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Luminescent coordination polymers based on Ca2+ and octahedral cluster anions [{M6Cli 8}Cla 6]2- (M = Mo, W) : Synthesis and thermal stability studies. / Evtushok, Darya V.; Vorotnikova, Natalya A.; Logvinenko, Vladimir A. et al.

In: New Journal of Chemistry, Vol. 41, No. 24, 21.12.2017, p. 14855-14861.

Research output: Contribution to journal › Article › peer-review

Harvard

Evtushok, DV, Vorotnikova, NA, Logvinenko, VA, Smolentsev, AI, Brylev, KA, Plyusnin, PE, Pishchur, DP, Kitamura, N, Mironov, YV, Solovieva, AO, Efremova, OA & Shestopalov, MA 2017, 'Luminescent coordination polymers based on Ca2+ and octahedral cluster anions [{M6Cli 8}Cla 6]2- (M = Mo, W): Synthesis and thermal stability studies', New Journal of Chemistry, vol. 41, no. 24, pp. 14855-14861. https://doi.org/10.1039/c7nj02858j

APA

Evtushok, D. V., Vorotnikova, N. A., Logvinenko, V. A., Smolentsev, A. I., Brylev, K. A., Plyusnin, P. E., Pishchur, D. P., Kitamura, N., Mironov, Y. V., Solovieva, A. O., Efremova, O. A., & Shestopalov, M. A. (2017). Luminescent coordination polymers based on Ca2+ and octahedral cluster anions [{M6Cli 8}Cla 6]2- (M = Mo, W): Synthesis and thermal stability studies. New Journal of Chemistry, 41(24), 14855-14861. https://doi.org/10.1039/c7nj02858j

Vancouver

Evtushok DV, Vorotnikova NA, Logvinenko VA, Smolentsev AI, Brylev KA, Plyusnin PE et al. Luminescent coordination polymers based on Ca2+ and octahedral cluster anions [{M6Cli 8}Cla 6]2- (M = Mo, W): Synthesis and thermal stability studies. New Journal of Chemistry. 2017 Dec 21;41(24):14855-14861. doi: 10.1039/c7nj02858j

Author

Evtushok, Darya V. ; Vorotnikova, Natalya A. ; Logvinenko, Vladimir A. et al. / Luminescent coordination polymers based on Ca2+ and octahedral cluster anions [{M6Cli 8}Cla 6]2- (M = Mo, W) : Synthesis and thermal stability studies. In: New Journal of Chemistry. 2017 ; Vol. 41, No. 24. pp. 14855-14861.

BibTeX

@article{7251ee7aed794936a715e18e025f8a3b,
title = "Luminescent coordination polymers based on Ca2+ and octahedral cluster anions [{M6Cli 8}Cla 6]2- (M = Mo, W): Synthesis and thermal stability studies",
abstract = "Luminescent coordination polymers (CPs) based on inexpensive stable precursors are attractive materials for applications. Here we report the synthesis and evaluation of the stability and photophysical characteristics of the first examples of phosphorescent CPs based on octahedral molybdenum and tungsten cluster anions. In particular, 1D CP trans-[{Ca(OPPh3)4}{{M6Cli 8}Cla 6}]∞ (M = Mo, W) can be obtained either directly at increased temperature or via intermediate phases [cis-Ca(OPPh3)4(H2O)2][{M6Cli 8}Cla 6]·2CH3CN that are stable at room-temperature, but convert to the titled CPs at temperatures above 100 °C.",
keywords = "CRYSTAL-STRUCTURE, HEXANUCLEAR MOLYBDENUM, BUILDING-BLOCKS, COMPLEXES, METHANOL, COMPOUND, CHLORIDE, LIGANDS, CALCIUM, CATIONS",
author = "Evtushok, {Darya V.} and Vorotnikova, {Natalya A.} and Logvinenko, {Vladimir A.} and Smolentsev, {Anton I.} and Brylev, {Konstantin A.} and Plyusnin, {Pavel E.} and Pishchur, {Denis P.} and Noboru Kitamura and Mironov, {Yuri V.} and Solovieva, {Anastasiya O.} and Efremova, {Olga A.} and Shestopalov, {Michael A.}",
year = "2017",
month = dec,
day = "21",
doi = "10.1039/c7nj02858j",
language = "English",
volume = "41",
pages = "14855--14861",
journal = "New Journal of Chemistry",
issn = "1144-0546",
publisher = "ROYAL SOC CHEMISTRY",
number = "24",

}

RIS

TY - JOUR

T1 - Luminescent coordination polymers based on Ca2+ and octahedral cluster anions [{M6Cli 8}Cla 6]2- (M = Mo, W)

T2 - Synthesis and thermal stability studies

AU - Evtushok, Darya V.

AU - Vorotnikova, Natalya A.

AU - Logvinenko, Vladimir A.

AU - Smolentsev, Anton I.

AU - Brylev, Konstantin A.

AU - Plyusnin, Pavel E.

AU - Pishchur, Denis P.

AU - Kitamura, Noboru

AU - Mironov, Yuri V.

AU - Solovieva, Anastasiya O.

AU - Efremova, Olga A.

AU - Shestopalov, Michael A.

PY - 2017/12/21

Y1 - 2017/12/21

N2 - Luminescent coordination polymers (CPs) based on inexpensive stable precursors are attractive materials for applications. Here we report the synthesis and evaluation of the stability and photophysical characteristics of the first examples of phosphorescent CPs based on octahedral molybdenum and tungsten cluster anions. In particular, 1D CP trans-[{Ca(OPPh3)4}{{M6Cli 8}Cla 6}]∞ (M = Mo, W) can be obtained either directly at increased temperature or via intermediate phases [cis-Ca(OPPh3)4(H2O)2][{M6Cli 8}Cla 6]·2CH3CN that are stable at room-temperature, but convert to the titled CPs at temperatures above 100 °C.

AB - Luminescent coordination polymers (CPs) based on inexpensive stable precursors are attractive materials for applications. Here we report the synthesis and evaluation of the stability and photophysical characteristics of the first examples of phosphorescent CPs based on octahedral molybdenum and tungsten cluster anions. In particular, 1D CP trans-[{Ca(OPPh3)4}{{M6Cli 8}Cla 6}]∞ (M = Mo, W) can be obtained either directly at increased temperature or via intermediate phases [cis-Ca(OPPh3)4(H2O)2][{M6Cli 8}Cla 6]·2CH3CN that are stable at room-temperature, but convert to the titled CPs at temperatures above 100 °C.

KW - CRYSTAL-STRUCTURE

KW - HEXANUCLEAR MOLYBDENUM

KW - BUILDING-BLOCKS

KW - COMPLEXES

KW - METHANOL

KW - COMPOUND

KW - CHLORIDE

KW - LIGANDS

KW - CALCIUM

KW - CATIONS

UR - http://www.scopus.com/inward/record.url?scp=85037651360&partnerID=8YFLogxK

U2 - 10.1039/c7nj02858j

DO - 10.1039/c7nj02858j

M3 - Article

AN - SCOPUS:85037651360

VL - 41

SP - 14855

EP - 14861

JO - New Journal of Chemistry

JF - New Journal of Chemistry

SN - 1144-0546

IS - 24

ER -

ID: 10065455