Research output: Contribution to journal › Article › peer-review
New red-luminescent cadmium coordination polymers with 4-amino-2,1,3-benzothiadiazole. / Sukhikh, T. S.; Ogienko, D. S.; Bashirov, D. A. et al.
In: Journal of Coordination Chemistry, Vol. 69, No. 21, 15.09.2016, p. 3284-3293.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - New red-luminescent cadmium coordination polymers with 4-amino-2,1,3-benzothiadiazole
AU - Sukhikh, T. S.
AU - Ogienko, D. S.
AU - Bashirov, D. A.
AU - Kuratieva, N. V.
AU - Komarov, V. Yu
AU - Rakhmanova, M. I.
AU - Konchenko, S. N.
PY - 2016/9/15
Y1 - 2016/9/15
N2 - New polymeric cadmium complexes, α-[CdLCl2]n (1), [CdL2Cl2]n (2) and β-[CdLCl2]n (3) (L = 4-amino-2,1,3-benzothiadiazole), were obtained as products of the reaction of CdCl2 with L. The synthetic procedures allowing isolation of pure 1–3 were optimized. The structures of 1–3 were established by single-crystal X-ray diffraction and the compounds were characterized by UV–Vis and IR spectroscopy. In these compounds, L is either μ-bridging (1) or terminal (2 and 3). The UV–Vis spectra of the complexes in the solid state resemble that of free L. However, coordination of L leads to a significant shift of emission in photoluminescence spectra from yellow (free L) to red (1–3).
AB - New polymeric cadmium complexes, α-[CdLCl2]n (1), [CdL2Cl2]n (2) and β-[CdLCl2]n (3) (L = 4-amino-2,1,3-benzothiadiazole), were obtained as products of the reaction of CdCl2 with L. The synthetic procedures allowing isolation of pure 1–3 were optimized. The structures of 1–3 were established by single-crystal X-ray diffraction and the compounds were characterized by UV–Vis and IR spectroscopy. In these compounds, L is either μ-bridging (1) or terminal (2 and 3). The UV–Vis spectra of the complexes in the solid state resemble that of free L. However, coordination of L leads to a significant shift of emission in photoluminescence spectra from yellow (free L) to red (1–3).
KW - Benzothiadiazole
KW - Cadmium
KW - Photoluminescence
KW - Polymer
KW - Red emission
UR - http://www.scopus.com/inward/record.url?scp=84987914582&partnerID=8YFLogxK
U2 - 10.1080/00958972.2016.1231304
DO - 10.1080/00958972.2016.1231304
M3 - Article
AN - SCOPUS:84987914582
VL - 69
SP - 3284
EP - 3293
JO - Journal of Coordination Chemistry
JF - Journal of Coordination Chemistry
SN - 0095-8972
IS - 21
ER -
ID: 25413724