Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Labile η6-areneruthenium sulfide clusters. Crystal structure of [(C6H6)4Ru5S4](PF6)2 and [(C6H6)4Ru4S5](PF6)2. / Korenev, V. S.; Abramov, P. A.; Kompankov, N. B. и др.
в: Journal of Organometallic Chemistry, Том 867, 15.07.2018, стр. 347-352.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Labile η6-areneruthenium sulfide clusters. Crystal structure of [(C6H6)4Ru5S4](PF6)2 and [(C6H6)4Ru4S5](PF6)2
AU - Korenev, V. S.
AU - Abramov, P. A.
AU - Kompankov, N. B.
AU - Gushchin, A. L.
AU - Sheven, D. G.
AU - Sokolov, M. N.
N1 - Publisher Copyright: © 2018 Elsevier B.V.
PY - 2018/7/15
Y1 - 2018/7/15
N2 - A new labile areneruthenium sulfide complex, [(C6H6)3Ru3S2](PF6)2 (1), was prepared and characterized both in solid state and in solution. Light-driven de-coodination of the arene ligands has been demonstrated. Two new polynuclear areneruthenium complexes, [(C6H6)4Ru5S4](PF6)2·2CH3CN (2) and [(C6H6)4Ru4S5](PF6)2·1.25CH3CN·0.5H2O (3), were obtained from 1 and structurally characterized. Redox behaviour of [(C6H6)3Ru3S2](PF6)2 and [Ru5S4(C6H6)4](PF6)2·2CH3CN was studied by cyclic voltammetry and reveals one reversible reduction wave.
AB - A new labile areneruthenium sulfide complex, [(C6H6)3Ru3S2](PF6)2 (1), was prepared and characterized both in solid state and in solution. Light-driven de-coodination of the arene ligands has been demonstrated. Two new polynuclear areneruthenium complexes, [(C6H6)4Ru5S4](PF6)2·2CH3CN (2) and [(C6H6)4Ru4S5](PF6)2·1.25CH3CN·0.5H2O (3), were obtained from 1 and structurally characterized. Redox behaviour of [(C6H6)3Ru3S2](PF6)2 and [Ru5S4(C6H6)4](PF6)2·2CH3CN was studied by cyclic voltammetry and reveals one reversible reduction wave.
KW - Areneruthenium complexes
KW - Electrochemistry
KW - Photoactivation
KW - Sulfide clusters
KW - ELECTROCHEMISTRY
KW - RU
KW - TRANSFER HYDROGENATION
KW - POLYMERIZATION
KW - KETONES
KW - LIGANDS
KW - ARENE RUTHENIUM COMPLEXES
KW - ASYMMETRIC EPOXIDATION
KW - CYTOTOXICITY
KW - CATALYSTS
UR - http://www.scopus.com/inward/record.url?scp=85041352611&partnerID=8YFLogxK
U2 - 10.1016/j.jorganchem.2018.01.021
DO - 10.1016/j.jorganchem.2018.01.021
M3 - Article
AN - SCOPUS:85041352611
VL - 867
SP - 347
EP - 352
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
SN - 0022-328X
ER -
ID: 12100107