Standard

Labile η6-areneruthenium sulfide clusters. Crystal structure of [(C6H6)4Ru5S4](PF6)2 and [(C6H6)4Ru4S5](PF6)2. / Korenev, V. S.; Abramov, P. A.; Kompankov, N. B. et al.

In: Journal of Organometallic Chemistry, Vol. 867, 15.07.2018, p. 347-352.

Research output: Contribution to journal › Article › peer-review

Harvard

Korenev, VS, Abramov, PA, Kompankov, NB, Gushchin, AL, Sheven, DG & Sokolov, MN 2018, 'Labile η6-areneruthenium sulfide clusters. Crystal structure of [(C6H6)4Ru5S4](PF6)2 and [(C6H6)4Ru4S5](PF6)2', Journal of Organometallic Chemistry, vol. 867, pp. 347-352. https://doi.org/10.1016/j.jorganchem.2018.01.021

APA

Korenev, V. S., Abramov, P. A., Kompankov, N. B., Gushchin, A. L., Sheven, D. G., & Sokolov, M. N. (2018). Labile η6-areneruthenium sulfide clusters. Crystal structure of [(C6H6)4Ru5S4](PF6)2 and [(C6H6)4Ru4S5](PF6)2. Journal of Organometallic Chemistry, 867, 347-352. https://doi.org/10.1016/j.jorganchem.2018.01.021

Vancouver

Korenev VS, Abramov PA, Kompankov NB, Gushchin AL, Sheven DG, Sokolov MN. Labile η6-areneruthenium sulfide clusters. Crystal structure of [(C6H6)4Ru5S4](PF6)2 and [(C6H6)4Ru4S5](PF6)2. Journal of Organometallic Chemistry. 2018 Jul 15;867:347-352. doi: 10.1016/j.jorganchem.2018.01.021

Author

Korenev, V. S. ; Abramov, P. A. ; Kompankov, N. B. et al. / Labile η6-areneruthenium sulfide clusters. Crystal structure of [(C6H6)4Ru5S4](PF6)2 and [(C6H6)4Ru4S5](PF6)2. In: Journal of Organometallic Chemistry. 2018 ; Vol. 867. pp. 347-352.

BibTeX

@article{0ff3378b36244af2b135e93608e62153,
title = "Labile η6-areneruthenium sulfide clusters. Crystal structure of [(C6H6)4Ru5S4](PF6)2 and [(C6H6)4Ru4S5](PF6)2",
abstract = "A new labile areneruthenium sulfide complex, [(C6H6)3Ru3S2](PF6)2 (1), was prepared and characterized both in solid state and in solution. Light-driven de-coodination of the arene ligands has been demonstrated. Two new polynuclear areneruthenium complexes, [(C6H6)4Ru5S4](PF6)2·2CH3CN (2) and [(C6H6)4Ru4S5](PF6)2·1.25CH3CN·0.5H2O (3), were obtained from 1 and structurally characterized. Redox behaviour of [(C6H6)3Ru3S2](PF6)2 and [Ru5S4(C6H6)4](PF6)2·2CH3CN was studied by cyclic voltammetry and reveals one reversible reduction wave.",
keywords = "Areneruthenium complexes, Electrochemistry, Photoactivation, Sulfide clusters, ELECTROCHEMISTRY, RU, TRANSFER HYDROGENATION, POLYMERIZATION, KETONES, LIGANDS, ARENE RUTHENIUM COMPLEXES, ASYMMETRIC EPOXIDATION, CYTOTOXICITY, CATALYSTS",
author = "Korenev, {V. S.} and Abramov, {P. A.} and Kompankov, {N. B.} and Gushchin, {A. L.} and Sheven, {D. G.} and Sokolov, {M. N.}",
note = "Publisher Copyright: {\textcopyright} 2018 Elsevier B.V.",
year = "2018",
month = jul,
day = "15",
doi = "10.1016/j.jorganchem.2018.01.021",
language = "English",
volume = "867",
pages = "347--352",
journal = "Journal of Organometallic Chemistry",
issn = "0022-328X",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Labile η6-areneruthenium sulfide clusters. Crystal structure of [(C6H6)4Ru5S4](PF6)2 and [(C6H6)4Ru4S5](PF6)2

AU - Korenev, V. S.

AU - Abramov, P. A.

AU - Kompankov, N. B.

AU - Gushchin, A. L.

AU - Sheven, D. G.

AU - Sokolov, M. N.

N1 - Publisher Copyright: © 2018 Elsevier B.V.

PY - 2018/7/15

Y1 - 2018/7/15

N2 - A new labile areneruthenium sulfide complex, [(C6H6)3Ru3S2](PF6)2 (1), was prepared and characterized both in solid state and in solution. Light-driven de-coodination of the arene ligands has been demonstrated. Two new polynuclear areneruthenium complexes, [(C6H6)4Ru5S4](PF6)2·2CH3CN (2) and [(C6H6)4Ru4S5](PF6)2·1.25CH3CN·0.5H2O (3), were obtained from 1 and structurally characterized. Redox behaviour of [(C6H6)3Ru3S2](PF6)2 and [Ru5S4(C6H6)4](PF6)2·2CH3CN was studied by cyclic voltammetry and reveals one reversible reduction wave.

AB - A new labile areneruthenium sulfide complex, [(C6H6)3Ru3S2](PF6)2 (1), was prepared and characterized both in solid state and in solution. Light-driven de-coodination of the arene ligands has been demonstrated. Two new polynuclear areneruthenium complexes, [(C6H6)4Ru5S4](PF6)2·2CH3CN (2) and [(C6H6)4Ru4S5](PF6)2·1.25CH3CN·0.5H2O (3), were obtained from 1 and structurally characterized. Redox behaviour of [(C6H6)3Ru3S2](PF6)2 and [Ru5S4(C6H6)4](PF6)2·2CH3CN was studied by cyclic voltammetry and reveals one reversible reduction wave.

KW - Areneruthenium complexes

KW - Electrochemistry

KW - Photoactivation

KW - Sulfide clusters

KW - ELECTROCHEMISTRY

KW - RU

KW - TRANSFER HYDROGENATION

KW - POLYMERIZATION

KW - KETONES

KW - LIGANDS

KW - ARENE RUTHENIUM COMPLEXES

KW - ASYMMETRIC EPOXIDATION

KW - CYTOTOXICITY

KW - CATALYSTS

UR - http://www.scopus.com/inward/record.url?scp=85041352611&partnerID=8YFLogxK

U2 - 10.1016/j.jorganchem.2018.01.021

DO - 10.1016/j.jorganchem.2018.01.021

M3 - Article

AN - SCOPUS:85041352611

VL - 867

SP - 347

EP - 352

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

SN - 0022-328X

ER -

ID: 12100107