al, Fe) molecules. Thermogravimetric studies show that complexes I and II are similarly volatile. For Cu(γ-Me-hd) 2 complex (III) the saturated vapor pressure is measured by the Knudsen method in the temperature range 100-150 °C. Sublimation thermodynamic parameters are found and vapor thermolysis is investigated.

AB - Abstract: The structures of two Al(III) and Fe(III) β-diketonates with a γ-substituted ligand are studied by single crystal X-ray diffraction at 150(2) K. Crystallographic data for Al(γ-Me-hd) 3 (I) are: space group P 1, a = 10.855(1) Å, b = 11.129(1) Å, с = 11.894(1) Å, α = 85.634(3)°, F0200062 = 73.118(3)°, γ = 66.771(3)°, V = 1262.2(2) Å 3, Z = 2, R 1 = 0.0438. For Fe(γ-Me-hd) 3 (II): space group P2 1/с, a = 10.0374(5) Å, b = 17.0798(7) Å, с = 15.7213(6) Å, F0200062 = 107.459(1)°, V = 2571.1(2) Å 3, Z = 4, R 1 = 0.0364. Compounds I and II are isotypical because their molecules have the same structure but crystallize in different crystal systems. The crystal structures of I and II are molecular and consist of discrete M(γ-Me-hd) 3 (M = Al, Fe) molecules. Thermogravimetric studies show that complexes I and II are similarly volatile. For Cu(γ-Me-hd) 2 complex (III) the saturated vapor pressure is measured by the Knudsen method in the temperature range 100-150 °C. Sublimation thermodynamic parameters are found and vapor thermolysis is investigated.

KW - substituted metal beta-diketonates

KW - crystal structure

KW - volatility

KW - MOCVD precursors

KW - MOLECULAR-STRUCTURE

KW - CRYSTAL-STRUCTURES

KW - VOLATILITY

KW - substituted metal β-diketonates

UR - http://www.scopus.com/inward/record.url?scp=85106819742&partnerID=8YFLogxK

U2 - 10.1134/S0022476620100145

DO - 10.1134/S0022476620100145

M3 - Article

VL - 61

SP - 1615

EP - 1623

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 10

ER -

ID: 27359825