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Luminescent Ag(I) scorpionates based on tris(2-pyridyl)phosphine oxide : Synthesis and cytotoxic activity evaluation. / Artem'ev, Alexander V.; Eremina, Julia A.; Lider, Elizaveta V. et al.

In: Polyhedron, Vol. 138, 14.12.2017, p. 218-224.

Research output: Contribution to journal › Article › peer-review

Harvard

Artem'ev, AV, Eremina, JA, Lider, EV, Antonova, OV, Vorontsova, EV & Bagryanskaya, IY 2017, 'Luminescent Ag(I) scorpionates based on tris(2-pyridyl)phosphine oxide: Synthesis and cytotoxic activity evaluation', Polyhedron, vol. 138, pp. 218-224. https://doi.org/10.1016/j.poly.2017.09.041

APA

Artem'ev, A. V., Eremina, J. A., Lider, E. V., Antonova, O. V., Vorontsova, E. V., & Bagryanskaya, I. Y. (2017). Luminescent Ag(I) scorpionates based on tris(2-pyridyl)phosphine oxide: Synthesis and cytotoxic activity evaluation. Polyhedron, 138, 218-224. https://doi.org/10.1016/j.poly.2017.09.041

Vancouver

Artem'ev AV, Eremina JA, Lider EV, Antonova OV, Vorontsova EV, Bagryanskaya IY. Luminescent Ag(I) scorpionates based on tris(2-pyridyl)phosphine oxide: Synthesis and cytotoxic activity evaluation. Polyhedron. 2017 Dec 14;138:218-224. doi: 10.1016/j.poly.2017.09.041

Author

Artem'ev, Alexander V. ; Eremina, Julia A. ; Lider, Elizaveta V. et al. / Luminescent Ag(I) scorpionates based on tris(2-pyridyl)phosphine oxide : Synthesis and cytotoxic activity evaluation. In: Polyhedron. 2017 ; Vol. 138. pp. 218-224.

BibTeX

@article{5217258172e94feb9bb6af1a1cc6a2c7,
title = "Luminescent Ag(I) scorpionates based on tris(2-pyridyl)phosphine oxide: Synthesis and cytotoxic activity evaluation",
abstract = "First representatives of Ag(I) scorpionates bearing tris(2-pyridyl)phosphine oxide (Py3P[dbnd]O), viz. [Ag(Py3P[dbnd]O)(PPh3)]BF4 (1) and [Ag(Py3P[dbnd]O)(PPh3)]ClO4 (2), have been synthesized and structurally characterized. X-ray diffraction analysis reveals that the silver atom of 1 is coordinated by Py3P[dbnd]O and Ph3P ligands in N,N′,N″-tripodal and P-monodentate fashions, respectively. The both complexes exhibit significant cytotoxic activity (IC50 being from 11 to 14 μM) screened in vitro against human larynx carcinoma (Hep-2) cell lines. The luminescent proprieties of the prepared scorpionates are also discussed.",
keywords = "Cytotoxic activity, Luminescence, Scorpionates, Silver, Tris(2-pyridyl)phosphine oxide, ANTIMICROBIAL PROPERTIES, ADDUCTS, COPPER, UNSUPPORTED SILVER-GERMANIUM, LIGANDS, CARBONYL, CATALYZED CARBENE INSERTION, TRIS(PYRAZOLYL)BORATE, DERIVATIVES, ETHYLENE COMPLEXES",
author = "Artem'ev, {Alexander V.} and Eremina, {Julia A.} and Lider, {Elizaveta V.} and Antonova, {Olga V.} and Vorontsova, {Elena V.} and Bagryanskaya, {Irina Yu}",
note = "Publisher Copyright: {\textcopyright} 2017 Elsevier Ltd",
year = "2017",
month = dec,
day = "14",
doi = "10.1016/j.poly.2017.09.041",
language = "English",
volume = "138",
pages = "218--224",
journal = "Polyhedron",
issn = "0277-5387",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Luminescent Ag(I) scorpionates based on tris(2-pyridyl)phosphine oxide

T2 - Synthesis and cytotoxic activity evaluation

AU - Artem'ev, Alexander V.

AU - Eremina, Julia A.

AU - Lider, Elizaveta V.

AU - Antonova, Olga V.

AU - Vorontsova, Elena V.

AU - Bagryanskaya, Irina Yu

N1 - Publisher Copyright: © 2017 Elsevier Ltd

PY - 2017/12/14

Y1 - 2017/12/14

N2 - First representatives of Ag(I) scorpionates bearing tris(2-pyridyl)phosphine oxide (Py3P[dbnd]O), viz. [Ag(Py3P[dbnd]O)(PPh3)]BF4 (1) and [Ag(Py3P[dbnd]O)(PPh3)]ClO4 (2), have been synthesized and structurally characterized. X-ray diffraction analysis reveals that the silver atom of 1 is coordinated by Py3P[dbnd]O and Ph3P ligands in N,N′,N″-tripodal and P-monodentate fashions, respectively. The both complexes exhibit significant cytotoxic activity (IC50 being from 11 to 14 μM) screened in vitro against human larynx carcinoma (Hep-2) cell lines. The luminescent proprieties of the prepared scorpionates are also discussed.

AB - First representatives of Ag(I) scorpionates bearing tris(2-pyridyl)phosphine oxide (Py3P[dbnd]O), viz. [Ag(Py3P[dbnd]O)(PPh3)]BF4 (1) and [Ag(Py3P[dbnd]O)(PPh3)]ClO4 (2), have been synthesized and structurally characterized. X-ray diffraction analysis reveals that the silver atom of 1 is coordinated by Py3P[dbnd]O and Ph3P ligands in N,N′,N″-tripodal and P-monodentate fashions, respectively. The both complexes exhibit significant cytotoxic activity (IC50 being from 11 to 14 μM) screened in vitro against human larynx carcinoma (Hep-2) cell lines. The luminescent proprieties of the prepared scorpionates are also discussed.

KW - Cytotoxic activity

KW - Luminescence

KW - Scorpionates

KW - Silver

KW - Tris(2-pyridyl)phosphine oxide

KW - ANTIMICROBIAL PROPERTIES

KW - ADDUCTS

KW - COPPER

KW - UNSUPPORTED SILVER-GERMANIUM

KW - LIGANDS

KW - CARBONYL

KW - CATALYZED CARBENE INSERTION

KW - TRIS(PYRAZOLYL)BORATE

KW - DERIVATIVES

KW - ETHYLENE COMPLEXES

UR - http://www.scopus.com/inward/record.url?scp=85031506873&partnerID=8YFLogxK

U2 - 10.1016/j.poly.2017.09.041

DO - 10.1016/j.poly.2017.09.041

M3 - Article

AN - SCOPUS:85031506873

VL - 138

SP - 218

EP - 224

JO - Polyhedron

JF - Polyhedron

SN - 0277-5387

ER -

ID: 9079229