Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Luminescent coordination polymers based on Ca2+ and octahedral cluster anions [{M6Cli 8}Cla 6]2- (M = Mo, W) : Synthesis and thermal stability studies. / Evtushok, Darya V.; Vorotnikova, Natalya A.; Logvinenko, Vladimir A. и др.
в: New Journal of Chemistry, Том 41, № 24, 21.12.2017, стр. 14855-14861.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Luminescent coordination polymers based on Ca2+ and octahedral cluster anions [{M6Cli 8}Cla 6]2- (M = Mo, W)
T2 - Synthesis and thermal stability studies
AU - Evtushok, Darya V.
AU - Vorotnikova, Natalya A.
AU - Logvinenko, Vladimir A.
AU - Smolentsev, Anton I.
AU - Brylev, Konstantin A.
AU - Plyusnin, Pavel E.
AU - Pishchur, Denis P.
AU - Kitamura, Noboru
AU - Mironov, Yuri V.
AU - Solovieva, Anastasiya O.
AU - Efremova, Olga A.
AU - Shestopalov, Michael A.
PY - 2017/12/21
Y1 - 2017/12/21
N2 - Luminescent coordination polymers (CPs) based on inexpensive stable precursors are attractive materials for applications. Here we report the synthesis and evaluation of the stability and photophysical characteristics of the first examples of phosphorescent CPs based on octahedral molybdenum and tungsten cluster anions. In particular, 1D CP trans-[{Ca(OPPh3)4}{{M6Cli 8}Cla 6}]∞ (M = Mo, W) can be obtained either directly at increased temperature or via intermediate phases [cis-Ca(OPPh3)4(H2O)2][{M6Cli 8}Cla 6]·2CH3CN that are stable at room-temperature, but convert to the titled CPs at temperatures above 100 °C.
AB - Luminescent coordination polymers (CPs) based on inexpensive stable precursors are attractive materials for applications. Here we report the synthesis and evaluation of the stability and photophysical characteristics of the first examples of phosphorescent CPs based on octahedral molybdenum and tungsten cluster anions. In particular, 1D CP trans-[{Ca(OPPh3)4}{{M6Cli 8}Cla 6}]∞ (M = Mo, W) can be obtained either directly at increased temperature or via intermediate phases [cis-Ca(OPPh3)4(H2O)2][{M6Cli 8}Cla 6]·2CH3CN that are stable at room-temperature, but convert to the titled CPs at temperatures above 100 °C.
KW - CRYSTAL-STRUCTURE
KW - HEXANUCLEAR MOLYBDENUM
KW - BUILDING-BLOCKS
KW - COMPLEXES
KW - METHANOL
KW - COMPOUND
KW - CHLORIDE
KW - LIGANDS
KW - CALCIUM
KW - CATIONS
UR - http://www.scopus.com/inward/record.url?scp=85037651360&partnerID=8YFLogxK
U2 - 10.1039/c7nj02858j
DO - 10.1039/c7nj02858j
M3 - Article
AN - SCOPUS:85037651360
VL - 41
SP - 14855
EP - 14861
JO - New Journal of Chemistry
JF - New Journal of Chemistry
SN - 1144-0546
IS - 24
ER -
ID: 10065455