Standard

Influence of water on the structure and magnetic properties of a copper bromide coordination compound with 3-amino-4-ethoxycarbonylpyrazole. / Berezin, A. S.; Ivanova, A. D.; Komarov, V. Yu et al.

In: New Journal of Chemistry, Vol. 42, No. 7, 07.04.2018, p. 4902-4908.

Research output: Contribution to journal › Article › peer-review

Harvard

Berezin, AS, Ivanova, AD, Komarov, VY, Nadolinny, VA & Lavrenova, LG 2018, 'Influence of water on the structure and magnetic properties of a copper bromide coordination compound with 3-amino-4-ethoxycarbonylpyrazole', New Journal of Chemistry, vol. 42, no. 7, pp. 4902-4908. https://doi.org/10.1039/c8nj00017d

APA

Berezin, A. S., Ivanova, A. D., Komarov, V. Y., Nadolinny, V. A., & Lavrenova, L. G. (2018). Influence of water on the structure and magnetic properties of a copper bromide coordination compound with 3-amino-4-ethoxycarbonylpyrazole. New Journal of Chemistry, 42(7), 4902-4908. https://doi.org/10.1039/c8nj00017d

Vancouver

Berezin AS, Ivanova AD, Komarov VY, Nadolinny VA, Lavrenova LG. Influence of water on the structure and magnetic properties of a copper bromide coordination compound with 3-amino-4-ethoxycarbonylpyrazole. New Journal of Chemistry. 2018 Apr 7;42(7):4902-4908. doi: 10.1039/c8nj00017d

Author

Berezin, A. S. ; Ivanova, A. D. ; Komarov, V. Yu et al. / Influence of water on the structure and magnetic properties of a copper bromide coordination compound with 3-amino-4-ethoxycarbonylpyrazole. In: New Journal of Chemistry. 2018 ; Vol. 42, No. 7. pp. 4902-4908.

BibTeX

@article{74ebbef08eba453b9cc66a935d41a92a,
title = "Influence of water on the structure and magnetic properties of a copper bromide coordination compound with 3-amino-4-ethoxycarbonylpyrazole",
abstract = "The influence of water on a polynuclear [CuL2Br2]n (1) copper bromide compound with 3-amino-4-ethoxycarbonylpyrazole (L) is investigated. The abundance of water in solution results in the formation of three new complexes with drastically different coordination units: polynuclear {[CuL4Br]Br}n·nH2O (2) and two mononuclear polymorphs [CuL4Br2]·2H2O (monoclinic-3, triclinic-4). The crystal structures are determined for all three complexes. Complex 2 has a weak (≪1 cm-1) superexchange interaction between copper ions and bromide ions. Complexes 3 and 4 have no exchange interaction. It is found that the two polynuclear complexes may transform into each other through dissolution followed by recrystallization under certain conditions.",
keywords = "SPIN TRANSITION, COMPLEXES, POLYMERS, LENGTH, CUCL2, EPR",
author = "Berezin, {A. S.} and Ivanova, {A. D.} and Komarov, {V. Yu} and Nadolinny, {V. A.} and Lavrenova, {L. G.}",
note = "Publisher Copyright: {\textcopyright} 2018 The Royal Society of Chemistry and the Centre National de la Recherche Scientifique.",
year = "2018",
month = apr,
day = "7",
doi = "10.1039/c8nj00017d",
language = "English",
volume = "42",
pages = "4902--4908",
journal = "New Journal of Chemistry",
issn = "1144-0546",
publisher = "ROYAL SOC CHEMISTRY",
number = "7",

}

RIS

TY - JOUR

T1 - Influence of water on the structure and magnetic properties of a copper bromide coordination compound with 3-amino-4-ethoxycarbonylpyrazole

AU - Berezin, A. S.

AU - Ivanova, A. D.

AU - Komarov, V. Yu

AU - Nadolinny, V. A.

AU - Lavrenova, L. G.

N1 - Publisher Copyright: © 2018 The Royal Society of Chemistry and the Centre National de la Recherche Scientifique.

PY - 2018/4/7

Y1 - 2018/4/7

N2 - The influence of water on a polynuclear [CuL2Br2]n (1) copper bromide compound with 3-amino-4-ethoxycarbonylpyrazole (L) is investigated. The abundance of water in solution results in the formation of three new complexes with drastically different coordination units: polynuclear {[CuL4Br]Br}n·nH2O (2) and two mononuclear polymorphs [CuL4Br2]·2H2O (monoclinic-3, triclinic-4). The crystal structures are determined for all three complexes. Complex 2 has a weak (≪1 cm-1) superexchange interaction between copper ions and bromide ions. Complexes 3 and 4 have no exchange interaction. It is found that the two polynuclear complexes may transform into each other through dissolution followed by recrystallization under certain conditions.

AB - The influence of water on a polynuclear [CuL2Br2]n (1) copper bromide compound with 3-amino-4-ethoxycarbonylpyrazole (L) is investigated. The abundance of water in solution results in the formation of three new complexes with drastically different coordination units: polynuclear {[CuL4Br]Br}n·nH2O (2) and two mononuclear polymorphs [CuL4Br2]·2H2O (monoclinic-3, triclinic-4). The crystal structures are determined for all three complexes. Complex 2 has a weak (≪1 cm-1) superexchange interaction between copper ions and bromide ions. Complexes 3 and 4 have no exchange interaction. It is found that the two polynuclear complexes may transform into each other through dissolution followed by recrystallization under certain conditions.

KW - SPIN TRANSITION

KW - COMPLEXES

KW - POLYMERS

KW - LENGTH

KW - CUCL2

KW - EPR

UR - http://www.scopus.com/inward/record.url?scp=85044418746&partnerID=8YFLogxK

U2 - 10.1039/c8nj00017d

DO - 10.1039/c8nj00017d

M3 - Article

AN - SCOPUS:85044418746

VL - 42

SP - 4902

EP - 4908

JO - New Journal of Chemistry

JF - New Journal of Chemistry

SN - 1144-0546

IS - 7

ER -

ID: 12214730