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Interaction of Na 9 [SbW 9 O 33 ] with Iridium(IV) Hydroxo Complexes. / Mukhacheva, A. A.; Abramov, P. A.; Sokolov, M. N.

In: Journal of Structural Chemistry, Vol. 60, No. 4, 01.04.2019, p. 647-653.

Research output: Contribution to journal › Article › peer-review

Harvard

Mukhacheva, AA, Abramov, PA & Sokolov, MN 2019, 'Interaction of Na 9 [SbW 9 O 33 ] with Iridium(IV) Hydroxo Complexes', Journal of Structural Chemistry, vol. 60, no. 4, pp. 647-653. https://doi.org/10.1134/S0022476619040164

APA

Mukhacheva, A. A., Abramov, P. A., & Sokolov, M. N. (2019). Interaction of Na 9 [SbW 9 O 33 ] with Iridium(IV) Hydroxo Complexes. Journal of Structural Chemistry, 60(4), 647-653. https://doi.org/10.1134/S0022476619040164

Vancouver

Mukhacheva AA, Abramov PA, Sokolov MN. Interaction of Na 9 [SbW 9 O 33 ] with Iridium(IV) Hydroxo Complexes. Journal of Structural Chemistry. 2019 Apr 1;60(4):647-653. doi: 10.1134/S0022476619040164

Author

Mukhacheva, A. A. ; Abramov, P. A. ; Sokolov, M. N. / Interaction of Na 9 [SbW 9 O 33 ] with Iridium(IV) Hydroxo Complexes. In: Journal of Structural Chemistry. 2019 ; Vol. 60, No. 4. pp. 647-653.

BibTeX

@article{813c3c0709d14b389598c6032e14697f,
title = "Interaction of Na 9 [SbW 9 O 33 ] with Iridium(IV) Hydroxo Complexes",
abstract = " Thermostating of the aqueous solution of Na 9 [SbW 9 O 33 ] with K 2 [Ir(OH) 6 ] at 70 °C for 17 h changes the solution{\textquoteright}s color from blue to brown. The addition of KNO 3 to the reaction solution and subsequent evaporation in air causes crystallization of the products to yield yellow crystals of composition K 5.47 Na 2.3 [Ir 0.17 Sb 0.83 W 6 O 24 ](NO 3 ) 0.6 ·12H 2 O containing an Anderson-type anion [SbVW6VIO24]7− with ∼20% of antimony positions occupied by iridium. ",
keywords = "Anderson-type anion, crystal structure, iridium, OXIDATION, ANIONS, CHLORIDE ANATION, CRYSTAL-STRUCTURE, HETEROPOLYANIONS, FRAGMENTS, KINETICS, POLYOXOMETALATE, AQUATION, HETEROPOLYTUNGSTATES",
author = "Mukhacheva, {A. A.} and Abramov, {P. A.} and Sokolov, {M. N.}",
year = "2019",
month = apr,
day = "1",
doi = "10.1134/S0022476619040164",
language = "English",
volume = "60",
pages = "647--653",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "4",

}

RIS

TY - JOUR

T1 - Interaction of Na 9 [SbW 9 O 33 ] with Iridium(IV) Hydroxo Complexes

AU - Mukhacheva, A. A.

AU - Abramov, P. A.

AU - Sokolov, M. N.

PY - 2019/4/1

Y1 - 2019/4/1

N2 - Thermostating of the aqueous solution of Na 9 [SbW 9 O 33 ] with K 2 [Ir(OH) 6 ] at 70 °C for 17 h changes the solution’s color from blue to brown. The addition of KNO 3 to the reaction solution and subsequent evaporation in air causes crystallization of the products to yield yellow crystals of composition K 5.47 Na 2.3 [Ir 0.17 Sb 0.83 W 6 O 24 ](NO 3 ) 0.6 ·12H 2 O containing an Anderson-type anion [SbVW6VIO24]7− with ∼20% of antimony positions occupied by iridium.

AB - Thermostating of the aqueous solution of Na 9 [SbW 9 O 33 ] with K 2 [Ir(OH) 6 ] at 70 °C for 17 h changes the solution’s color from blue to brown. The addition of KNO 3 to the reaction solution and subsequent evaporation in air causes crystallization of the products to yield yellow crystals of composition K 5.47 Na 2.3 [Ir 0.17 Sb 0.83 W 6 O 24 ](NO 3 ) 0.6 ·12H 2 O containing an Anderson-type anion [SbVW6VIO24]7− with ∼20% of antimony positions occupied by iridium.

KW - Anderson-type anion

KW - crystal structure

KW - iridium

KW - OXIDATION

KW - ANIONS

KW - CHLORIDE ANATION

KW - CRYSTAL-STRUCTURE

KW - HETEROPOLYANIONS

KW - FRAGMENTS

KW - KINETICS

KW - POLYOXOMETALATE

KW - AQUATION

KW - HETEROPOLYTUNGSTATES

UR - http://www.scopus.com/inward/record.url?scp=85065402030&partnerID=8YFLogxK

U2 - 10.1134/S0022476619040164

DO - 10.1134/S0022476619040164

M3 - Article

AN - SCOPUS:85065402030

VL - 60

SP - 647

EP - 653

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 4

ER -

ID: 20165008