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Influence of Magnetic Field on the Structure and Sensor Properties of Thin Titanyl Phthalocyanine Layers. / Dyusenova, S. E.; Klyamer, D. D.; Sukhikh, A. S. et al.

In: Journal of Structural Chemistry, Vol. 64, No. 3, 03.2023, p. 337-346.

Research output: Contribution to journalArticlepeer-review

Harvard

Dyusenova, SE, Klyamer, DD, Sukhikh, AS, Shchudlo, IM, Taskaev, SY, Basova, TV & Gromilov, SA 2023, 'Influence of Magnetic Field on the Structure and Sensor Properties of Thin Titanyl Phthalocyanine Layers', Journal of Structural Chemistry, vol. 64, no. 3, pp. 337-346. https://doi.org/10.1134/S0022476623030010

APA

Vancouver

Dyusenova SE, Klyamer DD, Sukhikh AS, Shchudlo IM, Taskaev SY, Basova TV et al. Influence of Magnetic Field on the Structure and Sensor Properties of Thin Titanyl Phthalocyanine Layers. Journal of Structural Chemistry. 2023 Mar;64(3):337-346. doi: 10.1134/S0022476623030010

Author

Dyusenova, S. E. ; Klyamer, D. D. ; Sukhikh, A. S. et al. / Influence of Magnetic Field on the Structure and Sensor Properties of Thin Titanyl Phthalocyanine Layers. In: Journal of Structural Chemistry. 2023 ; Vol. 64, No. 3. pp. 337-346.

BibTeX

@article{c3ed34d5257d45f7960a0649e3ec6569,
title = "Influence of Magnetic Field on the Structure and Sensor Properties of Thin Titanyl Phthalocyanine Layers",
abstract = "We report a study of the effect of magnetic field on the structural organization and sensory properties of thin titanyl phthalocyanine (TiOPc) layers deposited by vacuum thermal evaporation. It is shown that magnetic field (directed perpendicular to the substrate surface) does not affect the phase composition of the layers which are represented by II-triclinic and I-monoclinic crystal modifications in both cases. The crystallites of both phases demonstrate preferential orientations, the angles between molecular planes and the substrate are 62.53° and 5.30°, respectively. The 2D GIXD study shows that magnetic field significantly improves the crystallinity of obtained thin layers; the conductivity increases by ~10 times, but the sensory response to ammonia does not change. Irradiating the layer obtained in magnetic field by fast neutrons (fluence 3·1014 cm–2) decreases the conductivity by two orders of magnitude. This effect is not observed in the parallel experiment without magnetic field.",
keywords = "2D GIXD, conductivity, fast neutrons, film, metal phthalocyanines, powder XRD, sensory response, structural organization of films",
author = "Dyusenova, {S. E.} and Klyamer, {D. D.} and Sukhikh, {A. S.} and Shchudlo, {I. M.} and Taskaev, {S. Y.} and Basova, {T. V.} and Gromilov, {S. A.}",
note = "This work was funded by the Ministry of Science and Higher Education of the Russian Federation: project No. 121031700314-5 (synthesis, film deposition, study of sensory properties); project No. 121031700313-8 and “Priority 2030” program (XRD and crystal chemical studies). Публикация для корректировки.",
year = "2023",
month = mar,
doi = "10.1134/S0022476623030010",
language = "English",
volume = "64",
pages = "337--346",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "3",

}

RIS

TY - JOUR

T1 - Influence of Magnetic Field on the Structure and Sensor Properties of Thin Titanyl Phthalocyanine Layers

AU - Dyusenova, S. E.

AU - Klyamer, D. D.

AU - Sukhikh, A. S.

AU - Shchudlo, I. M.

AU - Taskaev, S. Y.

AU - Basova, T. V.

AU - Gromilov, S. A.

N1 - This work was funded by the Ministry of Science and Higher Education of the Russian Federation: project No. 121031700314-5 (synthesis, film deposition, study of sensory properties); project No. 121031700313-8 and “Priority 2030” program (XRD and crystal chemical studies). Публикация для корректировки.

PY - 2023/3

Y1 - 2023/3

N2 - We report a study of the effect of magnetic field on the structural organization and sensory properties of thin titanyl phthalocyanine (TiOPc) layers deposited by vacuum thermal evaporation. It is shown that magnetic field (directed perpendicular to the substrate surface) does not affect the phase composition of the layers which are represented by II-triclinic and I-monoclinic crystal modifications in both cases. The crystallites of both phases demonstrate preferential orientations, the angles between molecular planes and the substrate are 62.53° and 5.30°, respectively. The 2D GIXD study shows that magnetic field significantly improves the crystallinity of obtained thin layers; the conductivity increases by ~10 times, but the sensory response to ammonia does not change. Irradiating the layer obtained in magnetic field by fast neutrons (fluence 3·1014 cm–2) decreases the conductivity by two orders of magnitude. This effect is not observed in the parallel experiment without magnetic field.

AB - We report a study of the effect of magnetic field on the structural organization and sensory properties of thin titanyl phthalocyanine (TiOPc) layers deposited by vacuum thermal evaporation. It is shown that magnetic field (directed perpendicular to the substrate surface) does not affect the phase composition of the layers which are represented by II-triclinic and I-monoclinic crystal modifications in both cases. The crystallites of both phases demonstrate preferential orientations, the angles between molecular planes and the substrate are 62.53° and 5.30°, respectively. The 2D GIXD study shows that magnetic field significantly improves the crystallinity of obtained thin layers; the conductivity increases by ~10 times, but the sensory response to ammonia does not change. Irradiating the layer obtained in magnetic field by fast neutrons (fluence 3·1014 cm–2) decreases the conductivity by two orders of magnitude. This effect is not observed in the parallel experiment without magnetic field.

KW - 2D GIXD

KW - conductivity

KW - fast neutrons

KW - film

KW - metal phthalocyanines

KW - powder XRD

KW - sensory response

KW - structural organization of films

UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-85152699856&origin=inward&txGid=7dee559af2fbec8d84f7306e38f8995d

UR - https://www.mendeley.com/catalogue/9343bc21-31d2-3eac-bbf3-1979d4fadcd6/

U2 - 10.1134/S0022476623030010

DO - 10.1134/S0022476623030010

M3 - Article

VL - 64

SP - 337

EP - 346

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 3

ER -

ID: 59655057