Influence of water on the structure and magnetic properties of a copper bromide coordination compound with 3-amino-4-ethoxycarbonylpyrazole

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Influence of water on the structure and magnetic properties of a copper bromide coordination compound with 3-amino-4-ethoxycarbonylpyrazole. / Berezin, A. S.; Ivanova, A. D.; Komarov, V. Yu и др.

в: New Journal of Chemistry, Том 42, № 7, 07.04.2018, стр. 4902-4908.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

BibTeX

@article{74ebbef08eba453b9cc66a935d41a92a,

title = "Influence of water on the structure and magnetic properties of a copper bromide coordination compound with 3-amino-4-ethoxycarbonylpyrazole",

abstract = "The influence of water on a polynuclear [CuL2Br2]n (1) copper bromide compound with 3-amino-4-ethoxycarbonylpyrazole (L) is investigated. The abundance of water in solution results in the formation of three new complexes with drastically different coordination units: polynuclear {[CuL4Br]Br}n·nH2O (2) and two mononuclear polymorphs [CuL4Br2]·2H2O (monoclinic-3, triclinic-4). The crystal structures are determined for all three complexes. Complex 2 has a weak (≪1 cm-1) superexchange interaction between copper ions and bromide ions. Complexes 3 and 4 have no exchange interaction. It is found that the two polynuclear complexes may transform into each other through dissolution followed by recrystallization under certain conditions.",

keywords = "SPIN TRANSITION, COMPLEXES, POLYMERS, LENGTH, CUCL2, EPR",

author = "Berezin, {A. S.} and Ivanova, {A. D.} and Komarov, {V. Yu} and Nadolinny, {V. A.} and Lavrenova, {L. G.}",

note = "Publisher Copyright: {\textcopyright} 2018 The Royal Society of Chemistry and the Centre National de la Recherche Scientifique.",

year = "2018",

month = apr,

day = "7",

doi = "10.1039/c8nj00017d",

language = "English",

volume = "42",

pages = "4902--4908",

journal = "New Journal of Chemistry",

issn = "1144-0546",

publisher = "ROYAL SOC CHEMISTRY",

number = "7",

}

RIS

TY - JOUR

T1 - Influence of water on the structure and magnetic properties of a copper bromide coordination compound with 3-amino-4-ethoxycarbonylpyrazole

AU - Berezin, A. S.

AU - Ivanova, A. D.

AU - Komarov, V. Yu

AU - Nadolinny, V. A.

AU - Lavrenova, L. G.

PY - 2018/4/7

Y1 - 2018/4/7

N2 - The influence of water on a polynuclear [CuL2Br2]n (1) copper bromide compound with 3-amino-4-ethoxycarbonylpyrazole (L) is investigated. The abundance of water in solution results in the formation of three new complexes with drastically different coordination units: polynuclear {[CuL4Br]Br}n·nH2O (2) and two mononuclear polymorphs [CuL4Br2]·2H2O (monoclinic-3, triclinic-4). The crystal structures are determined for all three complexes. Complex 2 has a weak (≪1 cm-1) superexchange interaction between copper ions and bromide ions. Complexes 3 and 4 have no exchange interaction. It is found that the two polynuclear complexes may transform into each other through dissolution followed by recrystallization under certain conditions.

AB - The influence of water on a polynuclear [CuL2Br2]n (1) copper bromide compound with 3-amino-4-ethoxycarbonylpyrazole (L) is investigated. The abundance of water in solution results in the formation of three new complexes with drastically different coordination units: polynuclear {[CuL4Br]Br}n·nH2O (2) and two mononuclear polymorphs [CuL4Br2]·2H2O (monoclinic-3, triclinic-4). The crystal structures are determined for all three complexes. Complex 2 has a weak (≪1 cm-1) superexchange interaction between copper ions and bromide ions. Complexes 3 and 4 have no exchange interaction. It is found that the two polynuclear complexes may transform into each other through dissolution followed by recrystallization under certain conditions.

KW - SPIN TRANSITION

KW - COMPLEXES

KW - POLYMERS

KW - LENGTH

KW - CUCL2

KW - EPR

UR - http://www.scopus.com/inward/record.url?scp=85044418746&partnerID=8YFLogxK

U2 - 10.1039/c8nj00017d

DO - 10.1039/c8nj00017d

M3 - Article

AN - SCOPUS:85044418746

VL - 42

SP - 4902

EP - 4908

JO - New Journal of Chemistry

JF - New Journal of Chemistry

SN - 1144-0546

IS - 7

ER -

ID: 12214730