Standard

New fluoride borate with ‘anti-zeolite’ structure : A possible link to Ba3(BO3)2. / Rashchenko, Sergey V.; Bekker, Tatyana B.; Bakakin, Vladimir V. et al.

In: Journal of Alloys and Compounds, Vol. 694, 15.02.2017, p. 1196-1200.

Research output: Contribution to journal › Article › peer-review

Harvard

Rashchenko, SV, Bekker, TB, Bakakin, VV, Seryotkin, YV, Simonova, EA & Goryainov, SV 2017, 'New fluoride borate with ‘anti-zeolite’ structure: A possible link to Ba3(BO3)2', Journal of Alloys and Compounds, vol. 694, pp. 1196-1200. https://doi.org/10.1016/j.jallcom.2016.10.119

APA

Rashchenko, S. V., Bekker, T. B., Bakakin, V. V., Seryotkin, Y. V., Simonova, E. A., & Goryainov, S. V. (2017). New fluoride borate with ‘anti-zeolite’ structure: A possible link to Ba3(BO3)2. Journal of Alloys and Compounds, 694, 1196-1200. https://doi.org/10.1016/j.jallcom.2016.10.119

Vancouver

Rashchenko SV, Bekker TB, Bakakin VV, Seryotkin YV, Simonova EA, Goryainov SV. New fluoride borate with ‘anti-zeolite’ structure: A possible link to Ba3(BO3)2. Journal of Alloys and Compounds. 2017 Feb 15;694:1196-1200. doi: 10.1016/j.jallcom.2016.10.119

Author

Rashchenko, Sergey V. ; Bekker, Tatyana B. ; Bakakin, Vladimir V. et al. / New fluoride borate with ‘anti-zeolite’ structure : A possible link to Ba3(BO3)2. In: Journal of Alloys and Compounds. 2017 ; Vol. 694. pp. 1196-1200.

BibTeX

@article{5b526600a3d54ea5bbe5507debca1739,
title = "New fluoride borate with {\textquoteleft}anti-zeolite{\textquoteright} structure: A possible link to Ba3(BO3)2",
abstract = "Crystal growth and structure solution of new Ba3(BO3)2–xF3xsolid solution with x = 0.2 (Pbam, a = 13.60119 {\AA}, b = 13.65014 {\AA}, c = 14.87279 {\AA}) were performed. The solved structure demonstrate an unusual for borates feature – the presence of [Ba12(BO3)6]6+cation pattern with channels filled by disordered anions. We identify the same cation pattern also in two recently described LiBa12(BO3)7F4and NaBa12(BO3)7F4borates, where additional (LiF4)3–and (NaF4)3–anionic clusters are situated inside the channels as well. The unit cell metrics of the new solid solution fits well that reported for Ba3(BO3)2compound, indicating that the latter may represent the orthoborate end-member of Ba3(BO3)2–xF3x.",
keywords = "Anti-zeolite, Barium orthoborate, Channels, Color centers, Solid solution, BARIUM TETRABORATE, CRYSTAL-STRUCTURE, TEMPERATURE FORM",
author = "Rashchenko, {Sergey V.} and Bekker, {Tatyana B.} and Bakakin, {Vladimir V.} and Seryotkin, {Yurii V.} and Simonova, {Ekaterina A.} and Goryainov, {Sergey V.}",
note = "Publisher Copyright: {\textcopyright} 2016 Elsevier B.V.",
year = "2017",
month = feb,
day = "15",
doi = "10.1016/j.jallcom.2016.10.119",
language = "English",
volume = "694",
pages = "1196--1200",
journal = "Journal of Alloys and Compounds",
issn = "0925-8388",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - New fluoride borate with ‘anti-zeolite’ structure

T2 - A possible link to Ba3(BO3)2

AU - Rashchenko, Sergey V.

AU - Bekker, Tatyana B.

AU - Bakakin, Vladimir V.

AU - Seryotkin, Yurii V.

AU - Simonova, Ekaterina A.

AU - Goryainov, Sergey V.

N1 - Publisher Copyright: © 2016 Elsevier B.V.

PY - 2017/2/15

Y1 - 2017/2/15

N2 - Crystal growth and structure solution of new Ba3(BO3)2–xF3xsolid solution with x = 0.2 (Pbam, a = 13.60119 Å, b = 13.65014 Å, c = 14.87279 Å) were performed. The solved structure demonstrate an unusual for borates feature – the presence of [Ba12(BO3)6]6+cation pattern with channels filled by disordered anions. We identify the same cation pattern also in two recently described LiBa12(BO3)7F4and NaBa12(BO3)7F4borates, where additional (LiF4)3–and (NaF4)3–anionic clusters are situated inside the channels as well. The unit cell metrics of the new solid solution fits well that reported for Ba3(BO3)2compound, indicating that the latter may represent the orthoborate end-member of Ba3(BO3)2–xF3x.

AB - Crystal growth and structure solution of new Ba3(BO3)2–xF3xsolid solution with x = 0.2 (Pbam, a = 13.60119 Å, b = 13.65014 Å, c = 14.87279 Å) were performed. The solved structure demonstrate an unusual for borates feature – the presence of [Ba12(BO3)6]6+cation pattern with channels filled by disordered anions. We identify the same cation pattern also in two recently described LiBa12(BO3)7F4and NaBa12(BO3)7F4borates, where additional (LiF4)3–and (NaF4)3–anionic clusters are situated inside the channels as well. The unit cell metrics of the new solid solution fits well that reported for Ba3(BO3)2compound, indicating that the latter may represent the orthoborate end-member of Ba3(BO3)2–xF3x.

KW - Anti-zeolite

KW - Barium orthoborate

KW - Channels

KW - Color centers

KW - Solid solution

KW - BARIUM TETRABORATE

KW - CRYSTAL-STRUCTURE

KW - TEMPERATURE FORM

UR - http://www.scopus.com/inward/record.url?scp=84992316915&partnerID=8YFLogxK

U2 - 10.1016/j.jallcom.2016.10.119

DO - 10.1016/j.jallcom.2016.10.119

M3 - Article

AN - SCOPUS:84992316915

VL - 694

SP - 1196

EP - 1200

JO - Journal of Alloys and Compounds

JF - Journal of Alloys and Compounds

SN - 0925-8388

ER -

ID: 10320869