Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Low-temperature fabrication of SiO x -TiO 2 core-shell nanowires for photocatalytic application. / Lebedev, M. S.; Khmel, S. Ya; Lyulyukin, M. N. и др.
в: Vacuum, Том 165, 01.07.2019, стр. 51-57.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Low-temperature fabrication of SiO x -TiO 2 core-shell nanowires for photocatalytic application
AU - Lebedev, M. S.
AU - Khmel, S. Ya
AU - Lyulyukin, M. N.
AU - Petukhova, D. E.
AU - Barsukov, A. V.
PY - 2019/7/1
Y1 - 2019/7/1
N2 - A new low-temperature fabrication method of SiO x -TiO 2 core-shell nanowires (NWs) for photocatalytic application was suggested. In the present work, the gas-jet electron beam plasma chemical vapor deposition method was used to synthesize arrays of oriented bundles (microropes) of silicon oxide NWs. Tin nanoparticles were used as catalyst for the NW growth via the “vapor-liquid-solid” mechanism at a temperature of 335 °C. A conformal nanocrystalline TiO 2 coating was then deposited by atomic layer deposition using TiCl 4 and H 2 O at 300 °C. Anatase phase formation was confirmed by Raman spectroscopy and X-ray diffraction. The photocatalytic characteristics of the fabricated arrays were demonstrated by the example of the photo-oxidation reaction of acetone vapor. Options for further development and advantages of the method such as low temperature, scalability and good compatibility of the fabrication stages are discussed.
AB - A new low-temperature fabrication method of SiO x -TiO 2 core-shell nanowires (NWs) for photocatalytic application was suggested. In the present work, the gas-jet electron beam plasma chemical vapor deposition method was used to synthesize arrays of oriented bundles (microropes) of silicon oxide NWs. Tin nanoparticles were used as catalyst for the NW growth via the “vapor-liquid-solid” mechanism at a temperature of 335 °C. A conformal nanocrystalline TiO 2 coating was then deposited by atomic layer deposition using TiCl 4 and H 2 O at 300 °C. Anatase phase formation was confirmed by Raman spectroscopy and X-ray diffraction. The photocatalytic characteristics of the fabricated arrays were demonstrated by the example of the photo-oxidation reaction of acetone vapor. Options for further development and advantages of the method such as low temperature, scalability and good compatibility of the fabrication stages are discussed.
KW - Atomic layer deposition
KW - Core-shell structure
KW - Silicon oxide nanowires
KW - TiO photocatalyst
KW - OXIDATION
KW - TiO2 photocatalyst
KW - FILMS
KW - GROWTH
KW - SURFACE
KW - ANATASE
KW - DEGRADATION
KW - SPECTRUM
KW - SILICON-OXIDE NANOWIRES
KW - ATOMIC LAYER DEPOSITION
KW - TIO2
UR - http://www.scopus.com/inward/record.url?scp=85064068192&partnerID=8YFLogxK
U2 - 10.1016/j.vacuum.2019.03.059
DO - 10.1016/j.vacuum.2019.03.059
M3 - Article
AN - SCOPUS:85064068192
VL - 165
SP - 51
EP - 57
JO - Vacuum
JF - Vacuum
SN - 0042-207X
ER -
ID: 19357119