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Mixed Amidohalotantalates [Ta(NMe2)3X3]– (X = F, Cl). / Petrov, P. A.; Golubitskaya, E. A.; Kompan’kov, N. B. et al.

In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Vol. 46, No. 9, 01.09.2020, p. 593-599.

Research output: Contribution to journal › Article › peer-review

Harvard

Petrov, PA, Golubitskaya, EA, Kompan’kov, NB, Sukhikh, TS & Sokolov, MN 2020, 'Mixed Amidohalotantalates [Ta(NMe2)3X3]– (X = F, Cl)', Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 46, no. 9, pp. 593-599. https://doi.org/10.1134/S1070328420080059

APA

Petrov, P. A., Golubitskaya, E. A., Kompan’kov, N. B., Sukhikh, T. S., & Sokolov, M. N. (2020). Mixed Amidohalotantalates [Ta(NMe2)3X3]– (X = F, Cl). Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 46(9), 593-599. https://doi.org/10.1134/S1070328420080059

Vancouver

Petrov PA, Golubitskaya EA, Kompan’kov NB, Sukhikh TS, Sokolov MN. Mixed Amidohalotantalates [Ta(NMe2)3X3]– (X = F, Cl). Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2020 Sept 1;46(9):593-599. doi: 10.1134/S1070328420080059

Author

Petrov, P. A. ; Golubitskaya, E. A. ; Kompan’kov, N. B. et al. / Mixed Amidohalotantalates [Ta(NMe2)3X3]– (X = F, Cl). In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2020 ; Vol. 46, No. 9. pp. 593-599.

BibTeX

@article{c34cf70b72bb4c20b77e326b6e138e4b,
title = "Mixed Amidohalotantalates [Ta(NMe2)3X3]– (X = F, Cl)",
abstract = "The anionic tantalum complex (ItBuH)[Ta(NMe2)3Cl3] (I) is synthesized by the reaction of [Ta(NMe2)3Cl2]2 with N-heterocyclic carbene ItBu and is isolated as two crystalline modifications (Ia and Ib). Its fluoride analogue (ItBuH)[Ta(NMe2)3F3] (II) is synthesized by the reaction of Ta(NMe2)5 with (ItBuH)BF4. The structures of the complexes are determined by X-ray diffraction analysis (CIF files CCDC nos. 1977540 (Ia), 1977541 (Ib), and 1977542 (II)).",
keywords = "amides, halogens, N-heterocyclic carbenes, tantalum, X-ray diffraction analysis, CVD, METAL-NITROGEN BONDS, NIOBIUM, CHEMICAL-VAPOR-DEPOSITION, TANTALUM(V), COMPLEXES, CRYSTAL",
author = "Petrov, {P. A.} and Golubitskaya, {E. A.} and Kompan{\textquoteright}kov, {N. B.} and Sukhikh, {T. S.} and Sokolov, {M. N.}",
year = "2020",
month = sep,
day = "1",
doi = "10.1134/S1070328420080059",
language = "English",
volume = "46",
pages = "593--599",
journal = "Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya",
issn = "1070-3284",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "9",

}

RIS

TY - JOUR

T1 - Mixed Amidohalotantalates [Ta(NMe2)3X3]– (X = F, Cl)

AU - Petrov, P. A.

AU - Golubitskaya, E. A.

AU - Kompan’kov, N. B.

AU - Sukhikh, T. S.

AU - Sokolov, M. N.

PY - 2020/9/1

Y1 - 2020/9/1

N2 - The anionic tantalum complex (ItBuH)[Ta(NMe2)3Cl3] (I) is synthesized by the reaction of [Ta(NMe2)3Cl2]2 with N-heterocyclic carbene ItBu and is isolated as two crystalline modifications (Ia and Ib). Its fluoride analogue (ItBuH)[Ta(NMe2)3F3] (II) is synthesized by the reaction of Ta(NMe2)5 with (ItBuH)BF4. The structures of the complexes are determined by X-ray diffraction analysis (CIF files CCDC nos. 1977540 (Ia), 1977541 (Ib), and 1977542 (II)).

AB - The anionic tantalum complex (ItBuH)[Ta(NMe2)3Cl3] (I) is synthesized by the reaction of [Ta(NMe2)3Cl2]2 with N-heterocyclic carbene ItBu and is isolated as two crystalline modifications (Ia and Ib). Its fluoride analogue (ItBuH)[Ta(NMe2)3F3] (II) is synthesized by the reaction of Ta(NMe2)5 with (ItBuH)BF4. The structures of the complexes are determined by X-ray diffraction analysis (CIF files CCDC nos. 1977540 (Ia), 1977541 (Ib), and 1977542 (II)).

KW - amides

KW - halogens

KW - N-heterocyclic carbenes

KW - tantalum

KW - X-ray diffraction analysis

KW - CVD

KW - METAL-NITROGEN BONDS

KW - NIOBIUM

KW - CHEMICAL-VAPOR-DEPOSITION

KW - TANTALUM(V)

KW - COMPLEXES

KW - CRYSTAL

UR - http://www.scopus.com/inward/record.url?scp=85090399803&partnerID=8YFLogxK

U2 - 10.1134/S1070328420080059

DO - 10.1134/S1070328420080059

M3 - Article

AN - SCOPUS:85090399803

VL - 46

SP - 593

EP - 599

JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

SN - 1070-3284

IS - 9

ER -

ID: 25298695