Research output: Contribution to journal › Article › peer-review
New Chalcogenide Cobalt Complexes with Diimine Ligands : Synthesis and Crystal Structure. / Konokhova, A. Yu; Afonin, M. Yu; Sukhikh, T. S. et al.
In: Journal of Structural Chemistry, Vol. 60, No. 9, 01.09.2019, p. 1463-1467.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - New Chalcogenide Cobalt Complexes with Diimine Ligands
T2 - Synthesis and Crystal Structure
AU - Konokhova, A. Yu
AU - Afonin, M. Yu
AU - Sukhikh, T. S.
AU - Konchenko, S. N.
N1 - Publisher Copyright: © 2019, Pleiades Publishing, Inc. Copyright: Copyright 2019 Elsevier B.V., All rights reserved.
PY - 2019/9/1
Y1 - 2019/9/1
N2 - Reactions of a low-valent cobalt complex [Co(nacnac)(η6-C7H8)] (1) ((nacnac)− = (HC(C(Me)NC6H3-iPr2)2)−) with selenium and tellurium are studied. Two new binuclear complexes [(Co(nacnac))2(μ,η2-Se2)] (2) and [(Co(nacnac))2(μ,η2-Te2)] (3) have been isolated and characterized. The structures of the complexes are determined by single crystal X-ray diffraction.
AB - Reactions of a low-valent cobalt complex [Co(nacnac)(η6-C7H8)] (1) ((nacnac)− = (HC(C(Me)NC6H3-iPr2)2)−) with selenium and tellurium are studied. Two new binuclear complexes [(Co(nacnac))2(μ,η2-Se2)] (2) and [(Co(nacnac))2(μ,η2-Te2)] (3) have been isolated and characterized. The structures of the complexes are determined by single crystal X-ray diffraction.
KW - binuclear complexes
KW - cobalt
KW - crystal structure
KW - selenium
KW - tellurium
KW - PRECURSOR
UR - http://www.scopus.com/inward/record.url?scp=85073187196&partnerID=8YFLogxK
U2 - 10.1134/S0022476619090105
DO - 10.1134/S0022476619090105
M3 - Article
AN - SCOPUS:85073187196
VL - 60
SP - 1463
EP - 1467
JO - Journal of Structural Chemistry
JF - Journal of Structural Chemistry
SN - 0022-4766
IS - 9
ER -
ID: 21858252