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Low-temperature fabrication of SiO x -TiO 2 core-shell nanowires for photocatalytic application. / Lebedev, M. S.; Khmel, S. Ya; Lyulyukin, M. N. et al.

In: Vacuum, Vol. 165, 01.07.2019, p. 51-57.

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Lebedev MS, Khmel SY, Lyulyukin MN, Petukhova DE, Barsukov AV. Low-temperature fabrication of SiO x -TiO 2 core-shell nanowires for photocatalytic application. Vacuum. 2019 Jul 1;165:51-57. doi: 10.1016/j.vacuum.2019.03.059

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Lebedev, M. S. ; Khmel, S. Ya ; Lyulyukin, M. N. et al. / Low-temperature fabrication of SiO x -TiO 2 core-shell nanowires for photocatalytic application. In: Vacuum. 2019 ; Vol. 165. pp. 51-57.

BibTeX

@article{5c0f0ca1c1a045c0809472ae2fa8aa4f,
title = "Low-temperature fabrication of SiO x -TiO 2 core-shell nanowires for photocatalytic application",
abstract = " A new low-temperature fabrication method of SiO x -TiO 2 core-shell nanowires (NWs) for photocatalytic application was suggested. In the present work, the gas-jet electron beam plasma chemical vapor deposition method was used to synthesize arrays of oriented bundles (microropes) of silicon oxide NWs. Tin nanoparticles were used as catalyst for the NW growth via the “vapor-liquid-solid” mechanism at a temperature of 335 °C. A conformal nanocrystalline TiO 2 coating was then deposited by atomic layer deposition using TiCl 4 and H 2 O at 300 °C. Anatase phase formation was confirmed by Raman spectroscopy and X-ray diffraction. The photocatalytic characteristics of the fabricated arrays were demonstrated by the example of the photo-oxidation reaction of acetone vapor. Options for further development and advantages of the method such as low temperature, scalability and good compatibility of the fabrication stages are discussed. ",
keywords = "Atomic layer deposition, Core-shell structure, Silicon oxide nanowires, TiO photocatalyst, OXIDATION, TiO2 photocatalyst, FILMS, GROWTH, SURFACE, ANATASE, DEGRADATION, SPECTRUM, SILICON-OXIDE NANOWIRES, ATOMIC LAYER DEPOSITION, TIO2",
author = "Lebedev, {M. S.} and Khmel, {S. Ya} and Lyulyukin, {M. N.} and Petukhova, {D. E.} and Barsukov, {A. V.}",
year = "2019",
month = jul,
day = "1",
doi = "10.1016/j.vacuum.2019.03.059",
language = "English",
volume = "165",
pages = "51--57",
journal = "Vacuum",
issn = "0042-207X",
publisher = "Elsevier Ltd",

}

RIS

TY - JOUR

T1 - Low-temperature fabrication of SiO x -TiO 2 core-shell nanowires for photocatalytic application

AU - Lebedev, M. S.

AU - Khmel, S. Ya

AU - Lyulyukin, M. N.

AU - Petukhova, D. E.

AU - Barsukov, A. V.

PY - 2019/7/1

Y1 - 2019/7/1

N2 - A new low-temperature fabrication method of SiO x -TiO 2 core-shell nanowires (NWs) for photocatalytic application was suggested. In the present work, the gas-jet electron beam plasma chemical vapor deposition method was used to synthesize arrays of oriented bundles (microropes) of silicon oxide NWs. Tin nanoparticles were used as catalyst for the NW growth via the “vapor-liquid-solid” mechanism at a temperature of 335 °C. A conformal nanocrystalline TiO 2 coating was then deposited by atomic layer deposition using TiCl 4 and H 2 O at 300 °C. Anatase phase formation was confirmed by Raman spectroscopy and X-ray diffraction. The photocatalytic characteristics of the fabricated arrays were demonstrated by the example of the photo-oxidation reaction of acetone vapor. Options for further development and advantages of the method such as low temperature, scalability and good compatibility of the fabrication stages are discussed.

AB - A new low-temperature fabrication method of SiO x -TiO 2 core-shell nanowires (NWs) for photocatalytic application was suggested. In the present work, the gas-jet electron beam plasma chemical vapor deposition method was used to synthesize arrays of oriented bundles (microropes) of silicon oxide NWs. Tin nanoparticles were used as catalyst for the NW growth via the “vapor-liquid-solid” mechanism at a temperature of 335 °C. A conformal nanocrystalline TiO 2 coating was then deposited by atomic layer deposition using TiCl 4 and H 2 O at 300 °C. Anatase phase formation was confirmed by Raman spectroscopy and X-ray diffraction. The photocatalytic characteristics of the fabricated arrays were demonstrated by the example of the photo-oxidation reaction of acetone vapor. Options for further development and advantages of the method such as low temperature, scalability and good compatibility of the fabrication stages are discussed.

KW - Atomic layer deposition

KW - Core-shell structure

KW - Silicon oxide nanowires

KW - TiO photocatalyst

KW - OXIDATION

KW - TiO2 photocatalyst

KW - FILMS

KW - GROWTH

KW - SURFACE

KW - ANATASE

KW - DEGRADATION

KW - SPECTRUM

KW - SILICON-OXIDE NANOWIRES

KW - ATOMIC LAYER DEPOSITION

KW - TIO2

UR - http://www.scopus.com/inward/record.url?scp=85064068192&partnerID=8YFLogxK

U2 - 10.1016/j.vacuum.2019.03.059

DO - 10.1016/j.vacuum.2019.03.059

M3 - Article

AN - SCOPUS:85064068192

VL - 165

SP - 51

EP - 57

JO - Vacuum

JF - Vacuum

SN - 0042-207X

ER -

ID: 19357119